Hydrothermal synthesis and characterization of a novel two-dimensional framework materials constructed from the polyoxometalates and coordination groups: [As8IIIV14IVO42 (CO3)][Cu(en)2]3·10H2O

Xiao Bing Cui; Yan Qiong Sun; Guo Yu Yang

doi:10.1016/S1387-7003(02)00740-2

Hydrothermal synthesis and characterization of a novel two-dimensional framework materials constructed from the polyoxometalates and coordination groups: [As₈^IIIV₁₄^IVO₄₂ (CO₃)][Cu(en)₂]₃·10H₂O

Xiao Bing Cui
, Yan Qiong Sun
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

A new compound [As₈^IIIV₁₄^IVO₄₂ (CO₃)][Cu(en)₂]₃·10H₂O (1) has been synthesized from V₂O₅, As₂O₃, CuCl₂·2H₂O, en and H₂C₂O4·2H₂O in aqueous solution using the hydrothermal metho d and characterized by single-crystal X-ray diffraction analysis. X-ray crystallography reveals that 1 is a novel two-dimensional framework material constructed from the mixed As/V polyoxometalates and coordination groups.

Original language	English
Pages (from-to)	259-261
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	3
DOIs	https://doi.org/10.1016/S1387-7003(02)00740-2
Publication status	Published - 1 Mar 2003
Externally published	Yes

Keywords

As/V/O polyoxometalates
Coordination groups
Crystal structure
Hydrothermal synthesis
Two-dimensional structure

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10.1016/S1387-7003(02)00740-2

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title = "Hydrothermal synthesis and characterization of a novel two-dimensional framework materials constructed from the polyoxometalates and coordination groups: [As8IIIV14IVO42 (CO3)][Cu(en)2]3·10H2O",

abstract = "A new compound [As8IIIV14IVO42 (CO3)][Cu(en)2]3·10H2O (1) has been synthesized from V2O5, As2O3, CuCl2·2H2O, en and H2C2O4·2H2O in aqueous solution using the hydrothermal metho d and characterized by single-crystal X-ray diffraction analysis. X-ray crystallography reveals that 1 is a novel two-dimensional framework material constructed from the mixed As/V polyoxometalates and coordination groups.",

keywords = "As/V/O polyoxometalates, Coordination groups, Crystal structure, Hydrothermal synthesis, Two-dimensional structure",

author = "Cui, \{Xiao Bing\} and Sun, \{Yan Qiong\} and Yang, \{Guo Yu\}",

year = "2003",

month = mar,

day = "1",

doi = "10.1016/S1387-7003(02)00740-2",

language = "English",

volume = "6",

pages = "259--261",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "3",

}

Hydrothermal synthesis and characterization of a novel two-dimensional framework materials constructed from the polyoxometalates and coordination groups: [As₈^IIIV₁₄^IVO₄₂ (CO₃)][Cu(en)₂]₃·10H₂O. / Cui, Xiao Bing; Sun, Yan Qiong; Yang, Guo Yu.
In: Inorganic Chemistry Communications, Vol. 6, No. 3, 01.03.2003, p. 259-261.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Hydrothermal synthesis and characterization of a novel two-dimensional framework materials constructed from the polyoxometalates and coordination groups

T2 - [As8IIIV14IVO42 (CO3)][Cu(en)2]3·10H2O

AU - Cui, Xiao Bing

AU - Sun, Yan Qiong

AU - Yang, Guo Yu

PY - 2003/3/1

Y1 - 2003/3/1

N2 - A new compound [As8IIIV14IVO42 (CO3)][Cu(en)2]3·10H2O (1) has been synthesized from V2O5, As2O3, CuCl2·2H2O, en and H2C2O4·2H2O in aqueous solution using the hydrothermal metho d and characterized by single-crystal X-ray diffraction analysis. X-ray crystallography reveals that 1 is a novel two-dimensional framework material constructed from the mixed As/V polyoxometalates and coordination groups.

AB - A new compound [As8IIIV14IVO42 (CO3)][Cu(en)2]3·10H2O (1) has been synthesized from V2O5, As2O3, CuCl2·2H2O, en and H2C2O4·2H2O in aqueous solution using the hydrothermal metho d and characterized by single-crystal X-ray diffraction analysis. X-ray crystallography reveals that 1 is a novel two-dimensional framework material constructed from the mixed As/V polyoxometalates and coordination groups.

KW - As/V/O polyoxometalates

KW - Coordination groups

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Two-dimensional structure

UR - https://www.scopus.com/pages/publications/0037368499

U2 - 10.1016/S1387-7003(02)00740-2

DO - 10.1016/S1387-7003(02)00740-2

M3 - Article

AN - SCOPUS:0037368499

SN - 1387-7003

VL - 6

SP - 259

EP - 261

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 3

ER -

Hydrothermal synthesis and characterization of a novel two-dimensional framework materials constructed from the polyoxometalates and coordination groups: [As₈^IIIV₁₄^IVO₄₂ (CO₃)][Cu(en)₂]₃·10H₂O

Abstract

Keywords

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