Encapsulation and luminescent property of tetrakis (1-(2-thenoyl)-3,3,3-trifluoracetate) europium N-hexadecyl pyridinium in modified Si-MCM-41

Qinghong Xu; Liansheng Li; Bin Li; Jihong Yu; Ruren Xu

doi:10.1016/S1387-1811(00)00156-6

Encapsulation and luminescent property of tetrakis (1-(2-thenoyl)-3,3,3-trifluoracetate) europium N-hexadecyl pyridinium in modified Si-MCM-41

Qinghong Xu, Liansheng Li, Bin Li, Jihong Yu, Ruren Xu^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

Eu(TTA)₄C₅H₅NC₁₆H₃₃ (TTA:1-(2-thenoyl)-3,3,3-trifluoracetate) is encapsulated in Si-MCM-41 modified with N-(3-trimethoxysilylethyl)ethylenediamine. The X-ray photoelectron spectroscopy and UV-visible spectra of the rare earth (RE) complex and the assembly prove that the RE complex is dispersed in the channels of the modified Si-MCM-41. The emission spectrum of the assembly shows only a ⁵D₀ → ⁷F₂ transition. As compared with the RE complex itself, the lifetime of the assembly becomes longer, and its stability under the UV radiation is much better. (C) 2000 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	351-358
Number of pages	8
Journal	Microporous and Mesoporous Materials
Volume	38
Issue number	2-3
DOIs	https://doi.org/10.1016/S1387-1811(00)00156-6
Publication status	Published - Aug 2000
Externally published	Yes

Keywords

Assembly
Color purity
Encapsulation
Lifetime
Luminescence
Modification
Photostability

Access to Document

10.1016/S1387-1811(00)00156-6

Cite this

@article{e79644c7d35f4e1883c2e3f95b9208e1,

title = "Encapsulation and luminescent property of tetrakis (1-(2-thenoyl)-3,3,3-trifluoracetate) europium N-hexadecyl pyridinium in modified Si-MCM-41",

abstract = "Eu(TTA)4C5H5NC16H33 (TTA:1-(2-thenoyl)-3,3,3-trifluoracetate) is encapsulated in Si-MCM-41 modified with N-(3-trimethoxysilylethyl)ethylenediamine. The X-ray photoelectron spectroscopy and UV-visible spectra of the rare earth (RE) complex and the assembly prove that the RE complex is dispersed in the channels of the modified Si-MCM-41. The emission spectrum of the assembly shows only a 5D0 → 7F2 transition. As compared with the RE complex itself, the lifetime of the assembly becomes longer, and its stability under the UV radiation is much better. (C) 2000 Elsevier Science B.V. All rights reserved.",

keywords = "Assembly, Color purity, Encapsulation, Lifetime, Luminescence, Modification, Photostability",

author = "Qinghong Xu and Liansheng Li and Bin Li and Jihong Yu and Ruren Xu",

year = "2000",

month = aug,

doi = "10.1016/S1387-1811(00)00156-6",

language = "English",

volume = "38",

pages = "351--358",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

publisher = "Elsevier B.V.",

number = "2-3",

}

TY - JOUR

T1 - Encapsulation and luminescent property of tetrakis (1-(2-thenoyl)-3,3,3-trifluoracetate) europium N-hexadecyl pyridinium in modified Si-MCM-41

AU - Xu, Qinghong

AU - Li, Liansheng

AU - Li, Bin

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2000/8

Y1 - 2000/8

N2 - Eu(TTA)4C5H5NC16H33 (TTA:1-(2-thenoyl)-3,3,3-trifluoracetate) is encapsulated in Si-MCM-41 modified with N-(3-trimethoxysilylethyl)ethylenediamine. The X-ray photoelectron spectroscopy and UV-visible spectra of the rare earth (RE) complex and the assembly prove that the RE complex is dispersed in the channels of the modified Si-MCM-41. The emission spectrum of the assembly shows only a 5D0 → 7F2 transition. As compared with the RE complex itself, the lifetime of the assembly becomes longer, and its stability under the UV radiation is much better. (C) 2000 Elsevier Science B.V. All rights reserved.

AB - Eu(TTA)4C5H5NC16H33 (TTA:1-(2-thenoyl)-3,3,3-trifluoracetate) is encapsulated in Si-MCM-41 modified with N-(3-trimethoxysilylethyl)ethylenediamine. The X-ray photoelectron spectroscopy and UV-visible spectra of the rare earth (RE) complex and the assembly prove that the RE complex is dispersed in the channels of the modified Si-MCM-41. The emission spectrum of the assembly shows only a 5D0 → 7F2 transition. As compared with the RE complex itself, the lifetime of the assembly becomes longer, and its stability under the UV radiation is much better. (C) 2000 Elsevier Science B.V. All rights reserved.

KW - Assembly

KW - Color purity

KW - Encapsulation

KW - Lifetime

KW - Luminescence

KW - Modification

KW - Photostability

UR - http://www.scopus.com/inward/record.url?scp=0034253403&partnerID=8YFLogxK

U2 - 10.1016/S1387-1811(00)00156-6

DO - 10.1016/S1387-1811(00)00156-6

M3 - Article

AN - SCOPUS:0034253403

SN - 1387-1811

VL - 38

SP - 351

EP - 358

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 2-3

ER -

Encapsulation and luminescent property of tetrakis (1-(2-thenoyl)-3,3,3-trifluoracetate) europium N-hexadecyl pyridinium in modified Si-MCM-41

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this