Hydrothermal synthesis and structural characterization of a tubular arsenic-vanadate: [Co II (2,2′-bpy)2]2[As III 8V IV 14O42(H 2O)]•H2O

Chun Mei Wang; Qing Xin Zeng; Jie Zhang; Guo Yu Yang

doi:10.1007/s10876-005-2716-8

Hydrothermal synthesis and structural characterization of a tubular arsenic-vanadate: [Co ^II (2,2′-bpy)₂]₂[As ^III ₈V ^IV ₁₄O₄₂(H ₂O)]•H₂O

Chun Mei Wang, Qing Xin Zeng, Jie Zhang, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The hydrothermal reaction of VOSO₄, As₂O₃, CoC₂O₄•2H₂O and 2,2′-bipy yields a novel arsenic-vanadate [Co^II(2,2′-bpy)₂] ₂[As^III ₈V^IV ₁₄O ₄₂(H₂O)]•H₂O (1), which is characterized by IR, elemental analysis, TGA, magnetic susceptibility and single crystal X-ray diffraction analysis. X-ray diffraction shows that compound 1 is the first example of tubular arsenic-vanadium cluster containing infinite {[Co(2,2′-bpy)₂]₂[As₈V₁₄O ₄₂(H₂O)]}_∞ chain constructed from [As₈V₁₄O₄₂(H₂O)] clusters interconnected through [Co(2,2-bpy)]²⁺ units. Crystal data: 1, orthorhombic, P 2₁2₁2₁, a=12.1401(2) Å, b=15.8722(1) Å, c=39.9533(5) Å, Z=4. Graphical Abstract: A novel polyoxoarsenicvanadate, [Co^II(2,2′-bipy)₂] ₂ [As^III ₈V^IV ₁₄O ₄₂(H₂O)]•H₂O, is depicted along with a tubular hybrid solid with a rhombic tube formed within the chain.

Original language	English
Pages (from-to)	65-76
Number of pages	12
Journal	Journal of Cluster Science
Volume	16
Issue number	1
DOIs	https://doi.org/10.1007/s10876-005-2716-8
Publication status	Published - Mar 2005
Externally published	Yes

Keywords

Arsenic
Cobalt
Crystal structure
Hydrothermal synthesis
Polyoxometalate
Vanadium

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10.1007/s10876-005-2716-8

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@article{31e5900e9c474b799ab3d7e96c9fd09b,

title = "Hydrothermal synthesis and structural characterization of a tubular arsenic-vanadate: [Co II (2,2′-bpy)2]2[As III 8V IV 14O42(H 2O)]•H2O",

abstract = "The hydrothermal reaction of VOSO4, As2O3, CoC2O4•2H2O and 2,2′-bipy yields a novel arsenic-vanadate [CoII(2,2′-bpy)2] 2[AsIII 8VIV 14O 42(H2O)]•H2O (1), which is characterized by IR, elemental analysis, TGA, magnetic susceptibility and single crystal X-ray diffraction analysis. X-ray diffraction shows that compound 1 is the first example of tubular arsenic-vanadium cluster containing infinite {[Co(2,2′-bpy)2]2[As8V14O 42(H2O)]}∞ chain constructed from [As8V14O42(H2O)] clusters interconnected through [Co(2,2-bpy)]2+ units. Crystal data: 1, orthorhombic, P 212121, a=12.1401(2) {\AA}, b=15.8722(1) {\AA}, c=39.9533(5) {\AA}, Z=4. Graphical Abstract: A novel polyoxoarsenicvanadate, [CoII(2,2′-bipy)2] 2 [AsIII 8VIV 14O 42(H2O)]•H2O, is depicted along with a tubular hybrid solid with a rhombic tube formed within the chain.",

keywords = "Arsenic, Cobalt, Crystal structure, Hydrothermal synthesis, Polyoxometalate, Vanadium",

author = "Wang, {Chun Mei} and Zeng, {Qing Xin} and Jie Zhang and Yang, {Guo Yu}",

year = "2005",

month = mar,

doi = "10.1007/s10876-005-2716-8",

language = "English",

volume = "16",

pages = "65--76",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "1",

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TY - JOUR

T1 - Hydrothermal synthesis and structural characterization of a tubular arsenic-vanadate

T2 - [Co II (2,2′-bpy)2]2[As III 8V IV 14O42(H 2O)]•H2O

AU - Wang, Chun Mei

AU - Zeng, Qing Xin

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2005/3

Y1 - 2005/3

N2 - The hydrothermal reaction of VOSO4, As2O3, CoC2O4•2H2O and 2,2′-bipy yields a novel arsenic-vanadate [CoII(2,2′-bpy)2] 2[AsIII 8VIV 14O 42(H2O)]•H2O (1), which is characterized by IR, elemental analysis, TGA, magnetic susceptibility and single crystal X-ray diffraction analysis. X-ray diffraction shows that compound 1 is the first example of tubular arsenic-vanadium cluster containing infinite {[Co(2,2′-bpy)2]2[As8V14O 42(H2O)]}∞ chain constructed from [As8V14O42(H2O)] clusters interconnected through [Co(2,2-bpy)]2+ units. Crystal data: 1, orthorhombic, P 212121, a=12.1401(2) Å, b=15.8722(1) Å, c=39.9533(5) Å, Z=4. Graphical Abstract: A novel polyoxoarsenicvanadate, [CoII(2,2′-bipy)2] 2 [AsIII 8VIV 14O 42(H2O)]•H2O, is depicted along with a tubular hybrid solid with a rhombic tube formed within the chain.

AB - The hydrothermal reaction of VOSO4, As2O3, CoC2O4•2H2O and 2,2′-bipy yields a novel arsenic-vanadate [CoII(2,2′-bpy)2] 2[AsIII 8VIV 14O 42(H2O)]•H2O (1), which is characterized by IR, elemental analysis, TGA, magnetic susceptibility and single crystal X-ray diffraction analysis. X-ray diffraction shows that compound 1 is the first example of tubular arsenic-vanadium cluster containing infinite {[Co(2,2′-bpy)2]2[As8V14O 42(H2O)]}∞ chain constructed from [As8V14O42(H2O)] clusters interconnected through [Co(2,2-bpy)]2+ units. Crystal data: 1, orthorhombic, P 212121, a=12.1401(2) Å, b=15.8722(1) Å, c=39.9533(5) Å, Z=4. Graphical Abstract: A novel polyoxoarsenicvanadate, [CoII(2,2′-bipy)2] 2 [AsIII 8VIV 14O 42(H2O)]•H2O, is depicted along with a tubular hybrid solid with a rhombic tube formed within the chain.

KW - Arsenic

KW - Cobalt

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Polyoxometalate

KW - Vanadium

UR - http://www.scopus.com/inward/record.url?scp=17644424335&partnerID=8YFLogxK

U2 - 10.1007/s10876-005-2716-8

DO - 10.1007/s10876-005-2716-8

M3 - Article

AN - SCOPUS:17644424335

SN - 1040-7278

VL - 16

SP - 65

EP - 76

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 1

ER -

Hydrothermal synthesis and structural characterization of a tubular arsenic-vanadate: [Co ^II (2,2′-bpy)₂]₂[As ^III ₈V ^IV ₁₄O₄₂(H ₂O)]•H₂O

Abstract

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