Hydrothermal Synthesis and Structural Characterization of a New Keggin-Type Tungstogermanate Containing Heterometallic 3d-4f Cubane Clusters

Wei Dong Wang; Xin Xiong Li; Wei Hui Fang; Guo Yu Yang

doi:10.1007/s10876-011-0351-0

Hydrothermal Synthesis and Structural Characterization of a New Keggin-Type Tungstogermanate Containing Heterometallic 3d-4f Cubane Clusters

Wei Dong Wang
, Xin Xiong Li
, Wei Hui Fang
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

A new Keggin-type 3d-4f heterometallic incorporated polyoxotungstate, {[Cu(en)₂(H₂O)][DyCu₃(en)₃(OH)₃(H₂O)₂(GeW₁₁O₃₉)]}₂·18H₂O (1) (en = ethylenediamine), has been hydrothermally synthesized and characterized by IR spectroscopy, TG, and single-crystal X-ray diffraction. Structure analysis revealed that the dimeric compound 1 contains {DyCu₃(OH)₃O} cubane fragments and represents the first tungstogermanate with heterometallic 3d-4f cubane cluster.

Original language	English
Pages (from-to)	87-95
Number of pages	9
Journal	Journal of Cluster Science
Volume	22
Issue number	1
DOIs	https://doi.org/10.1007/s10876-011-0351-0
Publication status	Published - Mar 2011
Externally published	Yes

Keywords

Germanate
Heterometallic cubane
Hydrothermal synthesis
Lacunary polyoxometalate

Access to Document

10.1007/s10876-011-0351-0

Cite this

@article{6170bbbe08ad4ed6a632b5833d9f6ba4,

title = "Hydrothermal Synthesis and Structural Characterization of a New Keggin-Type Tungstogermanate Containing Heterometallic 3d-4f Cubane Clusters",

abstract = "A new Keggin-type 3d-4f heterometallic incorporated polyoxotungstate, \{[Cu(en)2(H2O)][DyCu3(en)3(OH)3(H2O)2(GeW11O39)]\}2·18H2O (1) (en = ethylenediamine), has been hydrothermally synthesized and characterized by IR spectroscopy, TG, and single-crystal X-ray diffraction. Structure analysis revealed that the dimeric compound 1 contains \{DyCu3(OH)3O\} cubane fragments and represents the first tungstogermanate with heterometallic 3d-4f cubane cluster.",

keywords = "Germanate, Heterometallic cubane, Hydrothermal synthesis, Lacunary polyoxometalate",

author = "Wang, \{Wei Dong\} and Li, \{Xin Xiong\} and Fang, \{Wei Hui\} and Yang, \{Guo Yu\}",

year = "2011",

month = mar,

doi = "10.1007/s10876-011-0351-0",

language = "English",

volume = "22",

pages = "87--95",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "1",

}

TY - JOUR

T1 - Hydrothermal Synthesis and Structural Characterization of a New Keggin-Type Tungstogermanate Containing Heterometallic 3d-4f Cubane Clusters

AU - Wang, Wei Dong

AU - Li, Xin Xiong

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2011/3

Y1 - 2011/3

N2 - A new Keggin-type 3d-4f heterometallic incorporated polyoxotungstate, {[Cu(en)2(H2O)][DyCu3(en)3(OH)3(H2O)2(GeW11O39)]}2·18H2O (1) (en = ethylenediamine), has been hydrothermally synthesized and characterized by IR spectroscopy, TG, and single-crystal X-ray diffraction. Structure analysis revealed that the dimeric compound 1 contains {DyCu3(OH)3O} cubane fragments and represents the first tungstogermanate with heterometallic 3d-4f cubane cluster.

AB - A new Keggin-type 3d-4f heterometallic incorporated polyoxotungstate, {[Cu(en)2(H2O)][DyCu3(en)3(OH)3(H2O)2(GeW11O39)]}2·18H2O (1) (en = ethylenediamine), has been hydrothermally synthesized and characterized by IR spectroscopy, TG, and single-crystal X-ray diffraction. Structure analysis revealed that the dimeric compound 1 contains {DyCu3(OH)3O} cubane fragments and represents the first tungstogermanate with heterometallic 3d-4f cubane cluster.

KW - Germanate

KW - Heterometallic cubane

KW - Hydrothermal synthesis

KW - Lacunary polyoxometalate

UR - https://www.scopus.com/pages/publications/79952573319

U2 - 10.1007/s10876-011-0351-0

DO - 10.1007/s10876-011-0351-0

M3 - Article

AN - SCOPUS:79952573319

SN - 1040-7278

VL - 22

SP - 87

EP - 95

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 1

ER -

Hydrothermal Synthesis and Structural Characterization of a New Keggin-Type Tungstogermanate Containing Heterometallic 3d-4f Cubane Clusters

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this