Iodide-Centered Cuprous Octatomic Ring: A Luminescent Molecular Thermometer Exhibiting Dual-Emission Character

Cheng Yang Yue; Fu Ling Liu; Wen Ting Deng; Jun Tao; Mao Chun Hong

doi:10.1021/acs.cgd.7b01261

Iodide-Centered Cuprous Octatomic Ring: A Luminescent Molecular Thermometer Exhibiting Dual-Emission Character

Cheng Yang Yue
, Fu Ling Liu
, Wen Ting Deng
, Jun Tao^*
, Mao Chun Hong

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Luminescent molecular thermometers have attracted great attention due to their potential application for temperature detection in special environments. By a very simple one-step method, we have synthesized one novel cuprous compound, [I@Cu₈(HMTZ)(MTZ)₇]·MeCN·2H₂O (I@Cu8), which consists of an infrequent octatomic [I@Cu₈S₈] ring. Importantly, compound I@Cu8 features dual-emitting behavior and shows successive visual luminescent emissions varying from green, to yellow, to orange, and then to red in the temperature range of 80-300 K, suggesting potential application for a luminescent molecular thermometer.

Original language	English
Pages (from-to)	22-26
Number of pages	5
Journal	Crystal Growth and Design
Volume	18
Issue number	1
DOIs	https://doi.org/10.1021/acs.cgd.7b01261
Publication status	Published - 3 Jan 2018

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title = "Iodide-Centered Cuprous Octatomic Ring: A Luminescent Molecular Thermometer Exhibiting Dual-Emission Character",

abstract = "Luminescent molecular thermometers have attracted great attention due to their potential application for temperature detection in special environments. By a very simple one-step method, we have synthesized one novel cuprous compound, [I@Cu8(HMTZ)(MTZ)7]·MeCN·2H2O (I@Cu8), which consists of an infrequent octatomic [I@Cu8S8] ring. Importantly, compound I@Cu8 features dual-emitting behavior and shows successive visual luminescent emissions varying from green, to yellow, to orange, and then to red in the temperature range of 80-300 K, suggesting potential application for a luminescent molecular thermometer.",

author = "Yue, \{Cheng Yang\} and Liu, \{Fu Ling\} and Deng, \{Wen Ting\} and Jun Tao and Hong, \{Mao Chun\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2018",

month = jan,

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doi = "10.1021/acs.cgd.7b01261",

language = "English",

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T1 - Iodide-Centered Cuprous Octatomic Ring

T2 - A Luminescent Molecular Thermometer Exhibiting Dual-Emission Character

AU - Yue, Cheng Yang

AU - Liu, Fu Ling

AU - Deng, Wen Ting

AU - Tao, Jun

AU - Hong, Mao Chun

PY - 2018/1/3

Y1 - 2018/1/3

N2 - Luminescent molecular thermometers have attracted great attention due to their potential application for temperature detection in special environments. By a very simple one-step method, we have synthesized one novel cuprous compound, [I@Cu8(HMTZ)(MTZ)7]·MeCN·2H2O (I@Cu8), which consists of an infrequent octatomic [I@Cu8S8] ring. Importantly, compound I@Cu8 features dual-emitting behavior and shows successive visual luminescent emissions varying from green, to yellow, to orange, and then to red in the temperature range of 80-300 K, suggesting potential application for a luminescent molecular thermometer.

AB - Luminescent molecular thermometers have attracted great attention due to their potential application for temperature detection in special environments. By a very simple one-step method, we have synthesized one novel cuprous compound, [I@Cu8(HMTZ)(MTZ)7]·MeCN·2H2O (I@Cu8), which consists of an infrequent octatomic [I@Cu8S8] ring. Importantly, compound I@Cu8 features dual-emitting behavior and shows successive visual luminescent emissions varying from green, to yellow, to orange, and then to red in the temperature range of 80-300 K, suggesting potential application for a luminescent molecular thermometer.

UR - https://www.scopus.com/pages/publications/85040171471

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DO - 10.1021/acs.cgd.7b01261

M3 - Article

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SN - 1528-7483

VL - 18

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EP - 26

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 1

ER -

Iodide-Centered Cuprous Octatomic Ring: A Luminescent Molecular Thermometer Exhibiting Dual-Emission Character

Abstract

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