Hierarchical three-dimensional Fe3O4@porous carbon matrix/graphene anodes for high performance lithium ion batteries

Shiji Hao; Bowei Zhang; Ying Wang; Chaojiang Li; Jianyong Feng; Sarah Ball; Madhavi Srinivasan; Junsheng Wu; Yizhong Huang

doi:10.1016/j.electacta.2017.12.078

Hierarchical three-dimensional Fe₃O₄@porous carbon matrix/graphene anodes for high performance lithium ion batteries

Shiji Hao
, Bowei Zhang
, Ying Wang
, Chaojiang Li
, Jianyong Feng
, Sarah Ball
, Madhavi Srinivasan
, Junsheng Wu
, Yizhong Huang^*

^*Corresponding author for this work

Nanyang Technological University
Johnson Matthey Plc
University of Science and Technology Beijing

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

In the present paper, the hierarchical three-dimensional Fe₃O₄@porous carbon matrix (PCM) and Fe₃O₄@PCM/graphene are synthesized by a facile annealing of Mil-53(Fe) templates. Their electrochemical performances are evaluated as anode materials for lithium ion batteries. In comparison with Fe₃O₄@PCM, the Fe₃O₄@PCM/graphene electrode exhibits a much better cycling performance with the reversible capacity high up to 1000 mAh g⁻¹ after 500 cycles at 1 C. The improved performance can be ascribed to the high conductivity and structure stability provided by the unique graphene based hierarchical three-dimensional nanostructure.

Original language	English
Pages (from-to)	965-973
Number of pages	9
Journal	Electrochimica Acta
Volume	260
DOIs	https://doi.org/10.1016/j.electacta.2017.12.078
Publication status	Published - 10 Jan 2018
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Anode
FeO
Graphene
Lithium ion batteries
Porous carbon matrix

Access to Document

10.1016/j.electacta.2017.12.078

Cite this

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title = "Hierarchical three-dimensional Fe3O4@porous carbon matrix/graphene anodes for high performance lithium ion batteries",

abstract = "In the present paper, the hierarchical three-dimensional Fe3O4@porous carbon matrix (PCM) and Fe3O4@PCM/graphene are synthesized by a facile annealing of Mil-53(Fe) templates. Their electrochemical performances are evaluated as anode materials for lithium ion batteries. In comparison with Fe3O4@PCM, the Fe3O4@PCM/graphene electrode exhibits a much better cycling performance with the reversible capacity high up to 1000 mAh g−1 after 500 cycles at 1 C. The improved performance can be ascribed to the high conductivity and structure stability provided by the unique graphene based hierarchical three-dimensional nanostructure.",

keywords = "Anode, FeO, Graphene, Lithium ion batteries, Porous carbon matrix",

author = "Shiji Hao and Bowei Zhang and Ying Wang and Chaojiang Li and Jianyong Feng and Sarah Ball and Madhavi Srinivasan and Junsheng Wu and Yizhong Huang",

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day = "10",

doi = "10.1016/j.electacta.2017.12.078",

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T1 - Hierarchical three-dimensional Fe3O4@porous carbon matrix/graphene anodes for high performance lithium ion batteries

AU - Hao, Shiji

AU - Zhang, Bowei

AU - Wang, Ying

AU - Li, Chaojiang

AU - Feng, Jianyong

AU - Ball, Sarah

AU - Srinivasan, Madhavi

AU - Wu, Junsheng

AU - Huang, Yizhong

PY - 2018/1/10

Y1 - 2018/1/10

N2 - In the present paper, the hierarchical three-dimensional Fe3O4@porous carbon matrix (PCM) and Fe3O4@PCM/graphene are synthesized by a facile annealing of Mil-53(Fe) templates. Their electrochemical performances are evaluated as anode materials for lithium ion batteries. In comparison with Fe3O4@PCM, the Fe3O4@PCM/graphene electrode exhibits a much better cycling performance with the reversible capacity high up to 1000 mAh g−1 after 500 cycles at 1 C. The improved performance can be ascribed to the high conductivity and structure stability provided by the unique graphene based hierarchical three-dimensional nanostructure.

AB - In the present paper, the hierarchical three-dimensional Fe3O4@porous carbon matrix (PCM) and Fe3O4@PCM/graphene are synthesized by a facile annealing of Mil-53(Fe) templates. Their electrochemical performances are evaluated as anode materials for lithium ion batteries. In comparison with Fe3O4@PCM, the Fe3O4@PCM/graphene electrode exhibits a much better cycling performance with the reversible capacity high up to 1000 mAh g−1 after 500 cycles at 1 C. The improved performance can be ascribed to the high conductivity and structure stability provided by the unique graphene based hierarchical three-dimensional nanostructure.

KW - Anode

KW - FeO

KW - Graphene

KW - Lithium ion batteries

KW - Porous carbon matrix

UR - https://www.scopus.com/pages/publications/85038380427

U2 - 10.1016/j.electacta.2017.12.078

DO - 10.1016/j.electacta.2017.12.078

M3 - Article

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JF - Electrochimica Acta

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