High-Pressure Synthesis of Quadruple Perovskite Oxide CaCu3Cr2Re2O12 with a High Ferrimagnetic Curie Temperature

Jie Zhang; Zhehong Liu; Xubin Ye; Xiao Wang; Dabiao Lu; Haoting Zhao; Maocai Pi; Chien Te Chen; Jeng Lung Chen; Chang Yang Kuo; Zhiwei Hu; Xiaohui Yu; Xueqiang Zhang; Zhao Pan; Youwen Long

doi:10.1021/acs.inorgchem.3c04243

High-Pressure Synthesis of Quadruple Perovskite Oxide CaCu₃Cr₂Re₂O₁₂ with a High Ferrimagnetic Curie Temperature

Jie Zhang
, Zhehong Liu
, Xubin Ye
, Xiao Wang
, Dabiao Lu
, Haoting Zhao
, Maocai Pi
, Chien Te Chen
, Jeng Lung Chen
, Chang Yang Kuo
, Zhiwei Hu
, Xiaohui Yu
, Xueqiang Zhang
, Zhao Pan^*
, Youwen Long^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

An AA’₃B₂B’₂O₁₂-type quadruple perovskite oxide of CaCu₃Cr₂Re₂O₁₂ was synthesized at 18 GPa and 1373 K. Both an A- and B-site ordered quadruple perovskite crystal structure was observed, with the space group Pn-3. The valence states are verified to be CaCu₃²⁺Cr₂³⁺Re₂⁵⁺O₁₂ by bond valence sum calculations and synchrotron X-ray absorption spectroscopy. The spin interaction among Cu²⁺, Cr³⁺, and Re⁵⁺ generates a ferrimagnetic transition with the Curie temperature (T_C) at about 360 K. Moreover, electric transport properties and specific heat data suggest the presence of a half-metallic feature for this compound. The present study provides a promising quadruple perovskite oxide with above-room-temperature ferrimagnetism and possible half-metallic properties, which shows potential in the usage of spintronic devices.

Original language	English
Pages (from-to)	3499-3505
Number of pages	7
Journal	Inorganic Chemistry
Volume	63
Issue number	7
DOIs	https://doi.org/10.1021/acs.inorgchem.3c04243
Publication status	Published - 19 Feb 2024
Externally published	Yes

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10.1021/acs.inorgchem.3c04243

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@article{83ff67dd8ef440598b72ec692b2b5ccb,

title = "High-Pressure Synthesis of Quadruple Perovskite Oxide CaCu3Cr2Re2O12 with a High Ferrimagnetic Curie Temperature",

abstract = "An AA{\textquoteright}3B2B{\textquoteright}2O12-type quadruple perovskite oxide of CaCu3Cr2Re2O12 was synthesized at 18 GPa and 1373 K. Both an A- and B-site ordered quadruple perovskite crystal structure was observed, with the space group Pn-3. The valence states are verified to be CaCu32+Cr23+Re25+O12 by bond valence sum calculations and synchrotron X-ray absorption spectroscopy. The spin interaction among Cu2+, Cr3+, and Re5+ generates a ferrimagnetic transition with the Curie temperature (TC) at about 360 K. Moreover, electric transport properties and specific heat data suggest the presence of a half-metallic feature for this compound. The present study provides a promising quadruple perovskite oxide with above-room-temperature ferrimagnetism and possible half-metallic properties, which shows potential in the usage of spintronic devices.",

author = "Jie Zhang and Zhehong Liu and Xubin Ye and Xiao Wang and Dabiao Lu and Haoting Zhao and Maocai Pi and Chen, \{Chien Te\} and Chen, \{Jeng Lung\} and Kuo, \{Chang Yang\} and Zhiwei Hu and Xiaohui Yu and Xueqiang Zhang and Zhao Pan and Youwen Long",

note = "Publisher Copyright: {\textcopyright} 2024 American Chemical Society.",

year = "2024",

month = feb,

day = "19",

doi = "10.1021/acs.inorgchem.3c04243",

language = "English",

volume = "63",

pages = "3499--3505",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - High-Pressure Synthesis of Quadruple Perovskite Oxide CaCu3Cr2Re2O12 with a High Ferrimagnetic Curie Temperature

AU - Zhang, Jie

AU - Liu, Zhehong

AU - Ye, Xubin

AU - Wang, Xiao

AU - Lu, Dabiao

AU - Zhao, Haoting

AU - Pi, Maocai

AU - Chen, Chien Te

AU - Chen, Jeng Lung

AU - Kuo, Chang Yang

AU - Hu, Zhiwei

AU - Yu, Xiaohui

AU - Zhang, Xueqiang

AU - Pan, Zhao

AU - Long, Youwen

PY - 2024/2/19

Y1 - 2024/2/19

N2 - An AA’3B2B’2O12-type quadruple perovskite oxide of CaCu3Cr2Re2O12 was synthesized at 18 GPa and 1373 K. Both an A- and B-site ordered quadruple perovskite crystal structure was observed, with the space group Pn-3. The valence states are verified to be CaCu32+Cr23+Re25+O12 by bond valence sum calculations and synchrotron X-ray absorption spectroscopy. The spin interaction among Cu2+, Cr3+, and Re5+ generates a ferrimagnetic transition with the Curie temperature (TC) at about 360 K. Moreover, electric transport properties and specific heat data suggest the presence of a half-metallic feature for this compound. The present study provides a promising quadruple perovskite oxide with above-room-temperature ferrimagnetism and possible half-metallic properties, which shows potential in the usage of spintronic devices.

AB - An AA’3B2B’2O12-type quadruple perovskite oxide of CaCu3Cr2Re2O12 was synthesized at 18 GPa and 1373 K. Both an A- and B-site ordered quadruple perovskite crystal structure was observed, with the space group Pn-3. The valence states are verified to be CaCu32+Cr23+Re25+O12 by bond valence sum calculations and synchrotron X-ray absorption spectroscopy. The spin interaction among Cu2+, Cr3+, and Re5+ generates a ferrimagnetic transition with the Curie temperature (TC) at about 360 K. Moreover, electric transport properties and specific heat data suggest the presence of a half-metallic feature for this compound. The present study provides a promising quadruple perovskite oxide with above-room-temperature ferrimagnetism and possible half-metallic properties, which shows potential in the usage of spintronic devices.

UR - https://www.scopus.com/pages/publications/85185394628

U2 - 10.1021/acs.inorgchem.3c04243

DO - 10.1021/acs.inorgchem.3c04243

M3 - Article

C2 - 38320745

AN - SCOPUS:85185394628

SN - 0020-1669

VL - 63

SP - 3499

EP - 3505

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

High-Pressure Synthesis of Quadruple Perovskite Oxide CaCu₃Cr₂Re₂O₁₂ with a High Ferrimagnetic Curie Temperature

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