Heteroatom-stabilized chiral framework of aluminophosphate molecular sieves

Xiaowei Song*, Yi Li, Lin Gan, Zhuopeng Wang, Jihong Yu, Ruren Xu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

105 Citations (Scopus)

Abstract

(Figure Presented) Intrinsically chiral: The compounds (C4H 12N)2[M2Al10P12O 48] (denoted MAPOCJ40; M = Co, Zn) were solvothermally synthesized. Their structure contains one-dimensional helical 10-ring channels enclosed by double-helical ribbons of the same handedness made of the edge-sharing of 6-rings along the 21 screw axis. The framework is intrinsically chiral and exhibits a new zeotype structure.

Original languageEnglish
Pages (from-to)314-317
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number2
DOIs
Publication statusPublished - 2 Jan 2009
Externally publishedYes

Keywords

  • Aluminophosphates
  • Chirality
  • Solvothermal synthesis
  • Transition metals
  • Zeolites

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