(en)Mn2(V2O7): A 3D manganese vanadate built by Mn-O layers and two types of pillars of V2O7 and en bridges

Gao Juan Cao; Shou Tian Zheng; Wei Hui Fang; Guo Yu Yang

doi:10.1016/j.inoche.2010.04.005

(en)Mn₂(V₂O₇): A 3D manganese vanadate built by Mn-O layers and two types of pillars of V₂O₇ and en bridges

Gao Juan Cao, Shou Tian Zheng, Wei Hui Fang, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

An unexpected 3D manganese vanadate (en)Mn₂(V₂O ₇) (1) (en=ethylenediamine) has been hydrothermally obtained by H₂E₂Ge₂O₃ (E=-CH₂CH ₂COO^-) ligands and well-prepared mixture of VMn-amine and characterized by IR spectroscopy, elemental analysis, thermal stability and powder X-ray diffraction. Single-crystal X-ray diffraction analysis reveals that the structure is a novel pillared-layer, in which MnO₅N octahedra are corner-linked to form an infinite sheet with 4-membered rings (MRs) and further condensed to the 3D framework. The most prominent feature of 1 is the connection between the sheets via double bridges, namely, inorganic V ₂O₇ dimeric units and organic en molecules. It is noteworthy that inorganic and organic double bridges between sheets have not been seen in manganese vanadates.

Original language	English
Pages (from-to)	834-836
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	13
Issue number	7
DOIs	https://doi.org/10.1016/j.inoche.2010.04.005
Publication status	Published - Jul 2010
Externally published	Yes

Keywords

Double bridges
Hydrothermal synthesis
Inorganic-organic hybrids
Manganese vanadate
Open-framework

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@article{57e04fc396a148479b61c9772b170b59,

title = "(en)Mn2(V2O7): A 3D manganese vanadate built by Mn-O layers and two types of pillars of V2O7 and en bridges",

abstract = "An unexpected 3D manganese vanadate (en)Mn2(V2O 7) (1) (en=ethylenediamine) has been hydrothermally obtained by H2E2Ge2O3 (E=-CH2CH 2COO-) ligands and well-prepared mixture of VMn-amine and characterized by IR spectroscopy, elemental analysis, thermal stability and powder X-ray diffraction. Single-crystal X-ray diffraction analysis reveals that the structure is a novel pillared-layer, in which MnO5N octahedra are corner-linked to form an infinite sheet with 4-membered rings (MRs) and further condensed to the 3D framework. The most prominent feature of 1 is the connection between the sheets via double bridges, namely, inorganic V 2O7 dimeric units and organic en molecules. It is noteworthy that inorganic and organic double bridges between sheets have not been seen in manganese vanadates.",

keywords = "Double bridges, Hydrothermal synthesis, Inorganic-organic hybrids, Manganese vanadate, Open-framework",

author = "Cao, {Gao Juan} and Zheng, {Shou Tian} and Fang, {Wei Hui} and Yang, {Guo Yu}",

year = "2010",

month = jul,

doi = "10.1016/j.inoche.2010.04.005",

language = "English",

volume = "13",

pages = "834--836",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "7",

}

TY - JOUR

T1 - (en)Mn2(V2O7)

T2 - A 3D manganese vanadate built by Mn-O layers and two types of pillars of V2O7 and en bridges

AU - Cao, Gao Juan

AU - Zheng, Shou Tian

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2010/7

Y1 - 2010/7

N2 - An unexpected 3D manganese vanadate (en)Mn2(V2O 7) (1) (en=ethylenediamine) has been hydrothermally obtained by H2E2Ge2O3 (E=-CH2CH 2COO-) ligands and well-prepared mixture of VMn-amine and characterized by IR spectroscopy, elemental analysis, thermal stability and powder X-ray diffraction. Single-crystal X-ray diffraction analysis reveals that the structure is a novel pillared-layer, in which MnO5N octahedra are corner-linked to form an infinite sheet with 4-membered rings (MRs) and further condensed to the 3D framework. The most prominent feature of 1 is the connection between the sheets via double bridges, namely, inorganic V 2O7 dimeric units and organic en molecules. It is noteworthy that inorganic and organic double bridges between sheets have not been seen in manganese vanadates.

AB - An unexpected 3D manganese vanadate (en)Mn2(V2O 7) (1) (en=ethylenediamine) has been hydrothermally obtained by H2E2Ge2O3 (E=-CH2CH 2COO-) ligands and well-prepared mixture of VMn-amine and characterized by IR spectroscopy, elemental analysis, thermal stability and powder X-ray diffraction. Single-crystal X-ray diffraction analysis reveals that the structure is a novel pillared-layer, in which MnO5N octahedra are corner-linked to form an infinite sheet with 4-membered rings (MRs) and further condensed to the 3D framework. The most prominent feature of 1 is the connection between the sheets via double bridges, namely, inorganic V 2O7 dimeric units and organic en molecules. It is noteworthy that inorganic and organic double bridges between sheets have not been seen in manganese vanadates.

KW - Double bridges

KW - Hydrothermal synthesis

KW - Inorganic-organic hybrids

KW - Manganese vanadate

KW - Open-framework

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DO - 10.1016/j.inoche.2010.04.005

M3 - Article

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SN - 1387-7003

VL - 13

SP - 834

EP - 836

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 7

ER -

(en)Mn₂(V₂O₇): A 3D manganese vanadate built by Mn-O layers and two types of pillars of V₂O₇ and en bridges

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Keywords

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