Hydrothermal synthesis and crystal structure of [Ni(2,2′-bpy)3]MoO4·7.5H2O

Qing Xin Zeng; Guo Yu Yang; Ji Qing Xu

Hydrothermal synthesis and crystal structure of [Ni(2,2′-bpy)₃]MoO₄·7.5H₂O

Qing Xin Zeng^*, Guo Yu Yang, Ji Qing Xu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound [Ni(2,2′-bpy)₃]MoO₄·7.5H₂O was hydrothermally synthesized and its structure was determined by single-crystal X-ray analysis. This compound crystallizes in monoclinic crystal system, space group C2/c with a = 23.019(5), b = 13.967(3), c = 23.510(5) Å, β = 107.28(3)°, T = 293(2) K, V = 7217(3) Å³, Z = 8, D_c = 1.514 g/cm³, F(000) = 3384, M_r = 822.32, μ(MoKα) = 0.934mm^-1, R = 0.0357, wR = 0.0794 (w = 1/[σ²(F_o²) + (0.0407P)²] where P = (F_o² + 2F_c²)/3), S = 0.910, (Δ/σ)_max = 0.002, (Δρ)_max = 0.321 and (Δρ)_min = -0.625 e/Å³. The structure constructs from MoO₄^2- anions, Ni(2,2-bpy)₃²⁺ cations and crystallographic water molecules. There exists electrostatic interaction between the anions and cations. In addition, the anions interact with the crystallographic water molecules via hydrogen bonds and further form inorganic layer.

Original language	English
Pages (from-to)	336-340
Number of pages	5
Journal	Jiegou Huaxue
Volume	22
Issue number	3
Publication status	Published - 2003
Externally published	Yes

Keywords

Crystal structure
Hydrothermal synthesis
Metal oxides
Molybdenate
Molybdenum

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@article{88e7b69fa76940bea8df7c4f6af24bb1,

title = "Hydrothermal synthesis and crystal structure of [Ni(2,2′-bpy)3]MoO4·7.5H2O",

abstract = "The title compound [Ni(2,2′-bpy)3]MoO4·7.5H2O was hydrothermally synthesized and its structure was determined by single-crystal X-ray analysis. This compound crystallizes in monoclinic crystal system, space group C2/c with a = 23.019(5), b = 13.967(3), c = 23.510(5) {\AA}, β = 107.28(3)°, T = 293(2) K, V = 7217(3) {\AA}3, Z = 8, Dc = 1.514 g/cm3, F(000) = 3384, Mr = 822.32, μ(MoKα) = 0.934mm-1, R = 0.0357, wR = 0.0794 (w = 1/[σ2(Fo2) + (0.0407P)2] where P = (Fo2 + 2Fc2)/3), S = 0.910, (Δ/σ)max = 0.002, (Δρ)max = 0.321 and (Δρ)min = -0.625 e/{\AA}3. The structure constructs from MoO42- anions, Ni(2,2-bpy)32+ cations and crystallographic water molecules. There exists electrostatic interaction between the anions and cations. In addition, the anions interact with the crystallographic water molecules via hydrogen bonds and further form inorganic layer.",

keywords = "Crystal structure, Hydrothermal synthesis, Metal oxides, Molybdenate, Molybdenum",

author = "Zeng, {Qing Xin} and Yang, {Guo Yu} and Xu, {Ji Qing}",

year = "2003",

language = "English",

volume = "22",

pages = "336--340",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "3",

}

TY - JOUR

T1 - Hydrothermal synthesis and crystal structure of [Ni(2,2′-bpy)3]MoO4·7.5H2O

AU - Zeng, Qing Xin

AU - Yang, Guo Yu

AU - Xu, Ji Qing

PY - 2003

Y1 - 2003

N2 - The title compound [Ni(2,2′-bpy)3]MoO4·7.5H2O was hydrothermally synthesized and its structure was determined by single-crystal X-ray analysis. This compound crystallizes in monoclinic crystal system, space group C2/c with a = 23.019(5), b = 13.967(3), c = 23.510(5) Å, β = 107.28(3)°, T = 293(2) K, V = 7217(3) Å3, Z = 8, Dc = 1.514 g/cm3, F(000) = 3384, Mr = 822.32, μ(MoKα) = 0.934mm-1, R = 0.0357, wR = 0.0794 (w = 1/[σ2(Fo2) + (0.0407P)2] where P = (Fo2 + 2Fc2)/3), S = 0.910, (Δ/σ)max = 0.002, (Δρ)max = 0.321 and (Δρ)min = -0.625 e/Å3. The structure constructs from MoO42- anions, Ni(2,2-bpy)32+ cations and crystallographic water molecules. There exists electrostatic interaction between the anions and cations. In addition, the anions interact with the crystallographic water molecules via hydrogen bonds and further form inorganic layer.

AB - The title compound [Ni(2,2′-bpy)3]MoO4·7.5H2O was hydrothermally synthesized and its structure was determined by single-crystal X-ray analysis. This compound crystallizes in monoclinic crystal system, space group C2/c with a = 23.019(5), b = 13.967(3), c = 23.510(5) Å, β = 107.28(3)°, T = 293(2) K, V = 7217(3) Å3, Z = 8, Dc = 1.514 g/cm3, F(000) = 3384, Mr = 822.32, μ(MoKα) = 0.934mm-1, R = 0.0357, wR = 0.0794 (w = 1/[σ2(Fo2) + (0.0407P)2] where P = (Fo2 + 2Fc2)/3), S = 0.910, (Δ/σ)max = 0.002, (Δρ)max = 0.321 and (Δρ)min = -0.625 e/Å3. The structure constructs from MoO42- anions, Ni(2,2-bpy)32+ cations and crystallographic water molecules. There exists electrostatic interaction between the anions and cations. In addition, the anions interact with the crystallographic water molecules via hydrogen bonds and further form inorganic layer.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Metal oxides

KW - Molybdenate

KW - Molybdenum

UR - http://www.scopus.com/inward/record.url?scp=0042592905&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0042592905

SN - 0254-5861

VL - 22

SP - 336

EP - 340

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 3

ER -

Hydrothermal synthesis and crystal structure of [Ni(2,2′-bpy)₃]MoO₄·7.5H₂O

Abstract

Keywords

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