Hydrothermal syntheses and crystal structures of two novel, hybrid materials based on secondary transition-metal-incorporated polyoxovanadate cluster backbones: [Cd(dien)2]2[(dien)CdAs 8V13O41(H2O)]·4H 2O and [Cd(en)2]2[(en)2Cd 2As8V12O40]

Shou Tian Zheng; Jie Zhang; Guo Yu Yang

doi:10.1021/ic0486015

Hydrothermal syntheses and crystal structures of two novel, hybrid materials based on secondary transition-metal-incorporated polyoxovanadate cluster backbones: [Cd(dien)₂]₂[(dien)CdAs ₈V₁₃O₄₁(H₂O)]·4H ₂O and [Cd(en)₂]₂[(en)₂Cd ₂As₈V₁₂O₄₀]

Shou Tian Zheng
, Jie Zhang
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

132 Citations (Scopus)

Abstract

Two new cadmium-substituted polyoxovanadates of [Cd(dien)₂] ₂[(dien)CdAs₈V₁₃O₄₁(H ₂O)·H₂O (1) and [Cd(en)₂] ₂[(en)₂Cd₂As₈V₁₂O ₄₀] (2), where dien is diethylenetriamine and en is ethylenediamine, have been hydrothermally synthesized and structurally characterized by elemental analyses, IR spectra, EPR spectra, XRD spectra, TG analyses, magnetic properties, and X-ray crystallography. Single-crystal X-ray diffraction analyses reveal that compounds 1 and 2 possess a discrete and 1D structure, respectively. The former contains an inorganic-organic hybrid monocadmium-substituted polyoxovanadate cluster unit that is derived from the well-known {As₈V₁₄O₄₂} cluster, whereas the latter is composed of an inorganic-organic hybrid bicadmium-substituted polyoxovanadate cluster unit that is derived from the well-known {As ₈V₁₂O₄₀} cluster.

Original language	English
Pages (from-to)	2426-2430
Number of pages	5
Journal	Inorganic Chemistry
Volume	44
Issue number	7
DOIs	https://doi.org/10.1021/ic0486015
Publication status	Published - 7 Apr 2005
Externally published	Yes

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@article{69d7d2682c394367837592b8508f4b18,

title = "Hydrothermal syntheses and crystal structures of two novel, hybrid materials based on secondary transition-metal-incorporated polyoxovanadate cluster backbones: [Cd(dien)2]2[(dien)CdAs 8V13O41(H2O)]·4H 2O and [Cd(en)2]2[(en)2Cd 2As8V12O40]",

abstract = "Two new cadmium-substituted polyoxovanadates of [Cd(dien)2] 2[(dien)CdAs8V13O41(H 2O)·H2O (1) and [Cd(en)2] 2[(en)2Cd2As8V12O 40] (2), where dien is diethylenetriamine and en is ethylenediamine, have been hydrothermally synthesized and structurally characterized by elemental analyses, IR spectra, EPR spectra, XRD spectra, TG analyses, magnetic properties, and X-ray crystallography. Single-crystal X-ray diffraction analyses reveal that compounds 1 and 2 possess a discrete and 1D structure, respectively. The former contains an inorganic-organic hybrid monocadmium-substituted polyoxovanadate cluster unit that is derived from the well-known \{As8V14O42\} cluster, whereas the latter is composed of an inorganic-organic hybrid bicadmium-substituted polyoxovanadate cluster unit that is derived from the well-known \{As 8V12O40\} cluster.",

author = "Zheng, \{Shou Tian\} and Jie Zhang and Yang, \{Guo Yu\}",

year = "2005",

month = apr,

day = "7",

doi = "10.1021/ic0486015",

language = "English",

volume = "44",

pages = "2426--2430",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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}

Hydrothermal syntheses and crystal structures of two novel, hybrid materials based on secondary transition-metal-incorporated polyoxovanadate cluster backbones: [Cd(dien)₂]₂[(dien)CdAs ₈V₁₃O₄₁(H₂O)]·4H ₂O and [Cd(en)₂]₂[(en)₂Cd ₂As₈V₁₂O₄₀]. / Zheng, Shou Tian; Zhang, Jie ; Yang, Guo Yu.
In: Inorganic Chemistry, Vol. 44, No. 7, 07.04.2005, p. 2426-2430.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Hydrothermal syntheses and crystal structures of two novel, hybrid materials based on secondary transition-metal-incorporated polyoxovanadate cluster backbones

T2 - [Cd(dien)2]2[(dien)CdAs 8V13O41(H2O)]·4H 2O and [Cd(en)2]2[(en)2Cd 2As8V12O40]

AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2005/4/7

Y1 - 2005/4/7

N2 - Two new cadmium-substituted polyoxovanadates of [Cd(dien)2] 2[(dien)CdAs8V13O41(H 2O)·H2O (1) and [Cd(en)2] 2[(en)2Cd2As8V12O 40] (2), where dien is diethylenetriamine and en is ethylenediamine, have been hydrothermally synthesized and structurally characterized by elemental analyses, IR spectra, EPR spectra, XRD spectra, TG analyses, magnetic properties, and X-ray crystallography. Single-crystal X-ray diffraction analyses reveal that compounds 1 and 2 possess a discrete and 1D structure, respectively. The former contains an inorganic-organic hybrid monocadmium-substituted polyoxovanadate cluster unit that is derived from the well-known {As8V14O42} cluster, whereas the latter is composed of an inorganic-organic hybrid bicadmium-substituted polyoxovanadate cluster unit that is derived from the well-known {As 8V12O40} cluster.

AB - Two new cadmium-substituted polyoxovanadates of [Cd(dien)2] 2[(dien)CdAs8V13O41(H 2O)·H2O (1) and [Cd(en)2] 2[(en)2Cd2As8V12O 40] (2), where dien is diethylenetriamine and en is ethylenediamine, have been hydrothermally synthesized and structurally characterized by elemental analyses, IR spectra, EPR spectra, XRD spectra, TG analyses, magnetic properties, and X-ray crystallography. Single-crystal X-ray diffraction analyses reveal that compounds 1 and 2 possess a discrete and 1D structure, respectively. The former contains an inorganic-organic hybrid monocadmium-substituted polyoxovanadate cluster unit that is derived from the well-known {As8V14O42} cluster, whereas the latter is composed of an inorganic-organic hybrid bicadmium-substituted polyoxovanadate cluster unit that is derived from the well-known {As 8V12O40} cluster.

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