Facile design and synthesis of Li-rich nanoplates cathodes with habit-tuned crystal for lithium ion batteries

Jili Li; Tiekun Jia; Kai Liu; Junwei Zhao; Jian Chen; Chuanbao Cao

doi:10.1016/j.jpowsour.2016.09.150

Facile design and synthesis of Li-rich nanoplates cathodes with habit-tuned crystal for lithium ion batteries

Jili Li^*
, Tiekun Jia
, Kai Liu
, Junwei Zhao
, Jian Chen
, Chuanbao Cao

^*Corresponding author for this work

School of Material Science and Engineering

Luoyang Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Li-ion batteries with high-energy and high-power density are pursued to apply in the electronic vehicles and renewable energy storage systems. In this work, layered Li-rich transition-metal oxide cathode Li_1.2Ni_0.2Mn_0.6O₂ nanoplates with enhanced growth of {010} planes (LNMO-NP) is successfully synthesized through a facile and versatile strategy. Ethylene glycol plays an important role in the formation of LNMO-NP nanoplates with {010} electrochemically active surface planes exposure. As cathode for Li-ion batteries, LNMO-NP demonstrates a high specific discharge capacity of 270.2 mAh g⁻¹ at 0.1 C (1 C = 300 mA g⁻¹) and an excellent rate capability. The good electrochemical performance can be attributed to the nanoplates with the growth of {010} electrochemically active planes which is in favor of Li⁺ intercalation/deintercalation.

Original language	English
Pages (from-to)	37-42
Number of pages	6
Journal	Journal of Power Sources
Volume	333
DOIs	https://doi.org/10.1016/j.jpowsour.2016.09.150
Publication status	Published - 30 Nov 2016

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Cathodes
Habit-tuned crystal
Li-ion batteries
Li-rich transition-metal oxide
Nanoplates

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10.1016/j.jpowsour.2016.09.150

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title = "Facile design and synthesis of Li-rich nanoplates cathodes with habit-tuned crystal for lithium ion batteries",

abstract = "Li-ion batteries with high-energy and high-power density are pursued to apply in the electronic vehicles and renewable energy storage systems. In this work, layered Li-rich transition-metal oxide cathode Li1.2Ni0.2Mn0.6O2 nanoplates with enhanced growth of \{010\} planes (LNMO-NP) is successfully synthesized through a facile and versatile strategy. Ethylene glycol plays an important role in the formation of LNMO-NP nanoplates with \{010\} electrochemically active surface planes exposure. As cathode for Li-ion batteries, LNMO-NP demonstrates a high specific discharge capacity of 270.2 mAh g−1 at 0.1 C (1 C = 300 mA g−1) and an excellent rate capability. The good electrochemical performance can be attributed to the nanoplates with the growth of \{010\} electrochemically active planes which is in favor of Li+ intercalation/deintercalation.",

keywords = "Cathodes, Habit-tuned crystal, Li-ion batteries, Li-rich transition-metal oxide, Nanoplates",

author = "Jili Li and Tiekun Jia and Kai Liu and Junwei Zhao and Jian Chen and Chuanbao Cao",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

month = nov,

day = "30",

doi = "10.1016/j.jpowsour.2016.09.150",

language = "English",

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TY - JOUR

T1 - Facile design and synthesis of Li-rich nanoplates cathodes with habit-tuned crystal for lithium ion batteries

AU - Li, Jili

AU - Jia, Tiekun

AU - Liu, Kai

AU - Zhao, Junwei

AU - Chen, Jian

AU - Cao, Chuanbao

PY - 2016/11/30

Y1 - 2016/11/30

N2 - Li-ion batteries with high-energy and high-power density are pursued to apply in the electronic vehicles and renewable energy storage systems. In this work, layered Li-rich transition-metal oxide cathode Li1.2Ni0.2Mn0.6O2 nanoplates with enhanced growth of {010} planes (LNMO-NP) is successfully synthesized through a facile and versatile strategy. Ethylene glycol plays an important role in the formation of LNMO-NP nanoplates with {010} electrochemically active surface planes exposure. As cathode for Li-ion batteries, LNMO-NP demonstrates a high specific discharge capacity of 270.2 mAh g−1 at 0.1 C (1 C = 300 mA g−1) and an excellent rate capability. The good electrochemical performance can be attributed to the nanoplates with the growth of {010} electrochemically active planes which is in favor of Li+ intercalation/deintercalation.

AB - Li-ion batteries with high-energy and high-power density are pursued to apply in the electronic vehicles and renewable energy storage systems. In this work, layered Li-rich transition-metal oxide cathode Li1.2Ni0.2Mn0.6O2 nanoplates with enhanced growth of {010} planes (LNMO-NP) is successfully synthesized through a facile and versatile strategy. Ethylene glycol plays an important role in the formation of LNMO-NP nanoplates with {010} electrochemically active surface planes exposure. As cathode for Li-ion batteries, LNMO-NP demonstrates a high specific discharge capacity of 270.2 mAh g−1 at 0.1 C (1 C = 300 mA g−1) and an excellent rate capability. The good electrochemical performance can be attributed to the nanoplates with the growth of {010} electrochemically active planes which is in favor of Li+ intercalation/deintercalation.

KW - Cathodes

KW - Habit-tuned crystal

KW - Li-ion batteries

KW - Li-rich transition-metal oxide

KW - Nanoplates

UR - https://www.scopus.com/pages/publications/84989204326

U2 - 10.1016/j.jpowsour.2016.09.150

DO - 10.1016/j.jpowsour.2016.09.150

M3 - Article

AN - SCOPUS:84989204326

SN - 0378-7753

VL - 333

SP - 37

EP - 42

JO - Journal of Power Sources

JF - Journal of Power Sources

ER -

Facile design and synthesis of Li-rich nanoplates cathodes with habit-tuned crystal for lithium ion batteries

Abstract

UN SDGs

Keywords

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