Heterogeneous Fenton-like catalyst for treatment of rhamnolipid-solubilized hexadecane wastewater

The treatment of wastewater containing hydrophobic organic pollutants solubilized by surfactants is of great environmental importance. In this work, the removal of rhamnolipid-solubilized hexadecane via a salicylic acid-methanol-acetone modified steel converter slag (SMA-SCS) catalyzed Fenton-like process was studied. First, we investigated the adsorption of rhamnolipid and hexadecane onto SCS and SMA-modified SCS. Compared to that of SCS, SMA-SCS exhibited better adsorption performance with maximum adsorption capacities of 0.23 and 0.28 mg/g for hexadecane and rhamnolipid, respectively. Degradation experiments showed that hexadecane was more readily degraded by the Fenton-like process than rhamnolipid. Up to 81.1% of hexadecane removal was achieved over 20 g/L of SMA-SCS within 24 h, whereas only 36% of rhamnolipid was degraded. On the other hand, the results indicated that increased rhamnolipid concentration had a negative effect on the degradation of hexadecane. During the oxidation reaction, the pH value of solution remained between 6.0 and 6.72. All these results demonstrated that the SMA-SCS/H₂O₂ Fenton-like process could be a cost-effective and promising approach for the treatment of surfactant-solubilized hydrophobic organic compounds.