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IrIII-based Octahedral Metalloligands Derived Primitive Cubic Frameworks for Enhanced CO2/N2 Separation

  • Sheng Li Huang
  • , Naifang Liu
  • , Yun Ling
  • , He Kuan Luo*
  • *Corresponding author for this work
  • Agency for Science, Technology and Research, Singapore
  • National University of Singapore
  • Fudan University

Research output: Contribution to journal › Article › peer-review

Abstract

We developed a metalloligand strategy to construct porous frameworks, viz. the combined use of IrIII-based octahedral metalloligands and the linear unit [Ni(cyclam)] easily afforded two isostructural complexes 1 and 2 with primitive cubic frameworks. Both complexes show good CO2/N2 separation property.

Original languageEnglish
Pages (from-to)3110-3113
Number of pages4
JournalChemistry - An Asian Journal
Volume12
Issue number24
DOIs
Publication statusPublished - 14 Dec 2017
Externally publishedYes

Keywords

  • carbon dioxide adsorption
  • gas separation
  • iridium
  • metal-organic frameworks
  • metalloligand
  • primitive cubic frameworks

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