Enhanced electrochemical performance of NASICON-type sodium ion cathode based on charge balance theory

Yang Liu; Chen Sun; Qing Ni; Zheng Sun; Meng Li; Su Ma; Haibo Jin; Yongjie Zhao

doi:10.1016/j.ensm.2022.10.011

Enhanced electrochemical performance of NASICON-type sodium ion cathode based on charge balance theory

Yang Liu
, Chen Sun
, Qing Ni
, Zheng Sun
, Meng Li
, Su Ma
, Haibo Jin
, Yongjie Zhao^*

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

The variable components and relatively high Na⁺ intercalation voltage makes sodium ion superconductors (NASICON) as ideal cathode materials for secondary sodium-ion batteries. Na₃V₂(PO₄)₃, as one of the most typical NASICON-type cathode, needs urgent improvement to enable its wide application. Based on charge balance theory, via utilizing Al³⁺and SiO₄⁴⁻ to replace V³⁺ and PO₄³⁻ in Na₃V₂(PO₄)₃, respectively, Na₃₊_xV_1.5Al_0.5(PO₄)_3-_x(SiO₄)_x (0 ≤ x ≤ 0.5) cathode materials were prepared in this work. In comparison with the initial state, the operation potential was apparently promoted because of the reversible access of V⁴⁺/V⁵⁺ redox couple at 4.0 V vs. Na⁺/Na; the higher specific capacity can be achieved owing to much more conductive Na⁺ involved in the redox reaction of V species. Furthermore, the structural stability and diffusion kinetics is dramatically enhanced, which are further validated by ex-situ XRD and GITT analysis. Specifically, Na_3.3V_1.5Al_0.5(PO₄)_2.7(SiO₄)_0.3 can offer highly reversible capacities of 127.3 and 181.5 mAh g⁻¹ within the region of 2.5–4.4 V and 1.4–4.4 V, respectively, making itself a promising sodium ion cathode material. Na-ion full cells paired with Na_3.3V_1.5Al_0.5(PO₄)_2.7(SiO₄)_0.3 cathode and hard carbon anode are assembled, rendering a specific capacity of 154.3 mAh g⁻¹ at 0.5 C based on the mass of cathode.

Original language	English
Pages (from-to)	881-889
Number of pages	9
Journal	Energy Storage Materials
Volume	53
DOIs	https://doi.org/10.1016/j.ensm.2022.10.011
Publication status	Published - Dec 2022

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Anion substitution
NASICON-type cathode
Rate capability
Sodium-ion batteries
cycling stability

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10.1016/j.ensm.2022.10.011

Cite this

@article{b7cf17d0edd94067a657f9facf536f3d,

title = "Enhanced electrochemical performance of NASICON-type sodium ion cathode based on charge balance theory",

abstract = "The variable components and relatively high Na+ intercalation voltage makes sodium ion superconductors (NASICON) as ideal cathode materials for secondary sodium-ion batteries. Na3V2(PO4)3, as one of the most typical NASICON-type cathode, needs urgent improvement to enable its wide application. Based on charge balance theory, via utilizing Al3+and SiO44− to replace V3+ and PO43− in Na3V2(PO4)3, respectively, Na3+xV1.5Al0.5(PO4)3-x(SiO4)x (0 ≤ x ≤ 0.5) cathode materials were prepared in this work. In comparison with the initial state, the operation potential was apparently promoted because of the reversible access of V4+/V5+ redox couple at 4.0 V vs. Na+/Na; the higher specific capacity can be achieved owing to much more conductive Na+ involved in the redox reaction of V species. Furthermore, the structural stability and diffusion kinetics is dramatically enhanced, which are further validated by ex-situ XRD and GITT analysis. Specifically, Na3.3V1.5Al0.5(PO4)2.7(SiO4)0.3 can offer highly reversible capacities of 127.3 and 181.5 mAh g−1 within the region of 2.5{\textendash}4.4 V and 1.4{\textendash}4.4 V, respectively, making itself a promising sodium ion cathode material. Na-ion full cells paired with Na3.3V1.5Al0.5(PO4)2.7(SiO4)0.3 cathode and hard carbon anode are assembled, rendering a specific capacity of 154.3 mAh g−1 at 0.5 C based on the mass of cathode.",

keywords = "Anion substitution, NASICON-type cathode, Rate capability, Sodium-ion batteries, cycling stability",

author = "Yang Liu and Chen Sun and Qing Ni and Zheng Sun and Meng Li and Su Ma and Haibo Jin and Yongjie Zhao",

note = "Publisher Copyright: {\textcopyright} 2022",

year = "2022",

month = dec,

doi = "10.1016/j.ensm.2022.10.011",

language = "English",

volume = "53",

pages = "881--889",

journal = "Energy Storage Materials",

issn = "2405-8297",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Enhanced electrochemical performance of NASICON-type sodium ion cathode based on charge balance theory

