Hydrothermal synthesis and structure of a novel two-dimensional complex: [Ni0.5(H2O)1.5{Ni(en)2} 3V18O42(Cl)]·3.5H2O

Shou Tian Zheng; Guo Yu Yang

Hydrothermal synthesis and structure of a novel two-dimensional complex: [Ni_0.5(H₂O)_1.5{Ni(en)₂} ₃V₁₈O₄₂(Cl)]·3.5H₂O

Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A novel two-dimensional compound [Ni_0.5(H₂O) _1.5{Ni(en)₂}₃V₁₈O ₄₂(Cl)]·3.5H₂O 1 has been hydrothermally synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction analysis. Crystal data for 1: monoclinic, space group C2/c with a = 12.824(3), b = 27.873(6), c = 21.092(4) Å, β = 92.93(3)°, V = 7529(3) Å³, Z = 4, D_c = 2.012 g/cm₃, M_r = 2280.56, F(000) = 4476 and μ = 3.092 mm^-1. The final R and wR are 0.0769 and 0.1783, respectively for 4203 observed reflections with I>2σ(I). The structure consists of [V ₁₈O₄₂(Cl)]^7- clusters linked by trans- {Ni(en)₂} groups into linear chains, while cis-{Ni(en)₂} groups provide the cross-linking adjacent chains to form a two-dimensional structure.

Original language	English
Pages (from-to)	252-256
Number of pages	5
Journal	Jiegou Huaxue
Volume	23
Issue number	3
Publication status	Published - 2004
Externally published	Yes

Keywords

Crystal structure
Hydrothermal synthesis
Nickel
Polyoxovanadate
Vanadium cluster

Cite this

@article{3c646766db4c414c804caa268110a8ba,

title = "Hydrothermal synthesis and structure of a novel two-dimensional complex: [Ni0.5(H2O)1.5\{Ni(en)2\} 3V18O42(Cl)]·3.5H2O",

abstract = "A novel two-dimensional compound [Ni0.5(H2O) 1.5\{Ni(en)2\}3V18O 42(Cl)]·3.5H2O 1 has been hydrothermally synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction analysis. Crystal data for 1: monoclinic, space group C2/c with a = 12.824(3), b = 27.873(6), c = 21.092(4) {\AA}, β = 92.93(3)°, V = 7529(3) {\AA}3, Z = 4, Dc = 2.012 g/cm3, Mr = 2280.56, F(000) = 4476 and μ = 3.092 mm-1. The final R and wR are 0.0769 and 0.1783, respectively for 4203 observed reflections with I>2σ(I). The structure consists of [V 18O42(Cl)]7- clusters linked by trans- \{Ni(en)2\} groups into linear chains, while cis-\{Ni(en)2\} groups provide the cross-linking adjacent chains to form a two-dimensional structure.",

keywords = "Crystal structure, Hydrothermal synthesis, Nickel, Polyoxovanadate, Vanadium cluster",

author = "Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2004",

language = "English",

volume = "23",

pages = "252--256",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "3",

}

TY - JOUR

T1 - Hydrothermal synthesis and structure of a novel two-dimensional complex

T2 - [Ni0.5(H2O)1.5{Ni(en)2} 3V18O42(Cl)]·3.5H2O

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004

Y1 - 2004

N2 - A novel two-dimensional compound [Ni0.5(H2O) 1.5{Ni(en)2}3V18O 42(Cl)]·3.5H2O 1 has been hydrothermally synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction analysis. Crystal data for 1: monoclinic, space group C2/c with a = 12.824(3), b = 27.873(6), c = 21.092(4) Å, β = 92.93(3)°, V = 7529(3) Å3, Z = 4, Dc = 2.012 g/cm3, Mr = 2280.56, F(000) = 4476 and μ = 3.092 mm-1. The final R and wR are 0.0769 and 0.1783, respectively for 4203 observed reflections with I>2σ(I). The structure consists of [V 18O42(Cl)]7- clusters linked by trans- {Ni(en)2} groups into linear chains, while cis-{Ni(en)2} groups provide the cross-linking adjacent chains to form a two-dimensional structure.

AB - A novel two-dimensional compound [Ni0.5(H2O) 1.5{Ni(en)2}3V18O 42(Cl)]·3.5H2O 1 has been hydrothermally synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction analysis. Crystal data for 1: monoclinic, space group C2/c with a = 12.824(3), b = 27.873(6), c = 21.092(4) Å, β = 92.93(3)°, V = 7529(3) Å3, Z = 4, Dc = 2.012 g/cm3, Mr = 2280.56, F(000) = 4476 and μ = 3.092 mm-1. The final R and wR are 0.0769 and 0.1783, respectively for 4203 observed reflections with I>2σ(I). The structure consists of [V 18O42(Cl)]7- clusters linked by trans- {Ni(en)2} groups into linear chains, while cis-{Ni(en)2} groups provide the cross-linking adjacent chains to form a two-dimensional structure.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Nickel

KW - Polyoxovanadate

KW - Vanadium cluster

UR - https://www.scopus.com/pages/publications/4644301826

M3 - Article

AN - SCOPUS:4644301826

SN - 0254-5861

VL - 23

SP - 252

EP - 256

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 3

ER -

Hydrothermal synthesis and structure of a novel two-dimensional complex: [Ni_0.5(H₂O)_1.5{Ni(en)₂} ₃V₁₈O₄₂(Cl)]·3.5H₂O

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