High-yield synthesis of 1,3-dimesityl-propane-1,3-dione: Isolation of its aluminum complex as a stable intermediate

Cui Zhang; Peiju Yang; Yue Yang; Xiaojuan Huang; Xiao Juan Yang; Biao Wu

doi:10.1080/00397910802138702

High-yield synthesis of 1,3-dimesityl-propane-1,3-dione: Isolation of its aluminum complex as a stable intermediate

Cui Zhang
, Peiju Yang
, Yue Yang
, Xiaojuan Huang
, Xiao Juan Yang
, Biao Wu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

1,3-Dimesityl-propane-1,3-dione was synthesized in high yield, via a stable intermediate (its aluminum complex) from malonyl dichloride and mesitylene by Friedel-Crafts reaction using anhydrous aluminum chloride as catalyst. The intermediate aluminum complex was isolated and characterized by X-ray diffraction analysis, which decomposed upon reflux in concentrate hydrochloric acid to give the title compound.

Original language	English
Pages (from-to)	2349-2356
Number of pages	8
Journal	Synthetic Communications
Volume	38
Issue number	14
DOIs	https://doi.org/10.1080/00397910802138702
Publication status	Published - Jan 2008
Externally published	Yes

Keywords

1,3-dimesityl-propane-1,3-dione
Aluminum complex
Friedel-Crafts reaction
Synthesis

Access to Document

10.1080/00397910802138702

Cite this

@article{381aa2e80d184e01b4dcb0a604a2a472,

title = "High-yield synthesis of 1,3-dimesityl-propane-1,3-dione: Isolation of its aluminum complex as a stable intermediate",

abstract = "1,3-Dimesityl-propane-1,3-dione was synthesized in high yield, via a stable intermediate (its aluminum complex) from malonyl dichloride and mesitylene by Friedel-Crafts reaction using anhydrous aluminum chloride as catalyst. The intermediate aluminum complex was isolated and characterized by X-ray diffraction analysis, which decomposed upon reflux in concentrate hydrochloric acid to give the title compound.",

keywords = "1,3-dimesityl-propane-1,3-dione, Aluminum complex, Friedel-Crafts reaction, Synthesis",

author = "Cui Zhang and Peiju Yang and Yue Yang and Xiaojuan Huang and Yang, \{Xiao Juan\} and Biao Wu",

year = "2008",

month = jan,

doi = "10.1080/00397910802138702",

language = "English",

volume = "38",

pages = "2349--2356",

journal = "Synthetic Communications",

issn = "0039-7911",

publisher = "Taylor and Francis Ltd.",

number = "14",

}

TY - JOUR

T1 - High-yield synthesis of 1,3-dimesityl-propane-1,3-dione

T2 - Isolation of its aluminum complex as a stable intermediate

AU - Zhang, Cui

AU - Yang, Peiju

AU - Yang, Yue

AU - Huang, Xiaojuan

AU - Yang, Xiao Juan

AU - Wu, Biao

PY - 2008/1

Y1 - 2008/1

N2 - 1,3-Dimesityl-propane-1,3-dione was synthesized in high yield, via a stable intermediate (its aluminum complex) from malonyl dichloride and mesitylene by Friedel-Crafts reaction using anhydrous aluminum chloride as catalyst. The intermediate aluminum complex was isolated and characterized by X-ray diffraction analysis, which decomposed upon reflux in concentrate hydrochloric acid to give the title compound.

AB - 1,3-Dimesityl-propane-1,3-dione was synthesized in high yield, via a stable intermediate (its aluminum complex) from malonyl dichloride and mesitylene by Friedel-Crafts reaction using anhydrous aluminum chloride as catalyst. The intermediate aluminum complex was isolated and characterized by X-ray diffraction analysis, which decomposed upon reflux in concentrate hydrochloric acid to give the title compound.

KW - 1,3-dimesityl-propane-1,3-dione

KW - Aluminum complex

KW - Friedel-Crafts reaction

KW - Synthesis

UR - https://www.scopus.com/pages/publications/47249126751

U2 - 10.1080/00397910802138702

DO - 10.1080/00397910802138702

M3 - Article

AN - SCOPUS:47249126751

SN - 0039-7911

VL - 38

SP - 2349

EP - 2356

JO - Synthetic Communications

JF - Synthetic Communications

IS - 14

ER -

High-yield synthesis of 1,3-dimesityl-propane-1,3-dione: Isolation of its aluminum complex as a stable intermediate

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this