Hydrothermal Synthesis and Structure of [Ni(en)2V6O14]n

Qing Xin Zeng; Hong Fei Li; Ya Feng Li; Guo Yu Yang; Ji Qing Xu

Hydrothermal Synthesis and Structure of [Ni(en)₂V₆O₁₄]_n

Qing Xin Zeng
, Hong Fei Li
, Ya Feng Li
, Guo Yu Yang^*
, Ji Qing Xu

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter
CAS - Changchun Institute of Applied Chemistry
Jilin University

Research output: Contribution to journal › Article › peer-review

Abstract

A new complex [Ni (en)₂V₆O₁₄]_n was hydrothermally synthesized and characterized by 2-dimensional vanadium oxide framework pillared by Ni(en)₂ group. Single crystal X-ray analysis indicates that this compound crystallizes in monoclinic system, space group P2₁/c with a=0. 892 17(18) nm, b= 1. 711 1(3) nm, c=0. 662 73(13) nm, β=111. 58(3)° V=0. 940 8(3) nm³, Z=2, D_c=2. 501 g/cm³, R=0. 042 3, wR=0. 060 9, S=1. 006.

Original language	English
Pages (from-to)	2242
Number of pages	1
Journal	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume	23
Issue number	12
Publication status	Published - 2002
Externally published	Yes

Keywords

Crystal structure
Hydrothermal synthesis
Vanadium oxides

Cite this

@article{762f16c35c044240af3b246e369681ba,

title = "Hydrothermal Synthesis and Structure of [Ni(en)2V6O14]n",

abstract = "A new complex [Ni (en)2V6O14]n was hydrothermally synthesized and characterized by 2-dimensional vanadium oxide framework pillared by Ni(en)2 group. Single crystal X-ray analysis indicates that this compound crystallizes in monoclinic system, space group P21/c with a=0. 892 17(18) nm, b= 1. 711 1(3) nm, c=0. 662 73(13) nm, β=111. 58(3)° V=0. 940 8(3) nm3, Z=2, Dc=2. 501 g/cm3, R=0. 042 3, wR=0. 060 9, S=1. 006.",

keywords = "Crystal structure, Hydrothermal synthesis, Vanadium oxides",

author = "Zeng, \{Qing Xin\} and Li, \{Hong Fei\} and Li, \{Ya Feng\} and Yang, \{Guo Yu\} and Xu, \{Ji Qing\}",

year = "2002",

language = "English",

volume = "23",

pages = "2242",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "12",

}

TY - JOUR

T1 - Hydrothermal Synthesis and Structure of [Ni(en)2V6O14]n

AU - Zeng, Qing Xin

AU - Li, Hong Fei

AU - Li, Ya Feng

AU - Yang, Guo Yu

AU - Xu, Ji Qing

PY - 2002

Y1 - 2002

N2 - A new complex [Ni (en)2V6O14]n was hydrothermally synthesized and characterized by 2-dimensional vanadium oxide framework pillared by Ni(en)2 group. Single crystal X-ray analysis indicates that this compound crystallizes in monoclinic system, space group P21/c with a=0. 892 17(18) nm, b= 1. 711 1(3) nm, c=0. 662 73(13) nm, β=111. 58(3)° V=0. 940 8(3) nm3, Z=2, Dc=2. 501 g/cm3, R=0. 042 3, wR=0. 060 9, S=1. 006.

AB - A new complex [Ni (en)2V6O14]n was hydrothermally synthesized and characterized by 2-dimensional vanadium oxide framework pillared by Ni(en)2 group. Single crystal X-ray analysis indicates that this compound crystallizes in monoclinic system, space group P21/c with a=0. 892 17(18) nm, b= 1. 711 1(3) nm, c=0. 662 73(13) nm, β=111. 58(3)° V=0. 940 8(3) nm3, Z=2, Dc=2. 501 g/cm3, R=0. 042 3, wR=0. 060 9, S=1. 006.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Vanadium oxides

UR - https://www.scopus.com/pages/publications/0346674845

M3 - Article

AN - SCOPUS:0346674845

SN - 0251-0790

VL - 23

SP - 2242

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 12

ER -

Hydrothermal Synthesis and Structure of [Ni(en)₂V₆O₁₄]_n

Abstract

Keywords

Other files and links

Fingerprint

Cite this