Isothermal hazards evaluation of benzoyl peroxide mixed with benzoic acid via TAM III test

Tien Szu Wang; Shang Hao Liu; Xin Ming Qian; Mei Li You; Wei Lung Chou; Chi Min Shu

doi:10.1007/s10973-013-3020-8

Isothermal hazards evaluation of benzoyl peroxide mixed with benzoic acid via TAM III test

Tien Szu Wang, Shang Hao Liu, Xin Ming Qian, Mei Li You, Wei Lung Chou, Chi Min Shu^*

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

Isothermal microcalorimetry can be used to investigate the thermokinetic parameters for reactive mechanisms. Benzoyl peroxide (BPO), a typical organic peroxide, undergoes an autocatalytic reaction under isothermal decomposition. It requires intrinsically safer design of preparation, manufacturing, transportation, storage, and even disposal. The scope of this study was to describe the exothermic reaction and reaction model of BPO and mixed with benzoic acid by the thermal activity monitor III (TAM III). The results showed the isothermal kinetic parameters, such as activation energy (E _a), frequency factor (A), heat of decomposition (ΔH _d), and time to maximum rate under isothermal conditions (TMR _iso), which were necessary and useful to insure safe storage or transportation for self-reactive substances applied in the process industries.

Original language	English
Pages (from-to)	1625-1631
Number of pages	7
Journal	Journal of Thermal Analysis and Calorimetry
Volume	113
Issue number	3
DOIs	https://doi.org/10.1007/s10973-013-3020-8
Publication status	Published - Sept 2013

Keywords

Autocatalytic reaction
Intrinsically safer design
Isothermal kinetic parameters
Process industries
Thermal activity monitor III (TAM III)
Thermokinetic parameters

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10.1007/s10973-013-3020-8

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title = "Isothermal hazards evaluation of benzoyl peroxide mixed with benzoic acid via TAM III test",

abstract = "Isothermal microcalorimetry can be used to investigate the thermokinetic parameters for reactive mechanisms. Benzoyl peroxide (BPO), a typical organic peroxide, undergoes an autocatalytic reaction under isothermal decomposition. It requires intrinsically safer design of preparation, manufacturing, transportation, storage, and even disposal. The scope of this study was to describe the exothermic reaction and reaction model of BPO and mixed with benzoic acid by the thermal activity monitor III (TAM III). The results showed the isothermal kinetic parameters, such as activation energy (E a), frequency factor (A), heat of decomposition (ΔH d), and time to maximum rate under isothermal conditions (TMR iso), which were necessary and useful to insure safe storage or transportation for self-reactive substances applied in the process industries.",

keywords = "Autocatalytic reaction, Intrinsically safer design, Isothermal kinetic parameters, Process industries, Thermal activity monitor III (TAM III), Thermokinetic parameters",

author = "Wang, \{Tien Szu\} and Liu, \{Shang Hao\} and Qian, \{Xin Ming\} and You, \{Mei Li\} and Chou, \{Wei Lung\} and Shu, \{Chi Min\}",

year = "2013",

month = sep,

doi = "10.1007/s10973-013-3020-8",

language = "English",

volume = "113",

pages = "1625--1631",

journal = "Journal of Thermal Analysis and Calorimetry",

issn = "1388-6150",

publisher = "Springer Science and Business Media B.V.",

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TY - JOUR

T1 - Isothermal hazards evaluation of benzoyl peroxide mixed with benzoic acid via TAM III test

AU - Wang, Tien Szu

AU - Liu, Shang Hao

AU - Qian, Xin Ming

AU - You, Mei Li

AU - Chou, Wei Lung

AU - Shu, Chi Min

PY - 2013/9

Y1 - 2013/9

N2 - Isothermal microcalorimetry can be used to investigate the thermokinetic parameters for reactive mechanisms. Benzoyl peroxide (BPO), a typical organic peroxide, undergoes an autocatalytic reaction under isothermal decomposition. It requires intrinsically safer design of preparation, manufacturing, transportation, storage, and even disposal. The scope of this study was to describe the exothermic reaction and reaction model of BPO and mixed with benzoic acid by the thermal activity monitor III (TAM III). The results showed the isothermal kinetic parameters, such as activation energy (E a), frequency factor (A), heat of decomposition (ΔH d), and time to maximum rate under isothermal conditions (TMR iso), which were necessary and useful to insure safe storage or transportation for self-reactive substances applied in the process industries.

AB - Isothermal microcalorimetry can be used to investigate the thermokinetic parameters for reactive mechanisms. Benzoyl peroxide (BPO), a typical organic peroxide, undergoes an autocatalytic reaction under isothermal decomposition. It requires intrinsically safer design of preparation, manufacturing, transportation, storage, and even disposal. The scope of this study was to describe the exothermic reaction and reaction model of BPO and mixed with benzoic acid by the thermal activity monitor III (TAM III). The results showed the isothermal kinetic parameters, such as activation energy (E a), frequency factor (A), heat of decomposition (ΔH d), and time to maximum rate under isothermal conditions (TMR iso), which were necessary and useful to insure safe storage or transportation for self-reactive substances applied in the process industries.

KW - Autocatalytic reaction

KW - Intrinsically safer design

KW - Isothermal kinetic parameters

KW - Process industries

KW - Thermal activity monitor III (TAM III)

KW - Thermokinetic parameters

UR - https://www.scopus.com/pages/publications/84883149851

U2 - 10.1007/s10973-013-3020-8

DO - 10.1007/s10973-013-3020-8

M3 - Article

AN - SCOPUS:84883149851

SN - 1388-6150

VL - 113

SP - 1625

EP - 1631

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

IS - 3

ER -

Isothermal hazards evaluation of benzoyl peroxide mixed with benzoic acid via TAM III test

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Keywords

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