TY - JOUR
T1 - Flame propagation and overpressure characteristics of methane-hydrogen-mixed cloud explosion in unconfined area
T2 - Experimental and model study
AU - Li, Shuhong
AU - Liu, Zhenyi
AU - Zhao, Yao
AU - Li, Mingzhi
AU - Li, Pengliang
N1 - Publisher Copyright:
© 2025
PY - 2025/5
Y1 - 2025/5
N2 - This study investigates the explosion behavior of methane-hydrogen vapor clouds in an unconfined space. Experiments were conducted on an 8 m³ platform to examine the effects of hydrogen volume mixing ratios (V = 0 %, 20 %, 35 %, 50 %) at an equivalence ratio of 1.1. The results show that higher hydrogen ratios increase flame instability and propagation speed. The flame development process can be divided into two stages based on the average flame velocity. Due to the influence of instability, the average flame speed in Stage 2 is nearly twice that of Stage 1. In Stage 2, the average speeds for V = 0 % (methane), 20 %, 35 %, and 50 % hydrogen mixtures reached 5.619, 7.268, 7.910, and 19.997 m/s, respectively. Peak overpressure, pressure rise rate, and impulse also increase with hydrogen content. While V = 20 % and V = 35 % exhibit similar overpressure and rise rates, the impulse at V = 35 % and V = 50 % is nearly double that at V = 20 %. Therefore, V = 20 % is identified as a key turning point in hazard impact. Peak overpressure is crucial for determining safety distances in the process industry. This study also refines prediction models by integrating flame instability and overpressure effects. The improved TNO model (k = 2.97) outperforms the Thermal Expansivity Model and the original TNO model (k = 5.8), providing more accurate results. Using 2.07 kPa as the safety threshold, the model predicts safe distances of 2 m for methane, 3.5 m for V = 20 %, 6 m for V = 35 %, and 12 m for V = 50 %. These findings enhance the experimental understanding of methane-hydrogen explosions in large-scale unconfined environments and inform safety distance guidelines for industrial applications.
AB - This study investigates the explosion behavior of methane-hydrogen vapor clouds in an unconfined space. Experiments were conducted on an 8 m³ platform to examine the effects of hydrogen volume mixing ratios (V = 0 %, 20 %, 35 %, 50 %) at an equivalence ratio of 1.1. The results show that higher hydrogen ratios increase flame instability and propagation speed. The flame development process can be divided into two stages based on the average flame velocity. Due to the influence of instability, the average flame speed in Stage 2 is nearly twice that of Stage 1. In Stage 2, the average speeds for V = 0 % (methane), 20 %, 35 %, and 50 % hydrogen mixtures reached 5.619, 7.268, 7.910, and 19.997 m/s, respectively. Peak overpressure, pressure rise rate, and impulse also increase with hydrogen content. While V = 20 % and V = 35 % exhibit similar overpressure and rise rates, the impulse at V = 35 % and V = 50 % is nearly double that at V = 20 %. Therefore, V = 20 % is identified as a key turning point in hazard impact. Peak overpressure is crucial for determining safety distances in the process industry. This study also refines prediction models by integrating flame instability and overpressure effects. The improved TNO model (k = 2.97) outperforms the Thermal Expansivity Model and the original TNO model (k = 5.8), providing more accurate results. Using 2.07 kPa as the safety threshold, the model predicts safe distances of 2 m for methane, 3.5 m for V = 20 %, 6 m for V = 35 %, and 12 m for V = 50 %. These findings enhance the experimental understanding of methane-hydrogen explosions in large-scale unconfined environments and inform safety distance guidelines for industrial applications.
KW - Methane-hydrogen mixture
KW - Overpressure
KW - Prediction model
KW - Unconfined area
UR - https://www.scopus.com/pages/publications/105000027950
U2 - 10.1016/j.psep.2025.106940
DO - 10.1016/j.psep.2025.106940
M3 - Article
AN - SCOPUS:105000027950
SN - 0957-5820
VL - 197
JO - Process Safety and Environmental Protection
JF - Process Safety and Environmental Protection
M1 - 106940
ER -