Kinetics of 2, 2-dinitropropyl acrylate polymerization and the copolymerization with acrylonitrile

Gong Zheng Zhang; Fang Wang; Xing Xiang

Kinetics of 2, 2-dinitropropyl acrylate polymerization and the copolymerization with acrylonitrile

Gong Zheng Zhang^*
, Fang Wang
, Xing Xiang

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The polymerization kinetics of 2, 2 dinitropropyl acrylate (DNPA) in toluene have been studied with dilatometer method, the polymerization rate equation was determined. At the same time, the behavior of the copolymerization between DNPA and acrylonitrile (AN) has also been studied, the composition of the copolymer was determined using the infrared spectrum method, and the reactivity ratios of DNPA and AN were determined. The results show that the polymerization rate equation for DNPA is R_p=k[M]^1.18[I]^0.6, which displays that the chain termination reaction is according to the mode of mono- and bi-molecule termination, and the inititate process is dependent of monomer concentration. The reactivity ratios of DNPA and AN are calculated by the Fineman-Ross method, and they are r_AN=0.508 and r_DNPA=0.157, respectively.

Original language	English
Pages (from-to)	35-38
Number of pages	4
Journal	Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering
Volume	26
Issue number	12
Publication status	Published - Dec 2010
Externally published	Yes

Keywords

2, 2-dinitropropyl acrylate
Acrylonitrile
Polymerization kinetics
Reactivity ratio
Solution copolymerization

Cite this

@article{3cc49c1b314f4a219f3b41cab25a7bf1,

title = "Kinetics of 2, 2-dinitropropyl acrylate polymerization and the copolymerization with acrylonitrile",

abstract = "The polymerization kinetics of 2, 2 dinitropropyl acrylate (DNPA) in toluene have been studied with dilatometer method, the polymerization rate equation was determined. At the same time, the behavior of the copolymerization between DNPA and acrylonitrile (AN) has also been studied, the composition of the copolymer was determined using the infrared spectrum method, and the reactivity ratios of DNPA and AN were determined. The results show that the polymerization rate equation for DNPA is Rp=k[M]1.18[I]0.6, which displays that the chain termination reaction is according to the mode of mono- and bi-molecule termination, and the inititate process is dependent of monomer concentration. The reactivity ratios of DNPA and AN are calculated by the Fineman-Ross method, and they are rAN=0.508 and rDNPA=0.157, respectively.",

keywords = "2, 2-dinitropropyl acrylate, Acrylonitrile, Polymerization kinetics, Reactivity ratio, Solution copolymerization",

author = "Zhang, \{Gong Zheng\} and Fang Wang and Xing Xiang",

year = "2010",

month = dec,

language = "English",

volume = "26",

pages = "35--38",

journal = "Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering",

issn = "1000-7555",

publisher = "Chengdu University of Science and Technology",

number = "12",

}

TY - JOUR

T1 - Kinetics of 2, 2-dinitropropyl acrylate polymerization and the copolymerization with acrylonitrile

AU - Zhang, Gong Zheng

AU - Wang, Fang

AU - Xiang, Xing

PY - 2010/12

Y1 - 2010/12

N2 - The polymerization kinetics of 2, 2 dinitropropyl acrylate (DNPA) in toluene have been studied with dilatometer method, the polymerization rate equation was determined. At the same time, the behavior of the copolymerization between DNPA and acrylonitrile (AN) has also been studied, the composition of the copolymer was determined using the infrared spectrum method, and the reactivity ratios of DNPA and AN were determined. The results show that the polymerization rate equation for DNPA is Rp=k[M]1.18[I]0.6, which displays that the chain termination reaction is according to the mode of mono- and bi-molecule termination, and the inititate process is dependent of monomer concentration. The reactivity ratios of DNPA and AN are calculated by the Fineman-Ross method, and they are rAN=0.508 and rDNPA=0.157, respectively.

AB - The polymerization kinetics of 2, 2 dinitropropyl acrylate (DNPA) in toluene have been studied with dilatometer method, the polymerization rate equation was determined. At the same time, the behavior of the copolymerization between DNPA and acrylonitrile (AN) has also been studied, the composition of the copolymer was determined using the infrared spectrum method, and the reactivity ratios of DNPA and AN were determined. The results show that the polymerization rate equation for DNPA is Rp=k[M]1.18[I]0.6, which displays that the chain termination reaction is according to the mode of mono- and bi-molecule termination, and the inititate process is dependent of monomer concentration. The reactivity ratios of DNPA and AN are calculated by the Fineman-Ross method, and they are rAN=0.508 and rDNPA=0.157, respectively.

KW - 2, 2-dinitropropyl acrylate

KW - Acrylonitrile

KW - Polymerization kinetics

KW - Reactivity ratio

KW - Solution copolymerization

UR - https://www.scopus.com/pages/publications/79952456886

M3 - Article

AN - SCOPUS:79952456886

SN - 1000-7555

VL - 26

SP - 35

EP - 38

JO - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

JF - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

IS - 12

ER -

Kinetics of 2, 2-dinitropropyl acrylate polymerization and the copolymerization with acrylonitrile

Abstract

Keywords

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