Host-Guest Technique for Designing Highly Energetic Compounds with the Nitroamino Group

Wenshuai Gong; Benyue Guo; Lu Hu; Siping Pang; Jean’ne M. Shreeve

doi:10.1021/acs.orglett.3c04258

Host-Guest Technique for Designing Highly Energetic Compounds with the Nitroamino Group

Wenshuai Gong, Benyue Guo, Lu Hu^*, Siping Pang^*, Jean’ne M. Shreeve^*

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A new energetic material, 2-azido-4,7-nitroamino-1H-imidazo[4,5-d]pyridazine (ANIP) with a highly sensitive azido group and its host-guest compounds (ANIP/H₂O and ANIP/H₂O₂), and energetic salts were obtained. With the guest and protons in host molecules, an abundant hydrogen bond system can be formed. This results in high crystal density and good sensitivity, which suggests that the host-guest strategy is a promising way to balance the contradiction between energy and sensitivity and provides a new path to obtain a new generation of high energetic materials.

Original language	English
Pages (from-to)	4417-4421
Number of pages	5
Journal	Organic Letters
Volume	26
Issue number	21
DOIs	https://doi.org/10.1021/acs.orglett.3c04258
Publication status	Published - 31 May 2024

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title = "Host-Guest Technique for Designing Highly Energetic Compounds with the Nitroamino Group",

abstract = "A new energetic material, 2-azido-4,7-nitroamino-1H-imidazo[4,5-d]pyridazine (ANIP) with a highly sensitive azido group and its host-guest compounds (ANIP/H2O and ANIP/H2O2), and energetic salts were obtained. With the guest and protons in host molecules, an abundant hydrogen bond system can be formed. This results in high crystal density and good sensitivity, which suggests that the host-guest strategy is a promising way to balance the contradiction between energy and sensitivity and provides a new path to obtain a new generation of high energetic materials.",

author = "Wenshuai Gong and Benyue Guo and Lu Hu and Siping Pang and Shreeve, {Jean{\textquoteright}ne M.}",

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T1 - Host-Guest Technique for Designing Highly Energetic Compounds with the Nitroamino Group

AU - Gong, Wenshuai

AU - Guo, Benyue

AU - Hu, Lu

AU - Pang, Siping

AU - Shreeve, Jean’ne M.

PY - 2024/5/31

Y1 - 2024/5/31

N2 - A new energetic material, 2-azido-4,7-nitroamino-1H-imidazo[4,5-d]pyridazine (ANIP) with a highly sensitive azido group and its host-guest compounds (ANIP/H2O and ANIP/H2O2), and energetic salts were obtained. With the guest and protons in host molecules, an abundant hydrogen bond system can be formed. This results in high crystal density and good sensitivity, which suggests that the host-guest strategy is a promising way to balance the contradiction between energy and sensitivity and provides a new path to obtain a new generation of high energetic materials.

AB - A new energetic material, 2-azido-4,7-nitroamino-1H-imidazo[4,5-d]pyridazine (ANIP) with a highly sensitive azido group and its host-guest compounds (ANIP/H2O and ANIP/H2O2), and energetic salts were obtained. With the guest and protons in host molecules, an abundant hydrogen bond system can be formed. This results in high crystal density and good sensitivity, which suggests that the host-guest strategy is a promising way to balance the contradiction between energy and sensitivity and provides a new path to obtain a new generation of high energetic materials.

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SP - 4417

EP - 4421

JO - Organic Letters

JF - Organic Letters

IS - 21

ER -

Host-Guest Technique for Designing Highly Energetic Compounds with the Nitroamino Group

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