Improving properties of energetic coordination polymers through structural modulation from 1D to 3D without changes of ligands or metal nodes

Xin Li; Qi Sun; Ming Lu; Qiuhan Lin

doi:10.1039/c8ce01912f

Improving properties of energetic coordination polymers through structural modulation from 1D to 3D without changes of ligands or metal nodes

Xin Li
, Qi Sun
, Ming Lu^*
, Qiuhan Lin

^*Corresponding author for this work

Nanjing University of Science and Technology

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Two energetic coordination polymers, Pb ₂ (AOT) ₂ ·7(H ₂ O) (1) (AOT: 5,5′-azo-bis(1-oxidotetrazonate)) and Pb ₂ (AOT)O·3(H ₂ O) (2), were prepared at different temperatures and pressures. X-ray data indicate that compound 1 is a 1D structure, while compound 2 is a compact 3D structure. Unlike previous methods on structural modulation, changes of organic ligands or metal nodes are not needed in this work. Experimental analysis and energetic evaluations show that 2 exhibits better mechanical sensitivity, thermal stability, and detonation performance than 1.

Original language	English
Pages (from-to)	937-940
Number of pages	4
Journal	CrystEngComm
Volume	21
Issue number	6
DOIs	https://doi.org/10.1039/c8ce01912f
Publication status	Published - 2019
Externally published	Yes

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title = "Improving properties of energetic coordination polymers through structural modulation from 1D to 3D without changes of ligands or metal nodes",

abstract = " Two energetic coordination polymers, Pb 2 (AOT) 2 ·7(H 2 O) (1) (AOT: 5,5′-azo-bis(1-oxidotetrazonate)) and Pb 2 (AOT)O·3(H 2 O) (2), were prepared at different temperatures and pressures. X-ray data indicate that compound 1 is a 1D structure, while compound 2 is a compact 3D structure. Unlike previous methods on structural modulation, changes of organic ligands or metal nodes are not needed in this work. Experimental analysis and energetic evaluations show that 2 exhibits better mechanical sensitivity, thermal stability, and detonation performance than 1.",

author = "Xin Li and Qi Sun and Ming Lu and Qiuhan Lin",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c8ce01912f",

language = "English",

volume = "21",

pages = "937--940",

journal = "CrystEngComm",

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T1 - Improving properties of energetic coordination polymers through structural modulation from 1D to 3D without changes of ligands or metal nodes

AU - Li, Xin

AU - Sun, Qi

AU - Lu, Ming

AU - Lin, Qiuhan

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - Two energetic coordination polymers, Pb 2 (AOT) 2 ·7(H 2 O) (1) (AOT: 5,5′-azo-bis(1-oxidotetrazonate)) and Pb 2 (AOT)O·3(H 2 O) (2), were prepared at different temperatures and pressures. X-ray data indicate that compound 1 is a 1D structure, while compound 2 is a compact 3D structure. Unlike previous methods on structural modulation, changes of organic ligands or metal nodes are not needed in this work. Experimental analysis and energetic evaluations show that 2 exhibits better mechanical sensitivity, thermal stability, and detonation performance than 1.

AB - Two energetic coordination polymers, Pb 2 (AOT) 2 ·7(H 2 O) (1) (AOT: 5,5′-azo-bis(1-oxidotetrazonate)) and Pb 2 (AOT)O·3(H 2 O) (2), were prepared at different temperatures and pressures. X-ray data indicate that compound 1 is a 1D structure, while compound 2 is a compact 3D structure. Unlike previous methods on structural modulation, changes of organic ligands or metal nodes are not needed in this work. Experimental analysis and energetic evaluations show that 2 exhibits better mechanical sensitivity, thermal stability, and detonation performance than 1.

UR - https://www.scopus.com/pages/publications/85061142616

U2 - 10.1039/c8ce01912f

DO - 10.1039/c8ce01912f

M3 - Article

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SN - 1466-8033

VL - 21

SP - 937

EP - 940

JO - CrystEngComm

JF - CrystEngComm

IS - 6

ER -

Improving properties of energetic coordination polymers through structural modulation from 1D to 3D without changes of ligands or metal nodes

Abstract

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