Abstract
We developed a metalloligand strategy to construct porous frameworks, viz. the combined use of IrIII-based octahedral metalloligands and the linear unit [Ni(cyclam)] easily afforded two isostructural complexes 1 and 2 with primitive cubic frameworks. Both complexes show good CO2/N2 separation property.
| Original language | English |
|---|---|
| Pages (from-to) | 3110-3113 |
| Number of pages | 4 |
| Journal | Chemistry - An Asian Journal |
| Volume | 12 |
| Issue number | 24 |
| DOIs | |
| Publication status | Published - 14 Dec 2017 |
| Externally published | Yes |
Keywords
- carbon dioxide adsorption
- gas separation
- iridium
- metal-organic frameworks
- metalloligand
- primitive cubic frameworks
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