Electrodeposition and electrocatalytic properties of platinum nanoparticles on multi-walled carbon nanotubes: Effect of the deposition conditions

Yue Zhao; Louzhen Fan; Haizheng Zhong; Yongfang Li

doi:10.1007/s00604-006-0701-z

Electrodeposition and electrocatalytic properties of platinum nanoparticles on multi-walled carbon nanotubes: Effect of the deposition conditions

Yue Zhao
, Louzhen Fan^*
, Haizheng Zhong
, Yongfang Li

^*Corresponding author for this work

Beijing Normal University
CAS - Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Platinum (Pt) nanoparticles were electrochemically deposited on multi-walled carbon nanotubes (MWCNTs) through a three-step process, including an electrochemical treatment of MWCNT, electro-oxidation of PtCl ₄^2- to Pt(IV) complex, and an electro-conversion of Pt(0) on MWCNT. The effect of formation conditions for Pt(IV) complexes on the Pt nanoparticals transformed was investigated. The structure and elemental composition of the resulting Pt/MWCNT electrode were characterized by transmission electron micrograph (TEM) and energy dispersive X-ray spectroscopy (EDX). The electrocatalytic properties of the resulting Pt/MWCNT electrode for methanol oxidation have been investigated. The high electrocatalytic activity and good stability of Pt/MWCNT electrode may be attributed to the high dispersion of platinum nanoparticles and the particular properties of the MWCNT supports.

Original language	English
Pages (from-to)	327-334
Number of pages	8
Journal	Microchimica Acta
Volume	158
Issue number	3-4
DOIs	https://doi.org/10.1007/s00604-006-0701-z
Publication status	Published - May 2007
Externally published	Yes

Keywords

Cyclic voltammetry
Electrocatalysis
MWCNTs
Platinum nanoparticles

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10.1007/s00604-006-0701-z

Cite this

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title = "Electrodeposition and electrocatalytic properties of platinum nanoparticles on multi-walled carbon nanotubes: Effect of the deposition conditions",

abstract = "Platinum (Pt) nanoparticles were electrochemically deposited on multi-walled carbon nanotubes (MWCNTs) through a three-step process, including an electrochemical treatment of MWCNT, electro-oxidation of PtCl 42- to Pt(IV) complex, and an electro-conversion of Pt(0) on MWCNT. The effect of formation conditions for Pt(IV) complexes on the Pt nanoparticals transformed was investigated. The structure and elemental composition of the resulting Pt/MWCNT electrode were characterized by transmission electron micrograph (TEM) and energy dispersive X-ray spectroscopy (EDX). The electrocatalytic properties of the resulting Pt/MWCNT electrode for methanol oxidation have been investigated. The high electrocatalytic activity and good stability of Pt/MWCNT electrode may be attributed to the high dispersion of platinum nanoparticles and the particular properties of the MWCNT supports.",

keywords = "Cyclic voltammetry, Electrocatalysis, MWCNTs, Platinum nanoparticles",

author = "Yue Zhao and Louzhen Fan and Haizheng Zhong and Yongfang Li",

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doi = "10.1007/s00604-006-0701-z",

language = "English",

volume = "158",

pages = "327--334",

journal = "Microchimica Acta",

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TY - JOUR

T1 - Electrodeposition and electrocatalytic properties of platinum nanoparticles on multi-walled carbon nanotubes

T2 - Effect of the deposition conditions

AU - Zhao, Yue

AU - Fan, Louzhen

AU - Zhong, Haizheng

AU - Li, Yongfang

PY - 2007/5

Y1 - 2007/5

N2 - Platinum (Pt) nanoparticles were electrochemically deposited on multi-walled carbon nanotubes (MWCNTs) through a three-step process, including an electrochemical treatment of MWCNT, electro-oxidation of PtCl 42- to Pt(IV) complex, and an electro-conversion of Pt(0) on MWCNT. The effect of formation conditions for Pt(IV) complexes on the Pt nanoparticals transformed was investigated. The structure and elemental composition of the resulting Pt/MWCNT electrode were characterized by transmission electron micrograph (TEM) and energy dispersive X-ray spectroscopy (EDX). The electrocatalytic properties of the resulting Pt/MWCNT electrode for methanol oxidation have been investigated. The high electrocatalytic activity and good stability of Pt/MWCNT electrode may be attributed to the high dispersion of platinum nanoparticles and the particular properties of the MWCNT supports.

AB - Platinum (Pt) nanoparticles were electrochemically deposited on multi-walled carbon nanotubes (MWCNTs) through a three-step process, including an electrochemical treatment of MWCNT, electro-oxidation of PtCl 42- to Pt(IV) complex, and an electro-conversion of Pt(0) on MWCNT. The effect of formation conditions for Pt(IV) complexes on the Pt nanoparticals transformed was investigated. The structure and elemental composition of the resulting Pt/MWCNT electrode were characterized by transmission electron micrograph (TEM) and energy dispersive X-ray spectroscopy (EDX). The electrocatalytic properties of the resulting Pt/MWCNT electrode for methanol oxidation have been investigated. The high electrocatalytic activity and good stability of Pt/MWCNT electrode may be attributed to the high dispersion of platinum nanoparticles and the particular properties of the MWCNT supports.

KW - Cyclic voltammetry

KW - Electrocatalysis

KW - MWCNTs

KW - Platinum nanoparticles

UR - https://www.scopus.com/pages/publications/34248547416

U2 - 10.1007/s00604-006-0701-z

DO - 10.1007/s00604-006-0701-z

M3 - Article

AN - SCOPUS:34248547416

SN - 0026-3672

VL - 158

SP - 327

EP - 334

JO - Microchimica Acta

JF - Microchimica Acta

IS - 3-4

ER -

Electrodeposition and electrocatalytic properties of platinum nanoparticles on multi-walled carbon nanotubes: Effect of the deposition conditions

Abstract

Keywords

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