Hydrothermal synthesis of [Mn5(H2PO4)2 (PO4)2(H2O)4] templated by calixarene under mild conditions

Yun Gong; Hui Li; Chang Wen Hu

Hydrothermal synthesis of [Mn₅(H₂PO₄)₂ (PO₄)₂(H₂O)₄] templated by calixarene under mild conditions

Yun Gong^*
, Hui Li
, Chang Wen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound [Mn₅(H₂PO₄)₂ (PO₄)₂(H₂O)₄] was hydrothermally synthesized in the presence of calix[4]arene-p-tetrasulfonate. The title compound was structurally characterized by X-ray single crystal diffraction. It crystallizes in the monoclinic space group C2/c with a = 1.762 9(4) nm, b = 0.913 44(18) nm, c = 0.949 77(19) nm, β = 96.52(3)°, V = 1.519 5(5) nm³, Z = 4 and R₁ = 0.028 3, and exhibits a three-dimensional framework and channel structure. It was proposed that calixarene can act as template during the formation of the title compound because calixarene can bind Mn²⁺ through second-sphere coordination.

Original language	English
Pages (from-to)	229-232
Number of pages	4
Journal	Journal of Beijing Institute of Technology (English Edition)
Volume	15
Issue number	2
Publication status	Published - Jun 2006

Keywords

Calixarene
Crystal structure
Hydrothermal synthesis
Manganese phosphate
Template

Cite this

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title = "Hydrothermal synthesis of [Mn5(H2PO4)2 (PO4)2(H2O)4] templated by calixarene under mild conditions",

abstract = "The title compound [Mn5(H2PO4)2 (PO4)2(H2O)4] was hydrothermally synthesized in the presence of calix[4]arene-p-tetrasulfonate. The title compound was structurally characterized by X-ray single crystal diffraction. It crystallizes in the monoclinic space group C2/c with a = 1.762 9(4) nm, b = 0.913 44(18) nm, c = 0.949 77(19) nm, β = 96.52(3)°, V = 1.519 5(5) nm3, Z = 4 and R1 = 0.028 3, and exhibits a three-dimensional framework and channel structure. It was proposed that calixarene can act as template during the formation of the title compound because calixarene can bind Mn2+ through second-sphere coordination.",

keywords = "Calixarene, Crystal structure, Hydrothermal synthesis, Manganese phosphate, Template",

author = "Yun Gong and Hui Li and Hu, \{Chang Wen\}",

year = "2006",

month = jun,

language = "English",

volume = "15",

pages = "229--232",

journal = "Journal of Beijing Institute of Technology (English Edition)",

issn = "1004-0579",

publisher = "Beijing Institute of Technology",

number = "2",

}

TY - JOUR

T1 - Hydrothermal synthesis of [Mn5(H2PO4)2 (PO4)2(H2O)4] templated by calixarene under mild conditions

AU - Gong, Yun

AU - Li, Hui

AU - Hu, Chang Wen

PY - 2006/6

Y1 - 2006/6

N2 - The title compound [Mn5(H2PO4)2 (PO4)2(H2O)4] was hydrothermally synthesized in the presence of calix[4]arene-p-tetrasulfonate. The title compound was structurally characterized by X-ray single crystal diffraction. It crystallizes in the monoclinic space group C2/c with a = 1.762 9(4) nm, b = 0.913 44(18) nm, c = 0.949 77(19) nm, β = 96.52(3)°, V = 1.519 5(5) nm3, Z = 4 and R1 = 0.028 3, and exhibits a three-dimensional framework and channel structure. It was proposed that calixarene can act as template during the formation of the title compound because calixarene can bind Mn2+ through second-sphere coordination.

AB - The title compound [Mn5(H2PO4)2 (PO4)2(H2O)4] was hydrothermally synthesized in the presence of calix[4]arene-p-tetrasulfonate. The title compound was structurally characterized by X-ray single crystal diffraction. It crystallizes in the monoclinic space group C2/c with a = 1.762 9(4) nm, b = 0.913 44(18) nm, c = 0.949 77(19) nm, β = 96.52(3)°, V = 1.519 5(5) nm3, Z = 4 and R1 = 0.028 3, and exhibits a three-dimensional framework and channel structure. It was proposed that calixarene can act as template during the formation of the title compound because calixarene can bind Mn2+ through second-sphere coordination.

KW - Calixarene

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Manganese phosphate

KW - Template

UR - https://www.scopus.com/pages/publications/33748443999

M3 - Article

AN - SCOPUS:33748443999

SN - 1004-0579

VL - 15

SP - 229

EP - 232

JO - Journal of Beijing Institute of Technology (English Edition)

JF - Journal of Beijing Institute of Technology (English Edition)

IS - 2

ER -

Hydrothermal synthesis of [Mn₅(H₂PO₄)₂ (PO₄)₂(H₂O)₄] templated by calixarene under mild conditions

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