Enantioselective Selenol-ene Using Rh-Hydride Catalysis

Hannah S. Slocumb; Shaozhen Nie; Vy M. Dong; Xiao Hui Yang

doi:10.1021/jacs.2c08475

Enantioselective Selenol-ene Using Rh-Hydride Catalysis

Hannah S. Slocumb
, Shaozhen Nie
, Vy M. Dong^*
, Xiao Hui Yang^*

^*Corresponding author for this work

University of California at Irvine
Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

This study showcases the first enantioselective hydroselenation of styrenes. Organoselenium building blocks are accessed with selectivity for the branched isomer. Through a Rh-hydride pathway, C-Se bonds can be forged with excellent regio- and enantiocontrol.

Original language	English
Pages (from-to)	18246-18250
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	144
Issue number	40
DOIs	https://doi.org/10.1021/jacs.2c08475
Publication status	Published - 12 Oct 2022
Externally published	Yes

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10.1021/jacs.2c08475

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title = "Enantioselective Selenol-ene Using Rh-Hydride Catalysis",

abstract = "This study showcases the first enantioselective hydroselenation of styrenes. Organoselenium building blocks are accessed with selectivity for the branched isomer. Through a Rh-hydride pathway, C-Se bonds can be forged with excellent regio- and enantiocontrol.",

author = "Slocumb, \{Hannah S.\} and Shaozhen Nie and Dong, \{Vy M.\} and Yang, \{Xiao Hui\}",

year = "2022",

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T1 - Enantioselective Selenol-ene Using Rh-Hydride Catalysis

AU - Slocumb, Hannah S.

AU - Nie, Shaozhen

AU - Dong, Vy M.

AU - Yang, Xiao Hui

PY - 2022/10/12

Y1 - 2022/10/12

N2 - This study showcases the first enantioselective hydroselenation of styrenes. Organoselenium building blocks are accessed with selectivity for the branched isomer. Through a Rh-hydride pathway, C-Se bonds can be forged with excellent regio- and enantiocontrol.

AB - This study showcases the first enantioselective hydroselenation of styrenes. Organoselenium building blocks are accessed with selectivity for the branched isomer. Through a Rh-hydride pathway, C-Se bonds can be forged with excellent regio- and enantiocontrol.

UR - https://www.scopus.com/pages/publications/85139248036

U2 - 10.1021/jacs.2c08475

DO - 10.1021/jacs.2c08475

M3 - Article

C2 - 36162123

AN - SCOPUS:85139248036

SN - 0002-7863

VL - 144

SP - 18246

EP - 18250

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 40

ER -

Enantioselective Selenol-ene Using Rh-Hydride Catalysis

Abstract

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