Hydrothermal synthesis, crystal structure and properties of the cluster compound with a bi-capped pseudo-Keggin structure: [HN(C2H 5)3]3[N(C2H5) 3]2[Mo8IVMo4 VV2IVO38(PO4)]

Xiao Bing Cui; Zhi En Lin; Guo Yu Yang

Hydrothermal synthesis, crystal structure and properties of the cluster compound with a bi-capped pseudo-Keggin structure: [HN(C₂H ₅)₃]₃[N(C₂H₅) ₃]₂[Mo₈^IVMo₄ ^VV₂^IVO₃₈(PO₄)]

Xiao Bing Cui^*
, Zhi En Lin
, Guo Yu Yang

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

Abstract

The novel polyoxometalate, [HN(C₂H₅) ₃] ₃[N(C₂H₅) ₃] ₂[Mo ₈^IVMo₄^VV₂ ^IVO₃₈(PO₄)], was synthesized and characterized by elementary analysis, EPR, IR spectra and X-ray diffraction. The compound crystallizes in triclinic system, space group P1̄ with a = 1.41999(2) nm, b = 1.43467 (2) nm, c = 1.694610(10) nm, α = 95. 7250(10)°, β = 92. 2110(10)°, γ = 92.6060(10)°, V=3.42829(7)nm³, Z = 2, D_c=2.388g·cm^-3, M_r = 2465.10g·mol^-1, μ = 2.489mm^-1 F(000) = F(000)=2388, R₁= 0.084, wR₂ = 0.1461, S = 1.164. The heteropolyanion is a bi-capped pseudo-Keggin complex. CCDC: 186645.

Original language	English
Pages (from-to)	86-90
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	19
Issue number	1
Publication status	Published - 1 Jan 2003
Externally published	Yes

Keywords

Bi-capped pseudo-Keggin structure
Crystal structure
Hydrothermal synthesis
Polyoxometalate

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@article{75b4f51e500e4a61b7349c68bd16d239,

title = "Hydrothermal synthesis, crystal structure and properties of the cluster compound with a bi-capped pseudo-Keggin structure: [HN(C2H 5)3]3[N(C2H5) 3]2[Mo8IVMo4 VV2IVO38(PO4)]",

abstract = "The novel polyoxometalate, [HN(C2H5) 3] 3[N(C2H5) 3] 2[Mo 8IVMo4VV2 IVO38(PO4)], was synthesized and characterized by elementary analysis, EPR, IR spectra and X-ray diffraction. The compound crystallizes in triclinic system, space group P{\=1} with a = 1.41999(2) nm, b = 1.43467 (2) nm, c = 1.694610(10) nm, α = 95. 7250(10)°, β = 92. 2110(10)°, γ = 92.6060(10)°, V=3.42829(7)nm3, Z = 2, Dc=2.388g·cm-3, Mr = 2465.10g·mol-1, μ = 2.489mm-1 F(000) = F(000)=2388, R1= 0.084, wR2 = 0.1461, S = 1.164. The heteropolyanion is a bi-capped pseudo-Keggin complex. CCDC: 186645.",

keywords = "Bi-capped pseudo-Keggin structure, Crystal structure, Hydrothermal synthesis, Polyoxometalate",

author = "Cui, \{Xiao Bing\} and Lin, \{Zhi En\} and Yang, \{Guo Yu\}",

year = "2003",

month = jan,

day = "1",

language = "English",

volume = "19",

pages = "86--90",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "1",

}

TY - JOUR

T1 - Hydrothermal synthesis, crystal structure and properties of the cluster compound with a bi-capped pseudo-Keggin structure

T2 - [HN(C2H 5)3]3[N(C2H5) 3]2[Mo8IVMo4 VV2IVO38(PO4)]

AU - Cui, Xiao Bing

AU - Lin, Zhi En

AU - Yang, Guo Yu

PY - 2003/1/1

Y1 - 2003/1/1

N2 - The novel polyoxometalate, [HN(C2H5) 3] 3[N(C2H5) 3] 2[Mo 8IVMo4VV2 IVO38(PO4)], was synthesized and characterized by elementary analysis, EPR, IR spectra and X-ray diffraction. The compound crystallizes in triclinic system, space group P1̄ with a = 1.41999(2) nm, b = 1.43467 (2) nm, c = 1.694610(10) nm, α = 95. 7250(10)°, β = 92. 2110(10)°, γ = 92.6060(10)°, V=3.42829(7)nm3, Z = 2, Dc=2.388g·cm-3, Mr = 2465.10g·mol-1, μ = 2.489mm-1 F(000) = F(000)=2388, R1= 0.084, wR2 = 0.1461, S = 1.164. The heteropolyanion is a bi-capped pseudo-Keggin complex. CCDC: 186645.

AB - The novel polyoxometalate, [HN(C2H5) 3] 3[N(C2H5) 3] 2[Mo 8IVMo4VV2 IVO38(PO4)], was synthesized and characterized by elementary analysis, EPR, IR spectra and X-ray diffraction. The compound crystallizes in triclinic system, space group P1̄ with a = 1.41999(2) nm, b = 1.43467 (2) nm, c = 1.694610(10) nm, α = 95. 7250(10)°, β = 92. 2110(10)°, γ = 92.6060(10)°, V=3.42829(7)nm3, Z = 2, Dc=2.388g·cm-3, Mr = 2465.10g·mol-1, μ = 2.489mm-1 F(000) = F(000)=2388, R1= 0.084, wR2 = 0.1461, S = 1.164. The heteropolyanion is a bi-capped pseudo-Keggin complex. CCDC: 186645.

KW - Bi-capped pseudo-Keggin structure

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Polyoxometalate

UR - https://www.scopus.com/pages/publications/0141463808

M3 - Article

AN - SCOPUS:0141463808

SN - 1001-4861

VL - 19

SP - 86

EP - 90

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 1

ER -

Hydrothermal synthesis, crystal structure and properties of the cluster compound with a bi-capped pseudo-Keggin structure: [HN(C₂H ₅)₃]₃[N(C₂H₅) ₃]₂[Mo₈^IVMo₄ ^VV₂^IVO₃₈(PO₄)]

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