Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)3]4[MoV5Mo VI5VIV6O40(PO 4)]2 · 4H2O Containing Double Tetracapped Pseudo-Keggin Cluster Anions

Qing Xin Zeng; Gao Meng Lü; Ya Feng Li; Guo Yu Yang; Ji Qing Xu

Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)₃]₄[Mo^V₅Mo ^VI₅V^IV₆O₄₀(PO ₄)]₂ · 4H₂O Containing Double Tetracapped Pseudo-Keggin Cluster Anions

Qing Xin Zeng
, Gao Meng Lü
, Ya Feng Li
, Guo Yu Yang^*
, Ji Qing Xu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound [Co(2, 2-bipy)₃]₄ [Mo₁₀V₆O₄₀(PO₄)]₂ · 4H₂O was synthesized by hydrothermal method and its structure was determined with-single crystal X-ray analysis. The cluster anion is double tetracapped Pseudo-Keggin cluster anions. The crystal is triclinic, space group P-1 with a= 1.316 5(3) nm, 6=1.438 2(3) nm, c=2.764 4(6) nm, a=79.51°, β=89.95°, γ=68.89°, V= 4.789 3(17) nm³, Z=1, D_c=2.176 g/cm³, R=0.075 5, wR=0.205 3, S=0.995.

Original language	English
Pages (from-to)	1856
Number of pages	1
Journal	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume	23
Issue number	10
Publication status	Published - Oct 2002
Externally published	Yes

Keywords

Crystal structure
Hydrothermal synthesis
Pseudo-Keggin

Cite this

@article{59bb8558254e4822a2292cc16704556d,

title = "Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)3]4[MoV5Mo VI5VIV6O40(PO 4)]2 · 4H2O Containing Double Tetracapped Pseudo-Keggin Cluster Anions",

abstract = "The title compound [Co(2, 2-bipy)3]4 [Mo10V6O40(PO4)]2 · 4H2O was synthesized by hydrothermal method and its structure was determined with-single crystal X-ray analysis. The cluster anion is double tetracapped Pseudo-Keggin cluster anions. The crystal is triclinic, space group P-1 with a= 1.316 5(3) nm, 6=1.438 2(3) nm, c=2.764 4(6) nm, a=79.51°, β=89.95°, γ=68.89°, V= 4.789 3(17) nm3, Z=1, Dc=2.176 g/cm3, R=0.075 5, wR=0.205 3, S=0.995.",

keywords = "Crystal structure, Hydrothermal synthesis, Pseudo-Keggin",

author = "Zeng, \{Qing Xin\} and L{\"u}, \{Gao Meng\} and Li, \{Ya Feng\} and Yang, \{Guo Yu\} and Xu, \{Ji Qing\}",

year = "2002",

month = oct,

language = "English",

volume = "23",

pages = "1856",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "10",

}

Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)₃]₄[Mo^V₅Mo ^VI₅V^IV₆O₄₀(PO ₄)]₂ · 4H₂O Containing Double Tetracapped Pseudo-Keggin Cluster Anions. / Zeng, Qing Xin; Lü, Gao Meng; Li, Ya Feng et al.
In: Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, Vol. 23, No. 10, 10.2002, p. 1856.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)3]4[MoV5Mo VI5VIV6O40(PO 4)]2 · 4H2O Containing Double Tetracapped Pseudo-Keggin Cluster Anions

AU - Zeng, Qing Xin

AU - Lü, Gao Meng

AU - Li, Ya Feng

AU - Yang, Guo Yu

AU - Xu, Ji Qing

PY - 2002/10

Y1 - 2002/10

N2 - The title compound [Co(2, 2-bipy)3]4 [Mo10V6O40(PO4)]2 · 4H2O was synthesized by hydrothermal method and its structure was determined with-single crystal X-ray analysis. The cluster anion is double tetracapped Pseudo-Keggin cluster anions. The crystal is triclinic, space group P-1 with a= 1.316 5(3) nm, 6=1.438 2(3) nm, c=2.764 4(6) nm, a=79.51°, β=89.95°, γ=68.89°, V= 4.789 3(17) nm3, Z=1, Dc=2.176 g/cm3, R=0.075 5, wR=0.205 3, S=0.995.

AB - The title compound [Co(2, 2-bipy)3]4 [Mo10V6O40(PO4)]2 · 4H2O was synthesized by hydrothermal method and its structure was determined with-single crystal X-ray analysis. The cluster anion is double tetracapped Pseudo-Keggin cluster anions. The crystal is triclinic, space group P-1 with a= 1.316 5(3) nm, 6=1.438 2(3) nm, c=2.764 4(6) nm, a=79.51°, β=89.95°, γ=68.89°, V= 4.789 3(17) nm3, Z=1, Dc=2.176 g/cm3, R=0.075 5, wR=0.205 3, S=0.995.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Pseudo-Keggin

UR - https://www.scopus.com/pages/publications/0347269237

M3 - Article

AN - SCOPUS:0347269237

SN - 0251-0790

VL - 23

SP - 1856

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 10

ER -

Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)₃]₄[Mo^V₅Mo ^VI₅V^IV₆O₄₀(PO ₄)]₂ · 4H₂O Containing Double Tetracapped Pseudo-Keggin Cluster Anions

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