Hydrothermal synthesis and crystal structure of a new dinuclear copper complex: [Cu2(Ophen)2]·2H2O (HOphen=2-Hydroxy-1,10-phenanthroline)

Chang Wen Hu; Chun Xiu Wang; Hui Li; Yan Ting He; Yun Gong

Hydrothermal synthesis and crystal structure of a new dinuclear copper complex: [Cu₂(Ophen)₂]·2H₂O (HOphen=2-Hydroxy-1,10-phenanthroline)

Chang Wen Hu^*
, Chun Xiu Wang
, Hui Li
, Yan Ting He
, Yun Gong

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

A new dinuclear copper complex: [Cu₂(Ophen)₂]·2H₂O (HOphen=2-hydroxy-1,10-phenanthroline) was hydrothermally synthesized and its structure characterized through IR spectra and single crystal X-ray diffraction analysis. Crystal data: Orthorhombic, α=0.3842(5) nm, b=1.913(3) nm, c=2.691(3) nm, α=β=γ=90.00°, Z=2, V=1.978(4) nm³, D^c=1.344 mg/m3, R₁=0.0839, wR₁=0.1471. The ligand 2-hydroxy-1,10-phenanthroline comes from the hydroxylation of phenanthroline. There are two solvent water molecules in the compound.

Original language	English
Pages (from-to)	1103-1105+1112
Journal	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
Volume	25
Issue number	12
Publication status	Published - Dec 2005

Keywords

Crystal structure
Cu(I) complex
Hydrothermal synthesis
Hydroxylation of phenanthroline

Cite this

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title = "Hydrothermal synthesis and crystal structure of a new dinuclear copper complex: [Cu2(Ophen)2]·2H2O (HOphen=2-Hydroxy-1,10-phenanthroline)",

abstract = "A new dinuclear copper complex: [Cu2(Ophen)2]·2H2O (HOphen=2-hydroxy-1,10-phenanthroline) was hydrothermally synthesized and its structure characterized through IR spectra and single crystal X-ray diffraction analysis. Crystal data: Orthorhombic, α=0.3842(5) nm, b=1.913(3) nm, c=2.691(3) nm, α=β=γ=90.00°, Z=2, V=1.978(4) nm3, Dc=1.344 mg/m3, R1=0.0839, wR1=0.1471. The ligand 2-hydroxy-1,10-phenanthroline comes from the hydroxylation of phenanthroline. There are two solvent water molecules in the compound.",

keywords = "Crystal structure, Cu(I) complex, Hydrothermal synthesis, Hydroxylation of phenanthroline",

author = "Hu, \{Chang Wen\} and Wang, \{Chun Xiu\} and Hui Li and He, \{Yan Ting\} and Yun Gong",

year = "2005",

month = dec,

language = "English",

volume = "25",

pages = "1103--1105+1112",

journal = "Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology",

issn = "1001-0645",

publisher = "Beijing Institute of Technology",

number = "12",

}

Hydrothermal synthesis and crystal structure of a new dinuclear copper complex: [Cu₂(Ophen)₂]·2H₂O (HOphen=2-Hydroxy-1,10-phenanthroline). / Hu, Chang Wen; Wang, Chun Xiu; Li, Hui et al.
In: Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology, Vol. 25, No. 12, 12.2005, p. 1103-1105+1112.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Hydrothermal synthesis and crystal structure of a new dinuclear copper complex

T2 - [Cu2(Ophen)2]·2H2O (HOphen=2-Hydroxy-1,10-phenanthroline)

AU - Hu, Chang Wen

AU - Wang, Chun Xiu

AU - Li, Hui

AU - He, Yan Ting

AU - Gong, Yun

PY - 2005/12

Y1 - 2005/12

N2 - A new dinuclear copper complex: [Cu2(Ophen)2]·2H2O (HOphen=2-hydroxy-1,10-phenanthroline) was hydrothermally synthesized and its structure characterized through IR spectra and single crystal X-ray diffraction analysis. Crystal data: Orthorhombic, α=0.3842(5) nm, b=1.913(3) nm, c=2.691(3) nm, α=β=γ=90.00°, Z=2, V=1.978(4) nm3, Dc=1.344 mg/m3, R1=0.0839, wR1=0.1471. The ligand 2-hydroxy-1,10-phenanthroline comes from the hydroxylation of phenanthroline. There are two solvent water molecules in the compound.

AB - A new dinuclear copper complex: [Cu2(Ophen)2]·2H2O (HOphen=2-hydroxy-1,10-phenanthroline) was hydrothermally synthesized and its structure characterized through IR spectra and single crystal X-ray diffraction analysis. Crystal data: Orthorhombic, α=0.3842(5) nm, b=1.913(3) nm, c=2.691(3) nm, α=β=γ=90.00°, Z=2, V=1.978(4) nm3, Dc=1.344 mg/m3, R1=0.0839, wR1=0.1471. The ligand 2-hydroxy-1,10-phenanthroline comes from the hydroxylation of phenanthroline. There are two solvent water molecules in the compound.

KW - Crystal structure

KW - Cu(I) complex

KW - Hydrothermal synthesis

KW - Hydroxylation of phenanthroline

UR - https://www.scopus.com/pages/publications/33644837874

M3 - Article

AN - SCOPUS:33644837874

SN - 1001-0645

VL - 25

SP - 1103-1105+1112

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - 12

ER -

Hydrothermal synthesis and crystal structure of a new dinuclear copper complex: [Cu₂(Ophen)₂]·2H₂O (HOphen=2-Hydroxy-1,10-phenanthroline)

Abstract

Keywords

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