In situ growth of MOFs on the surface of Si nanoparticles for highly efficient lithium storage: Si@MOF nanocomposites as anode materials for lithium-ion batteries

Yuzhen Han; Pengfei Qi; Xiao Feng; Siwu Li; Xiaotao Fu; Haiwei Li; Yifa Chen; Junwen Zhou; Xingguo Li; Bo Wang

doi:10.1021/am5081937

In situ growth of MOFs on the surface of Si nanoparticles for highly efficient lithium storage: Si@MOF nanocomposites as anode materials for lithium-ion batteries

Yuzhen Han
, Pengfei Qi
, Xiao Feng
, Siwu Li
, Xiaotao Fu
, Haiwei Li
, Yifa Chen
, Junwen Zhou
, Xingguo Li
, Bo Wang^*

^*Corresponding author for this work

Ministry of Education in China
Peking University

Research output: Contribution to journal › Article › peer-review

154 Citations (Scopus)

Abstract

A simple yet powerful one-pot strategy is developed to prepare metal-organic framework-coated silicon nanoparticles via in situ mechanochemical synthesis. After simple pyrolysis, the thus-obtained composite shows exceptional electrochemical properties with a lithium storage capacity up to 1050 mA h g^-1, excellent cycle stability (>99% capacity retention after 500 cycles) and outstanding rate performance. These characteristics, combined with their high stability and ease of fabrication, make such Si@MOF nanocomposites ideal alternative candidates as high-energy anode materials in lithium-ion batteries.

Original language	English
Pages (from-to)	2178-2182
Number of pages	5
Journal	ACS Applied Materials and Interfaces
Volume	7
Issue number	4
DOIs	https://doi.org/10.1021/am5081937
Publication status	Published - 4 Feb 2015
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

energy
in situ growth
lithium storage
metal-organic framework
silicon

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10.1021/am5081937

Cite this

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title = "In situ growth of MOFs on the surface of Si nanoparticles for highly efficient lithium storage: Si@MOF nanocomposites as anode materials for lithium-ion batteries",

abstract = "A simple yet powerful one-pot strategy is developed to prepare metal-organic framework-coated silicon nanoparticles via in situ mechanochemical synthesis. After simple pyrolysis, the thus-obtained composite shows exceptional electrochemical properties with a lithium storage capacity up to 1050 mA h g-1, excellent cycle stability (>99\% capacity retention after 500 cycles) and outstanding rate performance. These characteristics, combined with their high stability and ease of fabrication, make such Si@MOF nanocomposites ideal alternative candidates as high-energy anode materials in lithium-ion batteries.",

keywords = "energy, in situ growth, lithium storage, metal-organic framework, silicon",

author = "Yuzhen Han and Pengfei Qi and Xiao Feng and Siwu Li and Xiaotao Fu and Haiwei Li and Yifa Chen and Junwen Zhou and Xingguo Li and Bo Wang",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = feb,

day = "4",

doi = "10.1021/am5081937",

language = "English",

volume = "7",

pages = "2178--2182",

journal = "ACS Applied Materials and Interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

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TY - JOUR

T1 - In situ growth of MOFs on the surface of Si nanoparticles for highly efficient lithium storage

T2 - Si@MOF nanocomposites as anode materials for lithium-ion batteries

AU - Han, Yuzhen

AU - Qi, Pengfei

AU - Feng, Xiao

AU - Li, Siwu

AU - Fu, Xiaotao

AU - Li, Haiwei

AU - Chen, Yifa

AU - Zhou, Junwen

AU - Li, Xingguo

AU - Wang, Bo

PY - 2015/2/4

Y1 - 2015/2/4

N2 - A simple yet powerful one-pot strategy is developed to prepare metal-organic framework-coated silicon nanoparticles via in situ mechanochemical synthesis. After simple pyrolysis, the thus-obtained composite shows exceptional electrochemical properties with a lithium storage capacity up to 1050 mA h g-1, excellent cycle stability (>99% capacity retention after 500 cycles) and outstanding rate performance. These characteristics, combined with their high stability and ease of fabrication, make such Si@MOF nanocomposites ideal alternative candidates as high-energy anode materials in lithium-ion batteries.

AB - A simple yet powerful one-pot strategy is developed to prepare metal-organic framework-coated silicon nanoparticles via in situ mechanochemical synthesis. After simple pyrolysis, the thus-obtained composite shows exceptional electrochemical properties with a lithium storage capacity up to 1050 mA h g-1, excellent cycle stability (>99% capacity retention after 500 cycles) and outstanding rate performance. These characteristics, combined with their high stability and ease of fabrication, make such Si@MOF nanocomposites ideal alternative candidates as high-energy anode materials in lithium-ion batteries.

KW - energy

KW - in situ growth

KW - lithium storage

KW - metal-organic framework

KW - silicon

UR - https://www.scopus.com/pages/publications/84922467563

U2 - 10.1021/am5081937

DO - 10.1021/am5081937

M3 - Article

AN - SCOPUS:84922467563

SN - 1944-8244

VL - 7

SP - 2178

EP - 2182

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

IS - 4

ER -

In situ growth of MOFs on the surface of Si nanoparticles for highly efficient lithium storage: Si@MOF nanocomposites as anode materials for lithium-ion batteries

Abstract

UN SDGs

Keywords

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