Enhanced photovoltaic performances of novel all-ionic liquid integrated poly(acrylic acid/polyethylene glycol) gel electrolytes in quasi-solid-state dye-sensitized solar cells

Weifu Sun; Haitao Xu

doi:10.1039/c6ra14443h

Enhanced photovoltaic performances of novel all-ionic liquid integrated poly(acrylic acid/polyethylene glycol) gel electrolytes in quasi-solid-state dye-sensitized solar cells

Weifu Sun
, Haitao Xu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

In this study, 1-butyl-3-methylimidazolium tetrafluoroborate is employed as a solvent and 1-methyl-3-propylimidazolium iodide is used as an iodide source to synthesize a full-ionic liquid (IL) electrolyte, which then was successfully integrated into amphiphilic poly(acrylic acid/polyethylene glycol) [poly(AA/PEG)] with a three-dimensional framework. The resultant poly(AA/PEG) gel electrolyte exhibited interconnected porous structures for holding the I^-/I₃^- redox couple and the IL imbibed poly(AA/PEG) gel electrolyte demonstrates improved thermal stability and record room-temperature ionic conductivities of as high as 12.4 mS cm^-1 from the full IL imbibed poly(AA/PEG) gel electrolytes. Moreover, a decently high light-to-electric power conversion efficiency of 6.12% is obtained from their dye-sensitized solar cells devices as compared with 5.32% achieved from a conventional acetonitrile-based poly(AA/PEG) gel electrolyte.

Original language	English
Pages (from-to)	68193-68198
Number of pages	6
Journal	RSC Advances
Volume	6
Issue number	72
DOIs	https://doi.org/10.1039/c6ra14443h
Publication status	Published - 2016
Externally published	Yes

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This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

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10.1039/c6ra14443h

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@article{09a039d990c345278cdf1e0abe3ed21c,

title = "Enhanced photovoltaic performances of novel all-ionic liquid integrated poly(acrylic acid/polyethylene glycol) gel electrolytes in quasi-solid-state dye-sensitized solar cells",

abstract = "In this study, 1-butyl-3-methylimidazolium tetrafluoroborate is employed as a solvent and 1-methyl-3-propylimidazolium iodide is used as an iodide source to synthesize a full-ionic liquid (IL) electrolyte, which then was successfully integrated into amphiphilic poly(acrylic acid/polyethylene glycol) [poly(AA/PEG)] with a three-dimensional framework. The resultant poly(AA/PEG) gel electrolyte exhibited interconnected porous structures for holding the I-/I3- redox couple and the IL imbibed poly(AA/PEG) gel electrolyte demonstrates improved thermal stability and record room-temperature ionic conductivities of as high as 12.4 mS cm-1 from the full IL imbibed poly(AA/PEG) gel electrolytes. Moreover, a decently high light-to-electric power conversion efficiency of 6.12\% is obtained from their dye-sensitized solar cells devices as compared with 5.32\% achieved from a conventional acetonitrile-based poly(AA/PEG) gel electrolyte.",

author = "Weifu Sun and Haitao Xu",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6ra14443h",

language = "English",

volume = "6",

pages = "68193--68198",

journal = "RSC Advances",

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publisher = "Royal Society of Chemistry",

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T1 - Enhanced photovoltaic performances of novel all-ionic liquid integrated poly(acrylic acid/polyethylene glycol) gel electrolytes in quasi-solid-state dye-sensitized solar cells

AU - Sun, Weifu

AU - Xu, Haitao

PY - 2016

Y1 - 2016

N2 - In this study, 1-butyl-3-methylimidazolium tetrafluoroborate is employed as a solvent and 1-methyl-3-propylimidazolium iodide is used as an iodide source to synthesize a full-ionic liquid (IL) electrolyte, which then was successfully integrated into amphiphilic poly(acrylic acid/polyethylene glycol) [poly(AA/PEG)] with a three-dimensional framework. The resultant poly(AA/PEG) gel electrolyte exhibited interconnected porous structures for holding the I-/I3- redox couple and the IL imbibed poly(AA/PEG) gel electrolyte demonstrates improved thermal stability and record room-temperature ionic conductivities of as high as 12.4 mS cm-1 from the full IL imbibed poly(AA/PEG) gel electrolytes. Moreover, a decently high light-to-electric power conversion efficiency of 6.12% is obtained from their dye-sensitized solar cells devices as compared with 5.32% achieved from a conventional acetonitrile-based poly(AA/PEG) gel electrolyte.

AB - In this study, 1-butyl-3-methylimidazolium tetrafluoroborate is employed as a solvent and 1-methyl-3-propylimidazolium iodide is used as an iodide source to synthesize a full-ionic liquid (IL) electrolyte, which then was successfully integrated into amphiphilic poly(acrylic acid/polyethylene glycol) [poly(AA/PEG)] with a three-dimensional framework. The resultant poly(AA/PEG) gel electrolyte exhibited interconnected porous structures for holding the I-/I3- redox couple and the IL imbibed poly(AA/PEG) gel electrolyte demonstrates improved thermal stability and record room-temperature ionic conductivities of as high as 12.4 mS cm-1 from the full IL imbibed poly(AA/PEG) gel electrolytes. Moreover, a decently high light-to-electric power conversion efficiency of 6.12% is obtained from their dye-sensitized solar cells devices as compared with 5.32% achieved from a conventional acetonitrile-based poly(AA/PEG) gel electrolyte.

UR - https://www.scopus.com/pages/publications/84979210854

U2 - 10.1039/c6ra14443h

DO - 10.1039/c6ra14443h

M3 - Article

AN - SCOPUS:84979210854

SN - 2046-2069

VL - 6

SP - 68193

EP - 68198

JO - RSC Advances

JF - RSC Advances

IS - 72

ER -

Enhanced photovoltaic performances of novel all-ionic liquid integrated poly(acrylic acid/polyethylene glycol) gel electrolytes in quasi-solid-state dye-sensitized solar cells

Abstract

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