Hydrothermal synthesis and crystal structure of [H4As 8V14O42(H2O)]·6H2O

Xiao Bing Cui; Ji Qing Xu; Guang Hua Li; Zhan Shi; Hong Ding; Guo Yu Yang

Hydrothermal synthesis and crystal structure of [H₄As ₈V₁₄O₄₂(H₂O)]·6H₂O

Xiao Bing Cui
, Ji Qing Xu
, Guang Hua Li
, Zhan Shi
, Hong Ding
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter
Jilin University
Nanjing University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound [H₄As₈V₁₄O ₄₂(H₂O)]·6H₂O 1 has been synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis. It crystallizes in trigonal, space group R3c with a = b = 36.447(6), c = 21.485(5) Å, V = 24717(8) Å³, Z = 18, M_r = 2114.66, Dc = 2.557g/cm³, F(000) = 17928, μ = 7.149 mm ^-1, R = 0.0792 and wR = 0.1265. The [H₄As ₈V₁₄O₄₂- (H₂O)] cluster consists of fourteen VO₅ square pyramids linked by four As₂O ₅ handle-like units.

Original language	English
Pages (from-to)	1138-1142
Number of pages	5
Journal	Jiegou Huaxue
Volume	23
Issue number	10
Publication status	Published - 2004
Externally published	Yes

Keywords

Arsenic-vanadium cluster
Crystal structure
Hydrogen bond
Hydrothermal synthesis
Polyoxometalate

Cite this

@article{e14cbb0c295c41318c9b9b334b698e22,

title = "Hydrothermal synthesis and crystal structure of [H4As 8V14O42(H2O)]·6H2O",

abstract = "The title compound [H4As8V14O 42(H2O)]·6H2O 1 has been synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis. It crystallizes in trigonal, space group R3c with a = b = 36.447(6), c = 21.485(5) {\AA}, V = 24717(8) {\AA}3, Z = 18, Mr = 2114.66, Dc = 2.557g/cm3, F(000) = 17928, μ = 7.149 mm -1, R = 0.0792 and wR = 0.1265. The [H4As 8V14O42- (H2O)] cluster consists of fourteen VO5 square pyramids linked by four As2O 5 handle-like units.",

keywords = "Arsenic-vanadium cluster, Crystal structure, Hydrogen bond, Hydrothermal synthesis, Polyoxometalate",

author = "Cui, \{Xiao Bing\} and Xu, \{Ji Qing\} and Li, \{Guang Hua\} and Zhan Shi and Hong Ding and Yang, \{Guo Yu\}",

year = "2004",

language = "English",

volume = "23",

pages = "1138--1142",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "10",

}

TY - JOUR

T1 - Hydrothermal synthesis and crystal structure of [H4As 8V14O42(H2O)]·6H2O

AU - Cui, Xiao Bing

AU - Xu, Ji Qing

AU - Li, Guang Hua

AU - Shi, Zhan

AU - Ding, Hong

AU - Yang, Guo Yu

PY - 2004

Y1 - 2004

N2 - The title compound [H4As8V14O 42(H2O)]·6H2O 1 has been synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis. It crystallizes in trigonal, space group R3c with a = b = 36.447(6), c = 21.485(5) Å, V = 24717(8) Å3, Z = 18, Mr = 2114.66, Dc = 2.557g/cm3, F(000) = 17928, μ = 7.149 mm -1, R = 0.0792 and wR = 0.1265. The [H4As 8V14O42- (H2O)] cluster consists of fourteen VO5 square pyramids linked by four As2O 5 handle-like units.

AB - The title compound [H4As8V14O 42(H2O)]·6H2O 1 has been synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis. It crystallizes in trigonal, space group R3c with a = b = 36.447(6), c = 21.485(5) Å, V = 24717(8) Å3, Z = 18, Mr = 2114.66, Dc = 2.557g/cm3, F(000) = 17928, μ = 7.149 mm -1, R = 0.0792 and wR = 0.1265. The [H4As 8V14O42- (H2O)] cluster consists of fourteen VO5 square pyramids linked by four As2O 5 handle-like units.

KW - Arsenic-vanadium cluster

KW - Crystal structure

KW - Hydrogen bond

KW - Hydrothermal synthesis

KW - Polyoxometalate

UR - https://www.scopus.com/pages/publications/15044349831

M3 - Article

AN - SCOPUS:15044349831

SN - 0254-5861

VL - 23

SP - 1138

EP - 1142

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 10

ER -

Hydrothermal synthesis and crystal structure of [H₄As ₈V₁₄O₄₂(H₂O)]·6H₂O

Abstract

Keywords

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