Inorganic-organic hybrid materials constructed from [(VO2)(HPO4)]∞ helical chains and [M(4,4'-bpy)2]2+ (M = Co, Ni) fragments

Zhan Shi; Shouhua Feng; Shan Gao; Lirong Zhang; Guoyu Yang; Jia Hua

doi:10.1002/1521-3773(20000703)39:13<2325::AID-ANIE2325>3.0.CO;2-L

Inorganic-organic hybrid materials constructed from [(VO₂)(HPO₄)]∞ helical chains and [M(4,4'-bpy)₂]²⁺ (M = Co, Ni) fragments

Zhan Shi, Shouhua Feng^*, Shan Gao, Lirong Zhang, Guoyu Yang, Jia Hua

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

257 Citations (Scopus)

Abstract

Both left-handed and right-handed helical chains of [(VO₂)(HPO₄)]∞, which are linked by [M(4,4'-bpy)₂] to form three-dimensional framework structures (see picture), are present in the structures of two novel inorganic-organic hybrid materials, [M(4,4'-bpy)₂(VO₂)₂(HPO₄)₄]. These were prepared from hydrothermal systems and characterized by single-crystal X- ray diffraction. M = Co or Ni; bpy = bipyridine.

Original language	English
Pages (from-to)	2325-2327
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	13
DOIs	https://doi.org/10.1002/1521-3773(20000703)39:13<2325::AID-ANIE2325>3.0.CO;2-L
Publication status	Published - 3 Jul 2000
Externally published	Yes

Keywords

Coordination chemistry
Helical structures
N ligands
Polyoxometalates
Vanadium

Access to Document

10.1002/1521-3773(20000703)39:13<2325::AID-ANIE2325>3.0.CO;2-L

Cite this

@article{9cc6c81e01504b1ea588af835797f3d6,

title = "Inorganic-organic hybrid materials constructed from [(VO2)(HPO4)]∞ helical chains and [M(4,4'-bpy)2]2+ (M = Co, Ni) fragments",

abstract = "Both left-handed and right-handed helical chains of [(VO2)(HPO4)]∞, which are linked by [M(4,4'-bpy)2] to form three-dimensional framework structures (see picture), are present in the structures of two novel inorganic-organic hybrid materials, [M(4,4'-bpy)2(VO2)2(HPO4)4]. These were prepared from hydrothermal systems and characterized by single-crystal X- ray diffraction. M = Co or Ni; bpy = bipyridine.",

keywords = "Coordination chemistry, Helical structures, N ligands, Polyoxometalates, Vanadium",

author = "Zhan Shi and Shouhua Feng and Shan Gao and Lirong Zhang and Guoyu Yang and Jia Hua",

year = "2000",

month = jul,

day = "3",

doi = "10.1002/1521-3773(20000703)39:13<2325::AID-ANIE2325>3.0.CO;2-L",

language = "English",

volume = "39",

pages = "2325--2327",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "13",

}

TY - JOUR

T1 - Inorganic-organic hybrid materials constructed from [(VO2)(HPO4)]∞ helical chains and [M(4,4'-bpy)2]2+ (M = Co, Ni) fragments

AU - Shi, Zhan

AU - Feng, Shouhua

AU - Gao, Shan

AU - Zhang, Lirong

AU - Yang, Guoyu

AU - Hua, Jia

PY - 2000/7/3

Y1 - 2000/7/3

N2 - Both left-handed and right-handed helical chains of [(VO2)(HPO4)]∞, which are linked by [M(4,4'-bpy)2] to form three-dimensional framework structures (see picture), are present in the structures of two novel inorganic-organic hybrid materials, [M(4,4'-bpy)2(VO2)2(HPO4)4]. These were prepared from hydrothermal systems and characterized by single-crystal X- ray diffraction. M = Co or Ni; bpy = bipyridine.

AB - Both left-handed and right-handed helical chains of [(VO2)(HPO4)]∞, which are linked by [M(4,4'-bpy)2] to form three-dimensional framework structures (see picture), are present in the structures of two novel inorganic-organic hybrid materials, [M(4,4'-bpy)2(VO2)2(HPO4)4]. These were prepared from hydrothermal systems and characterized by single-crystal X- ray diffraction. M = Co or Ni; bpy = bipyridine.

KW - Coordination chemistry

KW - Helical structures

KW - N ligands

KW - Polyoxometalates

KW - Vanadium

UR - http://www.scopus.com/inward/record.url?scp=0034600773&partnerID=8YFLogxK

U2 - 10.1002/1521-3773(20000703)39:13<2325::AID-ANIE2325>3.0.CO;2-L

DO - 10.1002/1521-3773(20000703)39:13<2325::AID-ANIE2325>3.0.CO;2-L

M3 - Article

AN - SCOPUS:0034600773

SN - 1433-7851

VL - 39

SP - 2325

EP - 2327

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13

ER -

Inorganic-organic hybrid materials constructed from [(VO₂)(HPO₄)]∞ helical chains and [M(4,4'-bpy)₂]²⁺ (M = Co, Ni) fragments

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this