Fused rings with N-oxide and -NH2: Good combination for high density and low sensitivity energetic materials

Lu Hu; Ping Yin; Gregory H. Imler; Damon A. Parrish; Haixiang Gao; Jean'ne M. Shreeve

doi:10.1039/c9cc04496e

Fused rings with N-oxide and -NH₂: Good combination for high density and low sensitivity energetic materials

Lu Hu
, Ping Yin
, Gregory H. Imler
, Damon A. Parrish
, Haixiang Gao
, Jean'ne M. Shreeve^*

^*Corresponding author for this work

University of Idaho
Naval Research Laboratory
China Agricultural University

Research output: Contribution to journal › Article › peer-review

79 Citations (Scopus)

Abstract

Oxidation reactions of 3,6-diamino-1,2,4-triazolo[4,3-b][1,2,4,5]tetrazine give four N-oxide compounds. Because of the presence of an amino group and the N-oxide moiety, these compounds are extensively hydrogen bonded. Resulting from π-π stacking interactions between the fused rings, compounds 1-3 are impact and friction insensitive, are thermally stable and have good density.

Original language	English
Pages (from-to)	8979-8982
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	61
DOIs	https://doi.org/10.1039/c9cc04496e
Publication status	Published - 2019
Externally published	Yes

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title = "Fused rings with N-oxide and -NH2: Good combination for high density and low sensitivity energetic materials",

abstract = "Oxidation reactions of 3,6-diamino-1,2,4-triazolo[4,3-b][1,2,4,5]tetrazine give four N-oxide compounds. Because of the presence of an amino group and the N-oxide moiety, these compounds are extensively hydrogen bonded. Resulting from π-π stacking interactions between the fused rings, compounds 1-3 are impact and friction insensitive, are thermally stable and have good density.",

author = "Lu Hu and Ping Yin and Imler, \{Gregory H.\} and Parrish, \{Damon A.\} and Haixiang Gao and Shreeve, \{Jean'ne M.\}",

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doi = "10.1039/c9cc04496e",

language = "English",

volume = "55",

pages = "8979--8982",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Fused rings with N-oxide and -NH2

T2 - Good combination for high density and low sensitivity energetic materials

AU - Hu, Lu

AU - Yin, Ping

AU - Imler, Gregory H.

AU - Parrish, Damon A.

AU - Gao, Haixiang

AU - Shreeve, Jean'ne M.

PY - 2019

Y1 - 2019

N2 - Oxidation reactions of 3,6-diamino-1,2,4-triazolo[4,3-b][1,2,4,5]tetrazine give four N-oxide compounds. Because of the presence of an amino group and the N-oxide moiety, these compounds are extensively hydrogen bonded. Resulting from π-π stacking interactions between the fused rings, compounds 1-3 are impact and friction insensitive, are thermally stable and have good density.

AB - Oxidation reactions of 3,6-diamino-1,2,4-triazolo[4,3-b][1,2,4,5]tetrazine give four N-oxide compounds. Because of the presence of an amino group and the N-oxide moiety, these compounds are extensively hydrogen bonded. Resulting from π-π stacking interactions between the fused rings, compounds 1-3 are impact and friction insensitive, are thermally stable and have good density.

UR - https://www.scopus.com/pages/publications/85069764448

U2 - 10.1039/c9cc04496e

DO - 10.1039/c9cc04496e

M3 - Article

C2 - 31290493

AN - SCOPUS:85069764448

SN - 1359-7345

VL - 55

SP - 8979

EP - 8982

JO - Chemical Communications

JF - Chemical Communications

IS - 61

ER -

Fused rings with N-oxide and -NH₂: Good combination for high density and low sensitivity energetic materials

Abstract

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