Hydrothermal synthesis and characterization of a novel sinusoidal layer structure constructed from polyoxometalates and coordination complex fragments

Xiao Bing Cui; Ji Qing Xu; Yong Li; Ying Hua Sun; Guo Yu Yang

doi:10.1002/ejic.200300593

Hydrothermal synthesis and characterization of a novel sinusoidal layer structure constructed from polyoxometalates and coordination complex fragments

Xiao Bing Cui, Ji Qing Xu^*, Yong Li, Ying Hua Sun, Guo Yu Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

81 Citations (Scopus)

Abstract

A novel polyoxometalate compound, [As₈V₁₄O ₄₂(SO₄)][Ni(en)₂]₃·4.5H ₂O (1), has been synthesized by a hydrothermal method and characterized by X-ray crystallography, showing that the compound 1 is the first example of a sinusoidal layer structure constructed from polyoxometalates and coordination complex fragments.

Original language	English
Pages (from-to)	1051-1055
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Issue number	5
DOIs	https://doi.org/10.1002/ejic.200300593
Publication status	Published - 5 Mar 2004
Externally published	Yes

Keywords

Hydrothermal synthesis
Magnetic properties
Polyoxometalates
X-ray diffraction

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abstract = "A novel polyoxometalate compound, [As8V14O 42(SO4)][Ni(en)2]3·4.5H 2O (1), has been synthesized by a hydrothermal method and characterized by X-ray crystallography, showing that the compound 1 is the first example of a sinusoidal layer structure constructed from polyoxometalates and coordination complex fragments.",

keywords = "Hydrothermal synthesis, Magnetic properties, Polyoxometalates, X-ray diffraction",

author = "Cui, {Xiao Bing} and Xu, {Ji Qing} and Yong Li and Sun, {Ying Hua} and Yang, {Guo Yu}",

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AU - Cui, Xiao Bing

AU - Xu, Ji Qing

AU - Li, Yong

AU - Sun, Ying Hua

AU - Yang, Guo Yu

PY - 2004/3/5

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AB - A novel polyoxometalate compound, [As8V14O 42(SO4)][Ni(en)2]3·4.5H 2O (1), has been synthesized by a hydrothermal method and characterized by X-ray crystallography, showing that the compound 1 is the first example of a sinusoidal layer structure constructed from polyoxometalates and coordination complex fragments.

KW - Hydrothermal synthesis

KW - Magnetic properties

KW - Polyoxometalates

KW - X-ray diffraction

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DO - 10.1002/ejic.200300593

M3 - Article

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JO - European Journal of Inorganic Chemistry

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Hydrothermal synthesis and characterization of a novel sinusoidal layer structure constructed from polyoxometalates and coordination complex fragments

Abstract

Keywords

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