Kinetic study of parasitic reactions in lithium-ion batteries: A case study on LiNi0.6Mn0.2Co0.2O2

Xiaoqiao Zeng; Gui Liang Xu; Yan Li; Xiangyi Luo; Filippo Maglia; Christoph Bauer; Simon Franz Lux; Odysseas Paschos; Sung Jin Kim; Peter Lamp; Jun Lu; Khalil Amine; Zonghai Chen

doi:10.1021/acsami.5b11800

Kinetic study of parasitic reactions in lithium-ion batteries: A case study on LiNi_0.6Mn_0.2Co_0.2O₂

Xiaoqiao Zeng
, Gui Liang Xu
, Yan Li
, Xiangyi Luo
, Filippo Maglia
, Christoph Bauer
, Simon Franz Lux
, Odysseas Paschos
, Sung Jin Kim
, Peter Lamp
, Jun Lu
, Khalil Amine^*
, Zonghai Chen

^*Corresponding author for this work

Argonne National Laboratory
BMW Group

Research output: Contribution to journal › Article › peer-review

103 Citations (Scopus)

Abstract

The side reactions between the electrode materials and the nonaqueous electrolytes have been the major contributor to the degradation of electrochemical performance of lithium-ion batteries. A home-built high-precision leakage current measuring system was deployed to investigate the reaction kinetics between the delithiated LiNi_0.6Mn_0.2Co_0.2O₂ and a conventional nonaqueous electrolyte. It was found that the rate of parasitic reaction had strong dependence on the upper cutoff potential of the cathode material. The kinetic data also indicated a change of reaction mode at about 4.5 V vs Li⁺/Li.

Original language	English
Pages (from-to)	3446-3451
Number of pages	6
Journal	ACS applied materials & interfaces
Volume	8
Issue number	5
DOIs	https://doi.org/10.1021/acsami.5b11800
Publication status	Published - 10 Feb 2016
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

cathode
interfacial reaction
leakage current
lithium-ion battery
parasitic reaction

Access to Document

10.1021/acsami.5b11800

Cite this

@article{4d6ebed103bf4ccbb870ecc8929fa126,

title = "Kinetic study of parasitic reactions in lithium-ion batteries: A case study on LiNi0.6Mn0.2Co0.2O2",

abstract = "The side reactions between the electrode materials and the nonaqueous electrolytes have been the major contributor to the degradation of electrochemical performance of lithium-ion batteries. A home-built high-precision leakage current measuring system was deployed to investigate the reaction kinetics between the delithiated LiNi0.6Mn0.2Co0.2O2 and a conventional nonaqueous electrolyte. It was found that the rate of parasitic reaction had strong dependence on the upper cutoff potential of the cathode material. The kinetic data also indicated a change of reaction mode at about 4.5 V vs Li+/Li.",

keywords = "cathode, interfacial reaction, leakage current, lithium-ion battery, parasitic reaction",

author = "Xiaoqiao Zeng and Xu, \{Gui Liang\} and Yan Li and Xiangyi Luo and Filippo Maglia and Christoph Bauer and Lux, \{Simon Franz\} and Odysseas Paschos and Kim, \{Sung Jin\} and Peter Lamp and Jun Lu and Khalil Amine and Zonghai Chen",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = feb,

day = "10",

doi = "10.1021/acsami.5b11800",

language = "English",

volume = "8",

pages = "3446--3451",

journal = "ACS applied materials \& interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Kinetic study of parasitic reactions in lithium-ion batteries

T2 - A case study on LiNi0.6Mn0.2Co0.2O2

AU - Zeng, Xiaoqiao

AU - Xu, Gui Liang

AU - Li, Yan

AU - Luo, Xiangyi

AU - Maglia, Filippo

AU - Bauer, Christoph

AU - Lux, Simon Franz

AU - Paschos, Odysseas

AU - Kim, Sung Jin

AU - Lamp, Peter

AU - Lu, Jun

AU - Amine, Khalil

AU - Chen, Zonghai

PY - 2016/2/10

Y1 - 2016/2/10

N2 - The side reactions between the electrode materials and the nonaqueous electrolytes have been the major contributor to the degradation of electrochemical performance of lithium-ion batteries. A home-built high-precision leakage current measuring system was deployed to investigate the reaction kinetics between the delithiated LiNi0.6Mn0.2Co0.2O2 and a conventional nonaqueous electrolyte. It was found that the rate of parasitic reaction had strong dependence on the upper cutoff potential of the cathode material. The kinetic data also indicated a change of reaction mode at about 4.5 V vs Li+/Li.

AB - The side reactions between the electrode materials and the nonaqueous electrolytes have been the major contributor to the degradation of electrochemical performance of lithium-ion batteries. A home-built high-precision leakage current measuring system was deployed to investigate the reaction kinetics between the delithiated LiNi0.6Mn0.2Co0.2O2 and a conventional nonaqueous electrolyte. It was found that the rate of parasitic reaction had strong dependence on the upper cutoff potential of the cathode material. The kinetic data also indicated a change of reaction mode at about 4.5 V vs Li+/Li.

KW - cathode

KW - interfacial reaction

KW - leakage current

KW - lithium-ion battery

KW - parasitic reaction

UR - https://www.scopus.com/pages/publications/84958268072

U2 - 10.1021/acsami.5b11800

DO - 10.1021/acsami.5b11800

M3 - Article

AN - SCOPUS:84958268072

SN - 1944-8244

VL - 8

SP - 3446

EP - 3451

JO - ACS applied materials & interfaces

JF - ACS applied materials & interfaces

IS - 5

ER -