AU - Liu, Yang

AU - Sun, Chen

AU - Ni, Qing

AU - Sun, Zheng

AU - Li, Meng

AU - Ma, Su

AU - Jin, Haibo

AU - Zhao, Yongjie

PY - 2022/12

Y1 - 2022/12

N2 - The variable components and relatively high Na+ intercalation voltage makes sodium ion superconductors (NASICON) as ideal cathode materials for secondary sodium-ion batteries. Na3V2(PO4)3, as one of the most typical NASICON-type cathode, needs urgent improvement to enable its wide application. Based on charge balance theory, via utilizing Al3+and SiO44− to replace V3+ and PO43− in Na3V2(PO4)3, respectively, Na3+xV1.5Al0.5(PO4)3-x(SiO4)x (0 ≤ x ≤ 0.5) cathode materials were prepared in this work. In comparison with the initial state, the operation potential was apparently promoted because of the reversible access of V4+/V5+ redox couple at 4.0 V vs. Na+/Na; the higher specific capacity can be achieved owing to much more conductive Na+ involved in the redox reaction of V species. Furthermore, the structural stability and diffusion kinetics is dramatically enhanced, which are further validated by ex-situ XRD and GITT analysis. Specifically, Na3.3V1.5Al0.5(PO4)2.7(SiO4)0.3 can offer highly reversible capacities of 127.3 and 181.5 mAh g−1 within the region of 2.5–4.4 V and 1.4–4.4 V, respectively, making itself a promising sodium ion cathode material. Na-ion full cells paired with Na3.3V1.5Al0.5(PO4)2.7(SiO4)0.3 cathode and hard carbon anode are assembled, rendering a specific capacity of 154.3 mAh g−1 at 0.5 C based on the mass of cathode.

AB - The variable components and relatively high Na+ intercalation voltage makes sodium ion superconductors (NASICON) as ideal cathode materials for secondary sodium-ion batteries. Na3V2(PO4)3, as one of the most typical NASICON-type cathode, needs urgent improvement to enable its wide application. Based on charge balance theory, via utilizing Al3+and SiO44− to replace V3+ and PO43− in Na3V2(PO4)3, respectively, Na3+xV1.5Al0.5(PO4)3-x(SiO4)x (0 ≤ x ≤ 0.5) cathode materials were prepared in this work. In comparison with the initial state, the operation potential was apparently promoted because of the reversible access of V4+/V5+ redox couple at 4.0 V vs. Na+/Na; the higher specific capacity can be achieved owing to much more conductive Na+ involved in the redox reaction of V species. Furthermore, the structural stability and diffusion kinetics is dramatically enhanced, which are further validated by ex-situ XRD and GITT analysis. Specifically, Na3.3V1.5Al0.5(PO4)2.7(SiO4)0.3 can offer highly reversible capacities of 127.3 and 181.5 mAh g−1 within the region of 2.5–4.4 V and 1.4–4.4 V, respectively, making itself a promising sodium ion cathode material. Na-ion full cells paired with Na3.3V1.5Al0.5(PO4)2.7(SiO4)0.3 cathode and hard carbon anode are assembled, rendering a specific capacity of 154.3 mAh g−1 at 0.5 C based on the mass of cathode.

KW - Anion substitution

KW - NASICON-type cathode

KW - Rate capability

KW - Sodium-ion batteries

KW - cycling stability

UR - https://www.scopus.com/pages/publications/85139738117

U2 - 10.1016/j.ensm.2022.10.011

DO - 10.1016/j.ensm.2022.10.011

M3 - Article

AN - SCOPUS:85139738117

SN - 2405-8297

VL - 53

SP - 881

EP - 889

JO - Energy Storage Materials

JF - Energy Storage Materials

ER -

Enhanced electrochemical performance of NASICON-type sodium ion cathode based on charge balance theory

Abstract

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Keywords

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