Hydrothermal synthesis and characterization of [HN(C2H 5)3]4[Mov3Mo VI6VIV7O40(PO 4)]·2N(C2H5)3

Xiao Bing Cui; Shou Tian Zheng; Guo Yu Yang

Hydrothermal synthesis and characterization of [HN(C₂H ₅)₃]₄[Mo^v₃Mo ^VI₆V^IV₇O₄₀(PO ₄)]·2N(C₂H₅)₃

Xiao Bing Cui^*, Shou Tian Zheng, Guo Yu Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The novel molybdovanadophosphate [HN(C₂H₅) ₃]₄[Mo^V₃Mo_VIV ^IVO₄₀(PO₄)]·2N(C₂H ₅)₃ was synthesized and characterized by elemental analysis, EPR, IR spectra and X-ray diffraction. The compound crystallizes in monoclinic, space group P2₁/n with a = 14.0841(3), b = 14.2505(3), c = 19.6089(3) Å, β = 94.213(1)°, V = 3925.0(1) Å³, Z = 2, D_c = 2.171 g/cm³, M _r = 2566.18, μ = 2.284 mm^-1, F(000) = 2516, R = 0.0477 and wR = 0.0945. The heteropolyanion has a novel hexadecametal cage [Mo ^V₃Mo^VI₆V^IV ₇O₄₀(PO₄)]^4- which encloses a disorder PO₄^3- guest.

Original language	English
Pages (from-to)	95-99
Number of pages	5
Journal	Jiegou Huaxue
Volume	23
Issue number	1
Publication status	Published - 2004
Externally published	Yes

Keywords

Crystal structure
Hexadecametal cage
Hydrothermal synthesis

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@article{6ca3dbcdb73749b18a43f8953e0f05b5,

title = "Hydrothermal synthesis and characterization of [HN(C2H 5)3]4[Mov3Mo VI6VIV7O40(PO 4)]·2N(C2H5)3",

abstract = "The novel molybdovanadophosphate [HN(C2H5) 3]4[MoV3MoVIV IVO40(PO4)]·2N(C2H 5)3 was synthesized and characterized by elemental analysis, EPR, IR spectra and X-ray diffraction. The compound crystallizes in monoclinic, space group P21/n with a = 14.0841(3), b = 14.2505(3), c = 19.6089(3) {\AA}, β = 94.213(1)°, V = 3925.0(1) {\AA}3, Z = 2, Dc = 2.171 g/cm3, M r = 2566.18, μ = 2.284 mm-1, F(000) = 2516, R = 0.0477 and wR = 0.0945. The heteropolyanion has a novel hexadecametal cage [Mo V3MoVI6VIV 7O40(PO4)]4- which encloses a disorder PO43- guest.",

keywords = "Crystal structure, Hexadecametal cage, Hydrothermal synthesis",

author = "Cui, {Xiao Bing} and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2004",

language = "English",

volume = "23",

pages = "95--99",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "1",

}

TY - JOUR

T1 - Hydrothermal synthesis and characterization of [HN(C2H 5)3]4[Mov3Mo VI6VIV7O40(PO 4)]·2N(C2H5)3

AU - Cui, Xiao Bing

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004

Y1 - 2004

N2 - The novel molybdovanadophosphate [HN(C2H5) 3]4[MoV3MoVIV IVO40(PO4)]·2N(C2H 5)3 was synthesized and characterized by elemental analysis, EPR, IR spectra and X-ray diffraction. The compound crystallizes in monoclinic, space group P21/n with a = 14.0841(3), b = 14.2505(3), c = 19.6089(3) Å, β = 94.213(1)°, V = 3925.0(1) Å3, Z = 2, Dc = 2.171 g/cm3, M r = 2566.18, μ = 2.284 mm-1, F(000) = 2516, R = 0.0477 and wR = 0.0945. The heteropolyanion has a novel hexadecametal cage [Mo V3MoVI6VIV 7O40(PO4)]4- which encloses a disorder PO43- guest.

AB - The novel molybdovanadophosphate [HN(C2H5) 3]4[MoV3MoVIV IVO40(PO4)]·2N(C2H 5)3 was synthesized and characterized by elemental analysis, EPR, IR spectra and X-ray diffraction. The compound crystallizes in monoclinic, space group P21/n with a = 14.0841(3), b = 14.2505(3), c = 19.6089(3) Å, β = 94.213(1)°, V = 3925.0(1) Å3, Z = 2, Dc = 2.171 g/cm3, M r = 2566.18, μ = 2.284 mm-1, F(000) = 2516, R = 0.0477 and wR = 0.0945. The heteropolyanion has a novel hexadecametal cage [Mo V3MoVI6VIV 7O40(PO4)]4- which encloses a disorder PO43- guest.

KW - Crystal structure

KW - Hexadecametal cage

KW - Hydrothermal synthesis

UR - http://www.scopus.com/inward/record.url?scp=2442557893&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:2442557893

SN - 0254-5861

VL - 23

SP - 95

EP - 99

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 1

ER -

Hydrothermal synthesis and characterization of [HN(C₂H ₅)₃]₄[Mo^v₃Mo ^VI₆V^IV₇O₄₀(PO ₄)]·2N(C₂H₅)₃

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