Hydrothermal synthesis and structure of A novel organic-inorganic hybrid polyoxotungstate: H5[Cu(en)2H2O]{Cu(en)2[P2W19O69(H2O)]} · 2.5H2en · 8H2O

Yong Chao Liu; Shou Tian Zheng; Guo Yu Yang

doi:10.1007/s10876-009-0237-6

Hydrothermal synthesis and structure of A novel organic-inorganic hybrid polyoxotungstate: H₅[Cu(en)₂H₂O]{Cu(en)₂[P₂W₁₉O₆₉(H₂O)]} · 2.5H₂en · 8H₂O

Yong Chao Liu
, Shou Tian Zheng
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A novel polyoxotungstate H₅[Cu(en)₂H₂O]{Cu(en)₂[P₂W₁₉O₆₉(H₂O)]} · 2.5H₂en · 8H₂O (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, elemental analysis, and single crystal X-ray structural analysis. Crystal data for 1: Triclinic, P-1, a = 12.673(6) Å, b = 20.147(10) Å, c = 20.514(11) Å, α = 110.432(7)°, β = 90.171(5)°, γ = 97.502(6)°, V = 4859(4) Å³, Z = 2. Compound 1 exhibits a 1D linear structure, in which the [Cu(en)₂]²⁺ ions act as the linkages of {P₂W₁₉} lacunary units.

Original language	English
Pages (from-to)	481-488
Number of pages	8
Journal	Journal of Cluster Science
Volume	20
Issue number	3
DOIs	https://doi.org/10.1007/s10876-009-0237-6
Publication status	Published - 2009
Externally published	Yes

Keywords

Copper
Crystal structure
Hydrothermal synthesis
Lacunary polyoxometalates
Organic-inorganic hybrid

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10.1007/s10876-009-0237-6

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@article{6b303a988180427ebaace0f0a53cf2ff,

title = "Hydrothermal synthesis and structure of A novel organic-inorganic hybrid polyoxotungstate: H5[Cu(en)2H2O]\{Cu(en)2[P2W19O69(H2O)]\} · 2.5H2en · 8H2O",

abstract = "A novel polyoxotungstate H5[Cu(en)2H2O]\{Cu(en)2[P2W19O69(H2O)]\} · 2.5H2en · 8H2O (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, elemental analysis, and single crystal X-ray structural analysis. Crystal data for 1: Triclinic, P-1, a = 12.673(6) {\AA}, b = 20.147(10) {\AA}, c = 20.514(11) {\AA}, α = 110.432(7)°, β = 90.171(5)°, γ = 97.502(6)°, V = 4859(4) {\AA}3, Z = 2. Compound 1 exhibits a 1D linear structure, in which the [Cu(en)2]2+ ions act as the linkages of \{P2W19\} lacunary units.",

keywords = "Copper, Crystal structure, Hydrothermal synthesis, Lacunary polyoxometalates, Organic-inorganic hybrid",

author = "Liu, \{Yong Chao\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2009",

doi = "10.1007/s10876-009-0237-6",

language = "English",

volume = "20",

pages = "481--488",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "3",

}

TY - JOUR

T1 - Hydrothermal synthesis and structure of A novel organic-inorganic hybrid polyoxotungstate

T2 - H5[Cu(en)2H2O]{Cu(en)2[P2W19O69(H2O)]} · 2.5H2en · 8H2O

AU - Liu, Yong Chao

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2009

Y1 - 2009

N2 - A novel polyoxotungstate H5[Cu(en)2H2O]{Cu(en)2[P2W19O69(H2O)]} · 2.5H2en · 8H2O (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, elemental analysis, and single crystal X-ray structural analysis. Crystal data for 1: Triclinic, P-1, a = 12.673(6) Å, b = 20.147(10) Å, c = 20.514(11) Å, α = 110.432(7)°, β = 90.171(5)°, γ = 97.502(6)°, V = 4859(4) Å3, Z = 2. Compound 1 exhibits a 1D linear structure, in which the [Cu(en)2]2+ ions act as the linkages of {P2W19} lacunary units.

AB - A novel polyoxotungstate H5[Cu(en)2H2O]{Cu(en)2[P2W19O69(H2O)]} · 2.5H2en · 8H2O (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, elemental analysis, and single crystal X-ray structural analysis. Crystal data for 1: Triclinic, P-1, a = 12.673(6) Å, b = 20.147(10) Å, c = 20.514(11) Å, α = 110.432(7)°, β = 90.171(5)°, γ = 97.502(6)°, V = 4859(4) Å3, Z = 2. Compound 1 exhibits a 1D linear structure, in which the [Cu(en)2]2+ ions act as the linkages of {P2W19} lacunary units.

KW - Copper

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Lacunary polyoxometalates

KW - Organic-inorganic hybrid

UR - https://www.scopus.com/pages/publications/70350026523

U2 - 10.1007/s10876-009-0237-6

DO - 10.1007/s10876-009-0237-6

M3 - Article

AN - SCOPUS:70350026523

SN - 1040-7278

VL - 20

SP - 481

EP - 488

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 3

ER -

Hydrothermal synthesis and structure of A novel organic-inorganic hybrid polyoxotungstate: H₅[Cu(en)₂H₂O]{Cu(en)₂[P₂W₁₉O₆₉(H₂O)]} · 2.5H₂en · 8H₂O

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