Encapsulating [Mo3S13]2- clusters in cationic covalent organic frameworks: Enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst

Yuan Jie Cheng; Rui Wang; Shan Wang; Xiao Juan Xi; Lu Fang Ma; Shuang Quan Zang

doi:10.1039/c8cc07784c

Encapsulating [Mo₃S₁₃]^2- clusters in cationic covalent organic frameworks: Enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst

Yuan Jie Cheng
, Rui Wang
, Shan Wang
, Xiao Juan Xi
, Lu Fang Ma
, Shuang Quan Zang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

189 Citations (Scopus)

Abstract

We encapsulated anionic [Mo₃S₁₃]^2- clusters in cationic COFs (EB-COF) to obtain the novel composite photocatalytic material Mo₃S₁₃@EB-COF. Comprehensive studies indicated that the Mo₃S₁₃@EB-COF was the product of a successful conversion of a homogeneous to a heterogeneous catalyst, and exhibited excellent stability and recyclability as well as a remarkable photocatalytic hydrogen evolution rate of 13 215 μmol g^-1 h^-1 under visible-light irradiation over the course of 18 hours.

Original language	English
Pages (from-to)	13563-13566
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	96
DOIs	https://doi.org/10.1039/c8cc07784c
Publication status	Published - 2018
Externally published	Yes

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10.1039/c8cc07784c

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title = "Encapsulating [Mo3S13]2- clusters in cationic covalent organic frameworks: Enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst",

abstract = "We encapsulated anionic [Mo3S13]2- clusters in cationic COFs (EB-COF) to obtain the novel composite photocatalytic material Mo3S13@EB-COF. Comprehensive studies indicated that the Mo3S13@EB-COF was the product of a successful conversion of a homogeneous to a heterogeneous catalyst, and exhibited excellent stability and recyclability as well as a remarkable photocatalytic hydrogen evolution rate of 13 215 μmol g-1 h-1 under visible-light irradiation over the course of 18 hours.",

author = "Cheng, \{Yuan Jie\} and Rui Wang and Shan Wang and Xi, \{Xiao Juan\} and Ma, \{Lu Fang\} and Zang, \{Shuang Quan\}",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8cc07784c",

language = "English",

volume = "54",

pages = "13563--13566",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "96",

}

Encapsulating [Mo₃S₁₃]^2- clusters in cationic covalent organic frameworks: Enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst. / Cheng, Yuan Jie; Wang, Rui; Wang, Shan et al.
In: Chemical Communications, Vol. 54, No. 96, 2018, p. 13563-13566.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Encapsulating [Mo3S13]2- clusters in cationic covalent organic frameworks

T2 - Enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst

AU - Cheng, Yuan Jie

AU - Wang, Rui

AU - Wang, Shan

AU - Xi, Xiao Juan

AU - Ma, Lu Fang

AU - Zang, Shuang Quan

PY - 2018

Y1 - 2018

N2 - We encapsulated anionic [Mo3S13]2- clusters in cationic COFs (EB-COF) to obtain the novel composite photocatalytic material Mo3S13@EB-COF. Comprehensive studies indicated that the Mo3S13@EB-COF was the product of a successful conversion of a homogeneous to a heterogeneous catalyst, and exhibited excellent stability and recyclability as well as a remarkable photocatalytic hydrogen evolution rate of 13 215 μmol g-1 h-1 under visible-light irradiation over the course of 18 hours.

AB - We encapsulated anionic [Mo3S13]2- clusters in cationic COFs (EB-COF) to obtain the novel composite photocatalytic material Mo3S13@EB-COF. Comprehensive studies indicated that the Mo3S13@EB-COF was the product of a successful conversion of a homogeneous to a heterogeneous catalyst, and exhibited excellent stability and recyclability as well as a remarkable photocatalytic hydrogen evolution rate of 13 215 μmol g-1 h-1 under visible-light irradiation over the course of 18 hours.

UR - https://www.scopus.com/pages/publications/85057488359

U2 - 10.1039/c8cc07784c

DO - 10.1039/c8cc07784c

M3 - Article

C2 - 30444238

AN - SCOPUS:85057488359

SN - 1359-7345

VL - 54

SP - 13563

EP - 13566

JO - Chemical Communications

JF - Chemical Communications

IS - 96

ER -

Encapsulating [Mo₃S₁₃]^2- clusters in cationic covalent organic frameworks: Enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst

Abstract

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