Heteroatom-stabilized chiral framework of aluminophosphate molecular sieves

Xiaowei Song; Yi Li; Lin Gan; Zhuopeng Wang; Jihong Yu; Ruren Xu

doi:10.1002/anie.200803578

Heteroatom-stabilized chiral framework of aluminophosphate molecular sieves

Xiaowei Song^*, Yi Li, Lin Gan, Zhuopeng Wang, Jihong Yu, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

105 Citations (Scopus)

Abstract

(Figure Presented) Intrinsically chiral: The compounds (C₄H ₁₂N)₂[M₂Al₁₀P₁₂O ₄₈] (denoted MAPOCJ40; M = Co, Zn) were solvothermally synthesized. Their structure contains one-dimensional helical 10-ring channels enclosed by double-helical ribbons of the same handedness made of the edge-sharing of 6-rings along the 21 screw axis. The framework is intrinsically chiral and exhibits a new zeotype structure.

Original language	English
Pages (from-to)	314-317
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	2
DOIs	https://doi.org/10.1002/anie.200803578
Publication status	Published - 2 Jan 2009
Externally published	Yes

Keywords

Aluminophosphates
Chirality
Solvothermal synthesis
Transition metals
Zeolites

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10.1002/anie.200803578

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title = "Heteroatom-stabilized chiral framework of aluminophosphate molecular sieves",

abstract = "(Figure Presented) Intrinsically chiral: The compounds (C4H 12N)2[M2Al10P12O 48] (denoted MAPOCJ40; M = Co, Zn) were solvothermally synthesized. Their structure contains one-dimensional helical 10-ring channels enclosed by double-helical ribbons of the same handedness made of the edge-sharing of 6-rings along the 21 screw axis. The framework is intrinsically chiral and exhibits a new zeotype structure.",

keywords = "Aluminophosphates, Chirality, Solvothermal synthesis, Transition metals, Zeolites",

author = "Xiaowei Song and Yi Li and Lin Gan and Zhuopeng Wang and Jihong Yu and Ruren Xu",

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doi = "10.1002/anie.200803578",

language = "English",

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journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Heteroatom-stabilized chiral framework of aluminophosphate molecular sieves

AU - Song, Xiaowei

AU - Li, Yi

AU - Gan, Lin

AU - Wang, Zhuopeng

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2009/1/2

Y1 - 2009/1/2

N2 - (Figure Presented) Intrinsically chiral: The compounds (C4H 12N)2[M2Al10P12O 48] (denoted MAPOCJ40; M = Co, Zn) were solvothermally synthesized. Their structure contains one-dimensional helical 10-ring channels enclosed by double-helical ribbons of the same handedness made of the edge-sharing of 6-rings along the 21 screw axis. The framework is intrinsically chiral and exhibits a new zeotype structure.

AB - (Figure Presented) Intrinsically chiral: The compounds (C4H 12N)2[M2Al10P12O 48] (denoted MAPOCJ40; M = Co, Zn) were solvothermally synthesized. Their structure contains one-dimensional helical 10-ring channels enclosed by double-helical ribbons of the same handedness made of the edge-sharing of 6-rings along the 21 screw axis. The framework is intrinsically chiral and exhibits a new zeotype structure.

KW - Aluminophosphates

KW - Chirality

KW - Solvothermal synthesis

KW - Transition metals

KW - Zeolites

UR - http://www.scopus.com/inward/record.url?scp=58249097250&partnerID=8YFLogxK

U2 - 10.1002/anie.200803578

DO - 10.1002/anie.200803578

M3 - Article

C2 - 19053113

AN - SCOPUS:58249097250

SN - 1433-7851

VL - 48

SP - 314

EP - 317

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 2

ER -

Heteroatom-stabilized chiral framework of aluminophosphate molecular sieves

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Keywords

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