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Esterification of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with AlFm(OH)3-m

  • Heng Dao Quan
  • , Masanori Tamura
  • , Ren Xiao Gao
  • , Akira Sekiya*
  • *Corresponding author for this work
  • National Institute of Advanced Industrial Science and Technology

Research output: Contribution to journalArticlepeer-review

Abstract

Porous AlFm(OH)3-m was prepared by heating AlF3·3H2O. Methyl chlorodifluoroacetate was synthesized in 77% yield by the reaction of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with AlFm(OH)3-m. The reaction mechanism was inferred in terms of surface property of AlFm(OH)3-m.

Original languageEnglish
Pages (from-to)4111-4114
Number of pages4
JournalTetrahedron
Volume57
Issue number19
DOIs
Publication statusPublished - 7 May 2001
Externally publishedYes

Keywords

  • 1,2-dichloro-1,1,2-trifluoro-2- methoxyethane
  • AlF(OH)
  • Methyl chlorodifluoroacetate

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