Hexa-substituted polyoxometalates made of trivacant Dawson {P 2W15} fragments and {Ni6} clusters under hydrothermal conditions

Yong Chao Liu; Chun Hua Fu; Shou Tian Zheng; Jun Wei Zhao; Guo Yu Yang

doi:10.1039/c3dt51786a

Hexa-substituted polyoxometalates made of trivacant Dawson {P ₂W₁₅} fragments and {Ni₆} clusters under hydrothermal conditions

Yong Chao Liu
, Chun Hua Fu
, Shou Tian Zheng
, Jun Wei Zhao^*
, Guo Yu Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Three novel polyoxometalates (POMs) containing [Ni₆(μ ₃-OH)₃]^9- and [P₂W ₁₅O₅₆]^12- units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters.

Original language	English
Pages (from-to)	16676-16679
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	48
DOIs	https://doi.org/10.1039/c3dt51786a
Publication status	Published - 28 Dec 2013
Externally published	Yes

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abstract = "Three novel polyoxometalates (POMs) containing [Ni6(μ 3-OH)3]9- and [P2W 15O56]12- units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters.",

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AU - Liu, Yong Chao

AU - Fu, Chun Hua

AU - Zheng, Shou Tian

AU - Zhao, Jun Wei

AU - Yang, Guo Yu

PY - 2013/12/28

Y1 - 2013/12/28

N2 - Three novel polyoxometalates (POMs) containing [Ni6(μ 3-OH)3]9- and [P2W 15O56]12- units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters.

AB - Three novel polyoxometalates (POMs) containing [Ni6(μ 3-OH)3]9- and [P2W 15O56]12- units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters.

UR - https://www.scopus.com/pages/publications/84888254135

U2 - 10.1039/c3dt51786a

DO - 10.1039/c3dt51786a

M3 - Article

AN - SCOPUS:84888254135

SN - 1477-9226

VL - 42

SP - 16676

EP - 16679

JO - Dalton Transactions

JF - Dalton Transactions

IS - 48

ER -

Hexa-substituted polyoxometalates made of trivacant Dawson {P ₂W₁₅} fragments and {Ni₆} clusters under hydrothermal conditions

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