Abstract
(Figure Presented) Intrinsically chiral: The compounds (C4H 12N)2[M2Al10P12O 48] (denoted MAPOCJ40; M = Co, Zn) were solvothermally synthesized. Their structure contains one-dimensional helical 10-ring channels enclosed by double-helical ribbons of the same handedness made of the edge-sharing of 6-rings along the 21 screw axis. The framework is intrinsically chiral and exhibits a new zeotype structure.
Original language | English |
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Pages (from-to) | 314-317 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 48 |
Issue number | 2 |
DOIs | |
Publication status | Published - 2 Jan 2009 |
Externally published | Yes |
Keywords
- Aluminophosphates
- Chirality
- Solvothermal synthesis
- Transition metals
- Zeolites