Abstract
La 3Ni 2O 7 oxide has been synthesized by a facile sol-gel method using a nonionic surfactant (EO)106(PO)70(EO)106 tri-block copolymer (Pluronic F127) as the chelating agent. The pure phase of La 3Ni 2O 7 has been obtained by sintering at temperatures of 1100 °C for 12 h. La 3Ni 2O 7 oxide as a cathode presents no visible reaction with an Y 2O 3-stabilized ZrO 2 (YSZ) electrolyte. The electrochemical performance of the prepared oxide as a cathode has been investigated. Area specific resistance of La 3Ni 2O 7 material on YSZ electrolyte is as low as 0.39 Ω cm 2 at 750 °C. Furthermore, an anode-supported single-cell configuration of NiO-YSZ/YSZ/La 3Ni 2O 7 has been achieved a maximum power density of 848 mW cm - 2 at 750 °C. The cell performance was stable under a constant current of 0.6 A cm - 2 for over 30 h at 750 °C. These results therefore suggest that La 3Ni 2O 7 synthesized by this sol-gel method is a highly promising cathode material for applications in IT-SOFCs.
| Original language | English |
|---|---|
| Pages (from-to) | 97-100 |
| Number of pages | 4 |
| Journal | Electrochemistry Communications |
| Volume | 22 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Aug 2012 |
| Externally published | Yes |
Keywords
- Cathode
- F127
- La Ni O
- Sol-gel method
- Solid oxide fuel cells
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