First Nickel(II) cation inclusion within the mixed-valence polyoxomolybdate capped with four NiII(en)(H2O) groups: Hydrothermal synthesis and structure of [MoV8MoVI 4O30(μ2-OH)6(Ni IIO4){NiII(en)(H2O)}4]

Xiao Bing Cui; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/zaac.200400442

First Nickel(II) cation inclusion within the mixed-valence polyoxomolybdate capped with four Ni^II(en)(H₂O) groups: Hydrothermal synthesis and structure of [Mo^V₈Mo^VI ₄O₃₀(μ₂-OH)₆(Ni ^IIO₄){Ni^II(en)(H₂O)}₄]

Xiao Bing Cui, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The hydrothermal reaction of MoO₃, Ni(Ac)₂· 6H₂O, en (ethylenediamine) and H₂O produces [Mo ^V₈Mo^VI₄O₃₀(μ ₂-OH)₆(Ni^IIO₄){Ni ^II(en)(H₂O)}₄] (1), which is the first polyoxomolybdate capped with four {Ni^II(en)(H₂O)} groups and with inclusion of Nickel(II) cation. The structure of this compound was characterized by elemental analysis and single crystal X-ray diffraction. Crystal data for 1: Monoclinic, C2/m, a = 34.1719(4) Å, b = 15.3138(1) Å, c = 15.3408(3) Å, b = 116.575(2)°, V = 7179.72(8) Å³, Z = 4.

Original language	English
Pages (from-to)	642-644
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	631
Issue number	4
DOIs	https://doi.org/10.1002/zaac.200400442
Publication status	Published - 2005
Externally published	Yes

Keywords

Crystal structure
Hydrothermal synthesis
Keggin structure
Molybdenum
Nickel
Polyoxometalates
Vanadium

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@article{06e6070940a441a6a5d28878dc5c2de5,

title = "First Nickel(II) cation inclusion within the mixed-valence polyoxomolybdate capped with four NiII(en)(H2O) groups: Hydrothermal synthesis and structure of [MoV8MoVI 4O30(μ2-OH)6(Ni IIO4){NiII(en)(H2O)}4]",

abstract = "The hydrothermal reaction of MoO3, Ni(Ac)2· 6H2O, en (ethylenediamine) and H2O produces [Mo V8MoVI4O30(μ 2-OH)6(NiIIO4){Ni II(en)(H2O)}4] (1), which is the first polyoxomolybdate capped with four {NiII(en)(H2O)} groups and with inclusion of Nickel(II) cation. The structure of this compound was characterized by elemental analysis and single crystal X-ray diffraction. Crystal data for 1: Monoclinic, C2/m, a = 34.1719(4) {\AA}, b = 15.3138(1) {\AA}, c = 15.3408(3) {\AA}, b = 116.575(2)°, V = 7179.72(8) {\AA}3, Z = 4.",

keywords = "Crystal structure, Hydrothermal synthesis, Keggin structure, Molybdenum, Nickel, Polyoxometalates, Vanadium",

author = "Cui, {Xiao Bing} and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2005",

doi = "10.1002/zaac.200400442",

language = "English",

volume = "631",

pages = "642--644",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "4",

}

First Nickel(II) cation inclusion within the mixed-valence polyoxomolybdate capped with four Ni^II(en)(H₂O) groups: Hydrothermal synthesis and structure of [Mo^V₈Mo^VI ₄O₃₀(μ₂-OH)₆(Ni ^IIO₄){Ni^II(en)(H₂O)}₄]. / Cui, Xiao Bing; Zheng, Shou Tian; Yang, Guo Yu.
In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 631, No. 4, 2005, p. 642-644.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - First Nickel(II) cation inclusion within the mixed-valence polyoxomolybdate capped with four NiII(en)(H2O) groups

T2 - Hydrothermal synthesis and structure of [MoV8MoVI 4O30(μ2-OH)6(Ni IIO4){NiII(en)(H2O)}4]

AU - Cui, Xiao Bing

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2005

Y1 - 2005

N2 - The hydrothermal reaction of MoO3, Ni(Ac)2· 6H2O, en (ethylenediamine) and H2O produces [Mo V8MoVI4O30(μ 2-OH)6(NiIIO4){Ni II(en)(H2O)}4] (1), which is the first polyoxomolybdate capped with four {NiII(en)(H2O)} groups and with inclusion of Nickel(II) cation. The structure of this compound was characterized by elemental analysis and single crystal X-ray diffraction. Crystal data for 1: Monoclinic, C2/m, a = 34.1719(4) Å, b = 15.3138(1) Å, c = 15.3408(3) Å, b = 116.575(2)°, V = 7179.72(8) Å3, Z = 4.

AB - The hydrothermal reaction of MoO3, Ni(Ac)2· 6H2O, en (ethylenediamine) and H2O produces [Mo V8MoVI4O30(μ 2-OH)6(NiIIO4){Ni II(en)(H2O)}4] (1), which is the first polyoxomolybdate capped with four {NiII(en)(H2O)} groups and with inclusion of Nickel(II) cation. The structure of this compound was characterized by elemental analysis and single crystal X-ray diffraction. Crystal data for 1: Monoclinic, C2/m, a = 34.1719(4) Å, b = 15.3138(1) Å, c = 15.3408(3) Å, b = 116.575(2)°, V = 7179.72(8) Å3, Z = 4.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Keggin structure

KW - Molybdenum

KW - Nickel

KW - Polyoxometalates

KW - Vanadium

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U2 - 10.1002/zaac.200400442

DO - 10.1002/zaac.200400442

M3 - Article

AN - SCOPUS:17244382792

SN - 0044-2313

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