Energetic materials composed of coordination polymers: {[Zn(-atrz) 3](ClO 4) 2·2H 2O} n and {[Cu(-atrz) 3](NO 3) 2· 2H 2O} n

Y. L. Li; B. D. Wu; H. Qiu; T. L. Zhang; L. Yang

doi:10.1080/00958972.2014.935770

Energetic materials composed of coordination polymers: {[Zn(-atrz) ₃](ClO ₄) ₂·2H ₂O} _n and {[Cu(-atrz) ₃](NO ₃) ₂· 2H ₂O} _n

Y. L. Li
, B. D. Wu
, H. Qiu
, T. L. Zhang
, L. Yang^*

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

An improved synthetic pathway for trans-4,4'-azo-1,2,4-triazole (atrz) was discovered. Pure atrz was obtained directly without any other separation step in an environment friendly process. Treatment of atrz with zinc perchlorate and cupric nitrate led to the isolation of {[Zn(-atrz)₃](ClO ₄)₂·2H₂O}_n and {[Cu(-atrz)₃](NO₃)₂·2H ₂O}_n, which were well characterized. Their structures were determined by X-ray crystallographic analysis. The calculation results of the formation of {[Zn(-atrz)₃](ClO₄)₂ 2H ₂O}_n and {[Cu(-atrz)₃](NO₃) ₂ 2H₂O}_n indicates that the perfect crystal structures in spite of much resistance. A fundamental understanding of the structure and thermal properties involves factors, such as conjugated system, crystal structure, and inorganic metallic compounds that affect their thermal behavior. The high energy of the coordination compounds consists of chemical, electronic, and potential energy. The potential for the improvement of the coordination polymer opens up a new world for research of energetic materials.

Original language	English
Pages (from-to)	2016-2027
Number of pages	12
Journal	Journal of Coordination Chemistry
Volume	67
Issue number	11
DOIs	https://doi.org/10.1080/00958972.2014.935770
Publication status	Published - 3 Jun 2014

Keywords

Improved pathway
Perfect crystal structure
The great potential for improvement
Theoretical research
Thermal properties

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10.1080/00958972.2014.935770

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@article{495625662554444aaf848136edbb1c0a,

title = "Energetic materials composed of coordination polymers: \{[Zn(-atrz) 3](ClO 4) 2·2H 2O\} n and \{[Cu(-atrz) 3](NO 3) 2· 2H 2O\} n",

abstract = "An improved synthetic pathway for trans-4,4'-azo-1,2,4-triazole (atrz) was discovered. Pure atrz was obtained directly without any other separation step in an environment friendly process. Treatment of atrz with zinc perchlorate and cupric nitrate led to the isolation of \{[Zn(-atrz)3](ClO 4)2·2H2O\}n and \{[Cu(-atrz)3](NO3)2·2H 2O\}n, which were well characterized. Their structures were determined by X-ray crystallographic analysis. The calculation results of the formation of \{[Zn(-atrz)3](ClO4)2 2H 2O\}n and \{[Cu(-atrz)3](NO3) 2 2H2O\}n indicates that the perfect crystal structures in spite of much resistance. A fundamental understanding of the structure and thermal properties involves factors, such as conjugated system, crystal structure, and inorganic metallic compounds that affect their thermal behavior. The high energy of the coordination compounds consists of chemical, electronic, and potential energy. The potential for the improvement of the coordination polymer opens up a new world for research of energetic materials.",

keywords = "Improved pathway, Perfect crystal structure, The great potential for improvement, Theoretical research, Thermal properties",

author = "Li, \{Y. L.\} and Wu, \{B. D.\} and H. Qiu and Zhang, \{T. L.\} and L. Yang",

year = "2014",

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doi = "10.1080/00958972.2014.935770",

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T2 - {[Zn(-atrz) 3](ClO 4) 2·2H 2O} n and {[Cu(-atrz) 3](NO 3) 2· 2H 2O} n

AU - Li, Y. L.

AU - Wu, B. D.

AU - Qiu, H.

AU - Zhang, T. L.

AU - Yang, L.

PY - 2014/6/3

Y1 - 2014/6/3

N2 - An improved synthetic pathway for trans-4,4'-azo-1,2,4-triazole (atrz) was discovered. Pure atrz was obtained directly without any other separation step in an environment friendly process. Treatment of atrz with zinc perchlorate and cupric nitrate led to the isolation of {[Zn(-atrz)3](ClO 4)2·2H2O}n and {[Cu(-atrz)3](NO3)2·2H 2O}n, which were well characterized. Their structures were determined by X-ray crystallographic analysis. The calculation results of the formation of {[Zn(-atrz)3](ClO4)2 2H 2O}n and {[Cu(-atrz)3](NO3) 2 2H2O}n indicates that the perfect crystal structures in spite of much resistance. A fundamental understanding of the structure and thermal properties involves factors, such as conjugated system, crystal structure, and inorganic metallic compounds that affect their thermal behavior. The high energy of the coordination compounds consists of chemical, electronic, and potential energy. The potential for the improvement of the coordination polymer opens up a new world for research of energetic materials.

AB - An improved synthetic pathway for trans-4,4'-azo-1,2,4-triazole (atrz) was discovered. Pure atrz was obtained directly without any other separation step in an environment friendly process. Treatment of atrz with zinc perchlorate and cupric nitrate led to the isolation of {[Zn(-atrz)3](ClO 4)2·2H2O}n and {[Cu(-atrz)3](NO3)2·2H 2O}n, which were well characterized. Their structures were determined by X-ray crystallographic analysis. The calculation results of the formation of {[Zn(-atrz)3](ClO4)2 2H 2O}n and {[Cu(-atrz)3](NO3) 2 2H2O}n indicates that the perfect crystal structures in spite of much resistance. A fundamental understanding of the structure and thermal properties involves factors, such as conjugated system, crystal structure, and inorganic metallic compounds that affect their thermal behavior. The high energy of the coordination compounds consists of chemical, electronic, and potential energy. The potential for the improvement of the coordination polymer opens up a new world for research of energetic materials.

KW - Improved pathway

KW - Perfect crystal structure

KW - The great potential for improvement

KW - Theoretical research

KW - Thermal properties

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DO - 10.1080/00958972.2014.935770

M3 - Article

AN - SCOPUS:84905117388

SN - 0095-8972

VL - 67

SP - 2016

EP - 2027

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 11

ER -

Energetic materials composed of coordination polymers: {[Zn(-atrz) ₃](ClO ₄) ₂·2H ₂O} _n and {[Cu(-atrz) ₃](NO ₃) ₂· 2H ₂O} _n

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