Enhanced Photocatalytic H₂-Production Activity of CdS Quantum Dots Using Sn²⁺ as Cocatalyst under Visible Light Irradiation

Herein, oil-soluble CdS quantum dots (QDs) are first prepared through a solvent-thermal process. Then, oil-soluble CdS QDs are changed into water-soluble QDs via ligand exchange using mercaptopropionic acid as capping agent at pH 13. The photocatalytic performance is investigated under the visible light irradiation using glycerol as sacrificial agent and Sn²⁺ as cocatalyst. No H₂-production activity is observed for oil-soluble CdS QDs. Water-soluble CdS QDs exhibit significantly enhanced hydrogen evolution rate. When the concentration of cocatalyst Sn²⁺ increases to 0.2 × 10⁻³ m, the rate of hydrogen evolution reaches 1.61 mmol g⁻¹ h⁻¹, which is 24 times higher than that of the pristine water-soluble CdS QDs. The enhanced H₂-production efficiency is attributed to the adsorption of Sn²⁺ ions on the surface of CdS QDs that are further reduced to Sn atoms by photogenerated electrons. The in situ generated Sn atoms serve as photocatalytic cocatalyst for efficient hydrogen generation.