Flexible porous organic polymers with 1,2-diol subunits favoring the high loading of Pd nanoparticles

Zhi Cun Wang; Boya Kuang; Hanyuan Chen; Nicolas Bogliotti; Ran Guo; Yan Liu; Jin Xiu Zhou; Mu Hua Huang

doi:10.1039/d5nr00049a

Flexible porous organic polymers with 1,2-diol subunits favoring the high loading of Pd nanoparticles

Zhi Cun Wang, Boya Kuang, Hanyuan Chen, Nicolas Bogliotti, Ran Guo, Yan Liu, Jin Xiu Zhou^*, Mu Hua Huang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

In recent years, the flexibility of porous organic polymers has demonstrated very unique properties during their applications. This paper reports a novel soluble porous polymer (named BIT-POP-75 and BIT-POP-75-OH) with 1,2-diketone and 1,2-diol subunits in the flexible polymer chain using contorted subunits. The solubility of the porous polymer and the flexible chelating 1,2-diol moiety facilitates the high loading and uniform dispersion of Pd nanoparticles to give the catalyst Pd@BIT-POP-75-OH, which shows high efficiency (k_app = 0.965 min⁻¹) for the catalytic reduction of 4-nitrophenol with good recyclability (10 cycles).

Original language	English
Pages (from-to)	9914-9919
Number of pages	6
Journal	Nanoscale
Volume	17
Issue number	16
DOIs	https://doi.org/10.1039/d5nr00049a
Publication status	Published - 3 Apr 2025
Externally published	Yes

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title = "Flexible porous organic polymers with 1,2-diol subunits favoring the high loading of Pd nanoparticles",

abstract = "In recent years, the flexibility of porous organic polymers has demonstrated very unique properties during their applications. This paper reports a novel soluble porous polymer (named BIT-POP-75 and BIT-POP-75-OH) with 1,2-diketone and 1,2-diol subunits in the flexible polymer chain using contorted subunits. The solubility of the porous polymer and the flexible chelating 1,2-diol moiety facilitates the high loading and uniform dispersion of Pd nanoparticles to give the catalyst Pd@BIT-POP-75-OH, which shows high efficiency (kapp = 0.965 min−1) for the catalytic reduction of 4-nitrophenol with good recyclability (10 cycles).",

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AU - Wang, Zhi Cun

AU - Kuang, Boya

AU - Chen, Hanyuan

AU - Bogliotti, Nicolas

AU - Guo, Ran

AU - Liu, Yan

AU - Zhou, Jin Xiu

AU - Huang, Mu Hua

PY - 2025/4/3

Y1 - 2025/4/3

N2 - In recent years, the flexibility of porous organic polymers has demonstrated very unique properties during their applications. This paper reports a novel soluble porous polymer (named BIT-POP-75 and BIT-POP-75-OH) with 1,2-diketone and 1,2-diol subunits in the flexible polymer chain using contorted subunits. The solubility of the porous polymer and the flexible chelating 1,2-diol moiety facilitates the high loading and uniform dispersion of Pd nanoparticles to give the catalyst Pd@BIT-POP-75-OH, which shows high efficiency (kapp = 0.965 min−1) for the catalytic reduction of 4-nitrophenol with good recyclability (10 cycles).

AB - In recent years, the flexibility of porous organic polymers has demonstrated very unique properties during their applications. This paper reports a novel soluble porous polymer (named BIT-POP-75 and BIT-POP-75-OH) with 1,2-diketone and 1,2-diol subunits in the flexible polymer chain using contorted subunits. The solubility of the porous polymer and the flexible chelating 1,2-diol moiety facilitates the high loading and uniform dispersion of Pd nanoparticles to give the catalyst Pd@BIT-POP-75-OH, which shows high efficiency (kapp = 0.965 min−1) for the catalytic reduction of 4-nitrophenol with good recyclability (10 cycles).

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SN - 2040-3364

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Flexible porous organic polymers with 1,2-diol subunits favoring the high loading of Pd nanoparticles

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