Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type Polyoxometalate

Xin Xiong Li; Wei Hui Fang; Guo Yu Yang

doi:10.1007/s10876-010-0340-8

Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type Polyoxometalate

Xin Xiong Li, Wei Hui Fang, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A new 2-D organic-inorganic hybrid Wells-Dawson-Type polyoxotungstate K[Cu(Im)₂]₆P₂W₁₈O₆₂·2H₂O·(OH) (Im = Imidazole) (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, TG, and single crystal X-ray structural analysis. Crystal data for 1: triclinic, P-1, a = 15. 3676(12) Å, b = 15. 5059(14) Å, c = 24. 6437(19) Å, α = 98. 088(2)°, β = 96. 930(2)°, γ = 119. 312(2)°, Z = 2. Single crystal X-ray structural analysis reveals that the [P₂W₁₈O₆₂]^6- polyoxoanion is linked by [Cu(Im)₂]⁺ cation to form a 1-D chain along the a axis which is connected by K⁺ cation down the c axis to form a 2-D layer.

Original language	English
Pages (from-to)	803-811
Number of pages	9
Journal	Journal of Cluster Science
Volume	21
Issue number	4
DOIs	https://doi.org/10.1007/s10876-010-0340-8
Publication status	Published - Dec 2010
Externally published	Yes

Keywords

Copper
Crystal structure
Hydrothermal synthesis
Organic-inorganic hybrid
Polyoxometalates
Wells-Dawson

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10.1007/s10876-010-0340-8

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title = "Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type Polyoxometalate",

abstract = "A new 2-D organic-inorganic hybrid Wells-Dawson-Type polyoxotungstate K[Cu(Im)2]6P2W18O62·2H2O·(OH) (Im = Imidazole) (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, TG, and single crystal X-ray structural analysis. Crystal data for 1: triclinic, P-1, a = 15. 3676(12) {\AA}, b = 15. 5059(14) {\AA}, c = 24. 6437(19) {\AA}, α = 98. 088(2)°, β = 96. 930(2)°, γ = 119. 312(2)°, Z = 2. Single crystal X-ray structural analysis reveals that the [P2W18O62]6- polyoxoanion is linked by [Cu(Im)2]+ cation to form a 1-D chain along the a axis which is connected by K+ cation down the c axis to form a 2-D layer.",

keywords = "Copper, Crystal structure, Hydrothermal synthesis, Organic-inorganic hybrid, Polyoxometalates, Wells-Dawson",

author = "Li, {Xin Xiong} and Fang, {Wei Hui} and Yang, {Guo Yu}",

year = "2010",

month = dec,

doi = "10.1007/s10876-010-0340-8",

language = "English",

volume = "21",

pages = "803--811",

journal = "Journal of Cluster Science",

issn = "1040-7278",

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T1 - Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type Polyoxometalate

AU - Li, Xin Xiong

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2010/12

Y1 - 2010/12

N2 - A new 2-D organic-inorganic hybrid Wells-Dawson-Type polyoxotungstate K[Cu(Im)2]6P2W18O62·2H2O·(OH) (Im = Imidazole) (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, TG, and single crystal X-ray structural analysis. Crystal data for 1: triclinic, P-1, a = 15. 3676(12) Å, b = 15. 5059(14) Å, c = 24. 6437(19) Å, α = 98. 088(2)°, β = 96. 930(2)°, γ = 119. 312(2)°, Z = 2. Single crystal X-ray structural analysis reveals that the [P2W18O62]6- polyoxoanion is linked by [Cu(Im)2]+ cation to form a 1-D chain along the a axis which is connected by K+ cation down the c axis to form a 2-D layer.

AB - A new 2-D organic-inorganic hybrid Wells-Dawson-Type polyoxotungstate K[Cu(Im)2]6P2W18O62·2H2O·(OH) (Im = Imidazole) (1) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, TG, and single crystal X-ray structural analysis. Crystal data for 1: triclinic, P-1, a = 15. 3676(12) Å, b = 15. 5059(14) Å, c = 24. 6437(19) Å, α = 98. 088(2)°, β = 96. 930(2)°, γ = 119. 312(2)°, Z = 2. Single crystal X-ray structural analysis reveals that the [P2W18O62]6- polyoxoanion is linked by [Cu(Im)2]+ cation to form a 1-D chain along the a axis which is connected by K+ cation down the c axis to form a 2-D layer.

KW - Copper

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Organic-inorganic hybrid

KW - Polyoxometalates

KW - Wells-Dawson

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DO - 10.1007/s10876-010-0340-8

M3 - Article

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SN - 1040-7278

VL - 21

SP - 803

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JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 4

ER -

Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic-Inorganic Hybrid Wells-Dawson-Type Polyoxometalate

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Keywords

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