TY - JOUR
T1 - Highly active and recyclable Pt nanocatalyst for hydrogenation of quinolines and isoquinolines
AU - Xue, Xiuru
AU - Zeng, Min
AU - Wang, Yanhua
N1 - Publisher Copyright:
© 2018 Elsevier B.V.
PY - 2018/6/25
Y1 - 2018/6/25
N2 - Thermoregulated phase-transfer Pt nanocatalyst was shown to be highly active, selective and recyclable in the hydrogenation of quinolines and isoquinolines. The catalyst could be easily separated from the product by simple phase separation and directly reused in the next cycle without evident loss in catalytic activity and selectivity, even after ten recycles. Importantly, for quinoline, the TON of 10,474 is the highest value ever reported among Pt catalysts. More remarkably, for isoquinoline, the TON of 5340 is far ahead of the highest record among transition metal catalysts.
AB - Thermoregulated phase-transfer Pt nanocatalyst was shown to be highly active, selective and recyclable in the hydrogenation of quinolines and isoquinolines. The catalyst could be easily separated from the product by simple phase separation and directly reused in the next cycle without evident loss in catalytic activity and selectivity, even after ten recycles. Importantly, for quinoline, the TON of 10,474 is the highest value ever reported among Pt catalysts. More remarkably, for isoquinoline, the TON of 5340 is far ahead of the highest record among transition metal catalysts.
KW - Hydrogenation
KW - Pt nanoparticles
KW - Quinolines and isoquinolines
KW - Recycling
KW - Thermoregulated phase-transfer catalysis
UR - https://www.scopus.com/pages/publications/85046169946
U2 - 10.1016/j.apcata.2018.04.039
DO - 10.1016/j.apcata.2018.04.039
M3 - Article
AN - SCOPUS:85046169946
SN - 0926-860X
VL - 560
SP - 37
EP - 41
JO - Applied Catalysis A: General
JF - Applied Catalysis A: General
ER -