From supramolecular triangle to heteroleptic rhombus: A simple bridge can make a difference

Xiaocun Lu; Xiaopeng Li; Jin Liang Wang; Charles N. Moorefield; Chrys Wesdemiotis; George R. Newkome

doi:10.1039/c2cc35510h

From supramolecular triangle to heteroleptic rhombus: A simple bridge can make a difference

Xiaocun Lu
, Xiaopeng Li
, Jin Liang Wang
, Charles N. Moorefield
, Chrys Wesdemiotis^*
, George R. Newkome

^*Corresponding author for this work

University of Akron

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

Multicomponent, self-assembled rhomboidal constructs are reported, in which bis-terpyridines possessing 120° or 60° directionality and Zn^II or Cd^II in a stoichiometric ratio (1 : 1 : 2) initially form rhomboid and triangle mixtures; whereas, a tris-terpyridine reacts with the 60°-based bis-ligand and metal to quantitatively form a heteroleptic, centrally fused, rhomboidal structure.

Original language	English
Pages (from-to)	9873-9875
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	79
DOIs	https://doi.org/10.1039/c2cc35510h
Publication status	Published - 10 Sept 2012
Externally published	Yes

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abstract = "Multicomponent, self-assembled rhomboidal constructs are reported, in which bis-terpyridines possessing 120° or 60° directionality and ZnII or CdII in a stoichiometric ratio (1 : 1 : 2) initially form rhomboid and triangle mixtures; whereas, a tris-terpyridine reacts with the 60°-based bis-ligand and metal to quantitatively form a heteroleptic, centrally fused, rhomboidal structure.",

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AU - Wesdemiotis, Chrys

AU - Newkome, George R.

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AB - Multicomponent, self-assembled rhomboidal constructs are reported, in which bis-terpyridines possessing 120° or 60° directionality and ZnII or CdII in a stoichiometric ratio (1 : 1 : 2) initially form rhomboid and triangle mixtures; whereas, a tris-terpyridine reacts with the 60°-based bis-ligand and metal to quantitatively form a heteroleptic, centrally fused, rhomboidal structure.

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DO - 10.1039/c2cc35510h

M3 - Article

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From supramolecular triangle to heteroleptic rhombus: A simple bridge can make a difference

Abstract

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