Hydrogen generation from catalytic hydrolysis of sodium borohydride for proton exchange membrane fuel cells

Chuan Wu; Huaming Zhang; Baolian Yi

doi:10.1016/j.cattod.2004.06.095

Hydrogen generation from catalytic hydrolysis of sodium borohydride for proton exchange membrane fuel cells

Chuan Wu^*
, Huaming Zhang
, Baolian Yi

^*Corresponding author for this work

CAS - Dalian Institute of Chemical Physics

Research output: Contribution to journal › Conference article › peer-review

152 Citations (Scopus)

Abstract

A novel hydrogen generation (HG) method for proton exchange membrane fuel cell (PEMFC) is developed. Carbon-supported platinum catalysts were synthesized by an impregnation method, and adopted to catalysis hydrolysis of NaBH ₄ solution. These catalysts exhibit excellent hydrogen generation rates and approximate 100% efficiencies. A HG system with 100mg 20% Pt/C catalyst has the ability to supply a 299W PEMFC. Specific surface of the support is not a crucial factor affecting the HG performances of the catalysts, while Pt loading, Pt particle size and size distribution, and micropore structure play important roles in hydrogen generation reactions.

Original language	English
Pages (from-to)	477-483
Number of pages	7
Journal	Catalysis Today
Volume	93-95
DOIs	https://doi.org/10.1016/j.cattod.2004.06.095
Publication status	Published - 1 Sept 2004
Externally published	Yes
Event	Selections from the Presentations of the 3rd Asia-Pacific Congress - Dalian, China Duration: 12 Oct 2003 → 12 Oct 2003

Keywords

Carbon support
Hydrogen generation
PEMFC
Platinum
Sodium borohydride

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10.1016/j.cattod.2004.06.095

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@article{2105597e8057429bab8714640d349e74,

title = "Hydrogen generation from catalytic hydrolysis of sodium borohydride for proton exchange membrane fuel cells",

abstract = "A novel hydrogen generation (HG) method for proton exchange membrane fuel cell (PEMFC) is developed. Carbon-supported platinum catalysts were synthesized by an impregnation method, and adopted to catalysis hydrolysis of NaBH 4 solution. These catalysts exhibit excellent hydrogen generation rates and approximate 100\% efficiencies. A HG system with 100mg 20\% Pt/C catalyst has the ability to supply a 299W PEMFC. Specific surface of the support is not a crucial factor affecting the HG performances of the catalysts, while Pt loading, Pt particle size and size distribution, and micropore structure play important roles in hydrogen generation reactions.",

keywords = "Carbon support, Hydrogen generation, PEMFC, Platinum, Sodium borohydride",

author = "Chuan Wu and Huaming Zhang and Baolian Yi",

year = "2004",

month = sep,

day = "1",

doi = "10.1016/j.cattod.2004.06.095",

language = "English",

volume = "93-95",

pages = "477--483",

journal = "Catalysis Today",

issn = "0920-5861",

publisher = "Elsevier B.V.",

note = "Selections from the Presentations of the 3rd Asia-Pacific Congress ; Conference date: 12-10-2003 Through 12-10-2003",

}

TY - JOUR

T1 - Hydrogen generation from catalytic hydrolysis of sodium borohydride for proton exchange membrane fuel cells

AU - Wu, Chuan

AU - Zhang, Huaming

AU - Yi, Baolian

PY - 2004/9/1

Y1 - 2004/9/1

N2 - A novel hydrogen generation (HG) method for proton exchange membrane fuel cell (PEMFC) is developed. Carbon-supported platinum catalysts were synthesized by an impregnation method, and adopted to catalysis hydrolysis of NaBH 4 solution. These catalysts exhibit excellent hydrogen generation rates and approximate 100% efficiencies. A HG system with 100mg 20% Pt/C catalyst has the ability to supply a 299W PEMFC. Specific surface of the support is not a crucial factor affecting the HG performances of the catalysts, while Pt loading, Pt particle size and size distribution, and micropore structure play important roles in hydrogen generation reactions.

AB - A novel hydrogen generation (HG) method for proton exchange membrane fuel cell (PEMFC) is developed. Carbon-supported platinum catalysts were synthesized by an impregnation method, and adopted to catalysis hydrolysis of NaBH 4 solution. These catalysts exhibit excellent hydrogen generation rates and approximate 100% efficiencies. A HG system with 100mg 20% Pt/C catalyst has the ability to supply a 299W PEMFC. Specific surface of the support is not a crucial factor affecting the HG performances of the catalysts, while Pt loading, Pt particle size and size distribution, and micropore structure play important roles in hydrogen generation reactions.

KW - Carbon support

KW - Hydrogen generation

KW - PEMFC

KW - Platinum

KW - Sodium borohydride

UR - https://www.scopus.com/pages/publications/4344698663

U2 - 10.1016/j.cattod.2004.06.095

DO - 10.1016/j.cattod.2004.06.095

M3 - Conference article

AN - SCOPUS:4344698663

SN - 0920-5861

VL - 93-95

SP - 477

EP - 483

JO - Catalysis Today

JF - Catalysis Today

T2 - Selections from the Presentations of the 3rd Asia-Pacific Congress

Y2 - 12 October 2003 through 12 October 2003

ER -

Hydrogen generation from catalytic hydrolysis of sodium borohydride for proton exchange membrane fuel cells

Abstract

Keywords

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